Tuning the Regioselective Functionalization of Trifluoromethylated Dienes via Lanthanum-Mediated Single C−F Bond Activation

The development of new fluorine-containing building blocks and their efficient synthetic access is currently a challenging research field. Herein, the highly regio- and stereoselective addition of a large range of aldehydes onto trifluoromethylated benzofulvenes was achieved using a simple La/I₂/DIBAL-Cl system via a selective C−F bond activation process. This versatile methodology provided homodienyl alcohols bearing a terminal CF₂-alkene with potential further applications, as shown by the dehydration to the first benzofulvenes carrying a difluorovinyl group. In addition, for certain electron-poor aldehydes, unprecedented ipso substitution of the CF₃ group in a diene was observed, which, according to DFT studies, is related to the presence of the large, Lewis-acidic lanthanum metal.     

Eco-friendly process toward collector- and binder-free,high-energy density electrodes for lithium-ion batteries

Journal of Solid State Electrochemistry - The preparation of collector- and binder-free, high-energy density cathodes made from carbon-coated LiFePO4 (C-LFP) and single-walled carbon nanotubes...     

Convolution powers of complex functions on

Repeated convolution of a probability measure on leads to the central limit theorem and other limit theorems. This paper investigates what kinds of results remain without positivity. It reviews theorems due to Schoenberg, Greville, and Thomée which are motivated by applications to data smoothing (Schoenberg and Greville) and finite difference schemes (Thomée). Using Fourier transform arguments, we prove detailed decay bounds for convolution powers of finitely supported complex functions on . If M is an hermitian contraction, an estimate for the off‐diagonal entries of the powers of is obtained. This generalizes the Carne–Varopoulos Markov chain estimate.     

A Primal–Dual Splitting Method for Convex Optimization Involving Lipschitzian, Proximable and Linear Composite Terms

We propose a new first-order splitting algorithm for solving jointly the primal and dual formulations of large-scale convex minimization problems involving the sum of a smooth function with Lipschitzian gradient, a nonsmooth proximable function, and linear composite functions. This is a full splitting approach, in the sense that the gradient and the linear operators involved are applied explicitly without any inversion, while the nonsmooth functions are processed individually via their proximity operators. This work brings together and notably extends several classical splitting schemes, like the forward–backward and Douglas–Rachford methods, as well as the recent primal–dual method of Chambolle and Pock designed for problems with linear composite terms.     

On the spatially homogeneous landau equation for hard potentials part i : existence,uniqueness and smoothness

We study the Cauchy problem for the homogeneous Landau equation of kinetic theory, in the case of hard potentials. We prove that for a large class of initial data, there exists a unique weak solution to this problem, which becomes immediately smooth and rapidly decaying at infinity.     

Improved Duality Estimates and Applications to Reaction-Diffusion Equations

We present a refined duality estimate for parabolic equations. This estimate entails new results for systems of reaction-diffusion equations, including smoothness and exponential convergence towards equilibrium for equations with quadratic right-hand sides in two dimensions. For general systems in any space dimension, we obtain smooth solutions of reaction-diffusion systems coming out of reversible chemistry under an assumption that the diffusion coefficients are sufficiently close one to another.     

Connections between semidefinite relaxations of the max-cut and stable set problems

We describe links between a recently introduced semidefinite relaxation for the max-cut problem and the well known semidefinite relaxation for the stable set problem underlying the Lovász’s theta function. It turns out that the connection between the convex bodies defining the semidefinite relaxations mimics the connection existing between the corresponding polyhedra. We also show how the semidefinite relaxations can be combined with the classical linear relaxations in order to obtain tighter relaxations. This work was done while the author visited CWI, Amsterdam, The Netherlands. Svata Poljak untimely deceased in April 1995. We shall both miss Svata very much. Svata was an excellent colleague, from whom we learned a lot of mathematics and with whom working was always a very enjoyable experience; above all, Svata was a very nice person and a close friend of us. The research was partly done while the author visited CWI, Amsterdam, in October 1994 with a grant fom the Stieltjes Institute, whose support is gratefully acknowledged. Partially supported also by GACR 0519. Research support by Christian Doppler Laboratorium für Diskrete Optimierung.     

Generic super-exponential stability of elliptic equilibrium positions for symplectic vector fields

In this article, we consider linearly stable elliptic fixed points (equilibrium) for a symplectic vector field and prove generic results of super-exponential stability for nearby solutions. We will focus on the neighborhood of elliptic fixed points but the case of linearly stable isotropic reducible invariant tori in a Hamiltonian system should be similar. More specifically, Morbidelli and Giorgilli have proved a result of stability over superexponentially long times if one considers an analytic Lagrangian torus, invariant for an analytic Hamiltonian system, with a diophantine translation vector which admits a sign-definite torsion. Then, the solutions of the system move very little over times which are super-exponentially long with respect to the inverse of the distance to the invariant torus. The proof proceeds in two steps: first one constructs a high-order Birkhoff normal form, then one applies the Nekhoroshev theory. Bounemoura has shown that the second step of this construction remains valid if the Birkhoff normal form linked to the invariant torus or the elliptic fixed point belongs to a generic set among the formal series. This is not sufficient to prove this kind of super-exponential stability results in a general setting. We should also establish that the most strongly non resonant elliptic fixed point or invariant torus in a Hamiltonian system admits Birkhoff normal forms fitted for the application of the Nekhoroshev theory. Actually, the set introduced by Bounemoura is already very large but not big enough to ensure that a typical Birkhoff normal form falls into this class. We show here that this property is satisfied generically in the sense of the measure (prevalence) through infinite-dimensional probe spaces (that is, an infinite number of parameters chosen at random) with methods similar to those developed in a paper of Gorodetski, Kaloshin and Hunt in another setting.     

Convergence of the Structure Function of a Multifractal Random Walk in a Mixed Asymptotic Setting

Some asymptotic properties of a Brownian motion in multifractal time, also called multifractal random walk, are established. We show the almost sure and L ¹ convergence of its structure function. This is an issue directly connected to the scale invariance and multifractal property of the sample paths. We place ourselves in a mixed asymptotic setting where both the observation length and the sampling frequency may go together to infinity at different rates. The results we obtain are similar to the ones that were given by Ossiander and Waymire [19 Ossiander , M. , and Waymire , E.C. 2000 . Statistical estimation for multiplicative cascades . Ann. Stat. 28 : 1533 – 1560 .[Crossref], [Web of Science ®] , [Google Scholar]] and Bacry et al. [1 Bacry , E. , Gloter , A. , Hoffmann , M. , and Muzy , J.F. Multifractal analysis in a mixed asymptotic framework . Ann. Appl. Prob. (to appear) . [Google Scholar]] in the simpler framework of Mandelbrot cascades.