Chromatographic and mass spectral studies on isobaric and isomeric substances related to 3,4-methylenedioxymethamphetamine

A series of isobaric and isomeric molecules related to 3,4methylenedioxymethamphetamine (3,4-MDMA) are prepared and evaluated as potential mass spectral equivalents to this controlled substance. These compounds have the potential to produce a mass spectrum equivalent to 3,4-MDMA, thus making mass spectrometry a nonconclusive method for confirming the identity of any one of the substances. The various isomeric forms of the methoxymethylphenethylamines and the methoxymethcathinones have mass spectra essentially equivalent to 3,4-MDMA, but the ethoxy substituted phenethylamines show a unique fragment at m/z 107. Gas chromatographic separation on nonpolar stationary phases successfully resolved these compounds from 3,4-MDMA, however only a limited set of side chain regioisomers and ring substitution patterns are evaluated in this initial study.     

Radius,perimeter, and density profile for percolation clusters and lattice animals

Monte Carlo simulation and series expansion shows the radius of gyration of large clusters withs sites each to vary ass with0.56 in two and0.47 in three dimensions at the percolation threshold, and with(d=2)0.65 and(d=3)0.53 for random lattice animals (zero concentration). Clusters up tos=100 were used. The perimeter of random animals approaches 2.8s for larges on the simple cubic lattice. Monte Carlo simulation of the Eden process (growing animals) up tos=5,000 indicates a systematic variation of about ±0.05 for the effective exponent=(s) and thus suggests that the true asymptotic exponents may be compatible with the predictions of hyper-scaling.     

Intermolecular Domino Reaction of Two Aryl Iodides Involving Two C?H Functionalizations

A palladium‐catalyzed intermolecular cross‐coupling of two aryl iodides is reported, giving polycyclic ring systems with a high level of convergence and efficiency.     

Chemoenzymatic synthesis of highly enantiomerically enriched secondary alcohols with a thiazolic core

Stereoselective preparative enzymatic acylation and hydrolysis/methanolysis of various C-substituted rac-thiazol-2-yl-methanols were achieved for the preparation of enantiopure or enantiomerically enriched, naturally occurring 2-hydroxymethylthiazoles. The absolute configurations of the resulting secondary alcohols were determined by a detailed ¹H NMR study of Mosher’s derivatives.     

Marine Sediments and Snow from Ross Sea Region (Antarctica) Dating by 210Pb Method

Abstract

²¹⁰Pb is widely used to determine accumulation rates in order to obtain a time scale in environmental samples. The most accurate method uses the determination of ²¹⁰Pb via its grand-daughter ²¹⁰Po by alpha spectrometry. Unfortunately this method requires a complex wet-chemistry procedure to achieve the separation of ²¹⁰Po from its matrix. In this work a simplified procedure for the chemical separation of ²¹⁰Po is proposed and applied to three marine sediment cores and a 10 m snow core collected in Antarctica. The calculated sedimentation rates for marine sediments range from 0.053 to 0.071 cm y^?1. The mean annual accumulation rate for the snow is 16.6 cm y^?1 w.e. A comparison with literature data in the same region is given.     

Kinetic Study of the CCl2 Radical Recombination Reaction by Laser‐Induced Fluorescence Technique

An experimental setup that coupled IR multiple‐photon dissociation (IRMPD) and laser‐induced fluorescence (LIF) techniques was implemented to study the kinetics of the recombination reaction of dichlorocarbene radicals, CCl₂, in an Ar bath. The CCl₂ radicals were generated by IRMPD of CDCl₃. The time dependence of the CCl₂ radicals’ concentration in the presence of Ar was determined by LIF. The experimental conditions achieved allowed us to associate the decrease in the concentration of radicals to the self‐recombination reaction to form C₂Cl₄. The rate constant for this reaction was determined in both the falloff and the high‐pressure regimes at room temperature. The values obtained were k₀ = (2.23 ± 0.89) × 10^?29 cm⁶ molecules^?2 s^?1 and k_∞ = (6.73 ± 0.23) × 10^?13 cm³ molecules^?1 s^?1, respectively.     

A New Bismuth Nitrate–Catalyzed Electrophilic Substitution of Indoles with Carbonyl Compounds Under Solvent-Free Conditions

An expeditious synthetic method for the preparation of bis(indollyl)methane derivatives has been developed through a bismuth nitrate-catalyzed reaction of indole with various carbonyl compounds in mortar and pastle under solvent-free conditions.     

Alternating and Random Copolymers of Vinyl Acetate and Maleic Anhydride

Alternating copolymers of vinyl acetate (VAc) and maleic anhydride (MA) are produced preferentially when VAc and MA are copolymerized at moderate temperatures while random copolymers are produced at temperatures above 90°C. A charge-transfer complex (CTC) of VAc/MA exists at moderate temperatures but does not exist at temperatures above 90°C.     

Waste Cleaning Waste: Combining Alginate with Biowaste-Derived Substances in Hydrogels and Films for Water Cleanup

Biowaste-derived substances isolated from green compost (BBS-GC) are environmentally friendly reactants similar to humic substances, which contain multiple functionalities, that are suitable for adsorbing different kinds of pollutants in wastewater. Herein, sodium alginate (derived from brown algae) cross-linked with both Ca²⁺ ions and BBS-GC in the form of hydrogels and dried films are proposed as green, easy-to-form, and handleable materials for tertiary water treatments. The results show that both hydrogels and films are mechanically stable and can effectively remove differently charged dyes through an adsorption mechanism that can be described by the Freundlich model. BBS-GC-containing gels always performed better than samples prepared without BBS-GC, revealing that such unconventional materials can integrate waste valorization and water decontamination, potentially providing social and environmental benefits.