基带同步的调制离散性分析及射频同步应用研究

目前基于多载波调制技术的地面数字电视单频网,采用基带码流分配方式保证数据接收的可靠性,但存在调制离散性,长时延多径等产生的同频干扰问题.而基于射频分发产生的射频同步技术(RFST)为有效解决这些问题提供新的组网方案.通过对现有基带同步的调制离散性分析,得出调制误差率不一致对接收信号误码率的影响结果,并与采用RFST技术的单频网系统方案进行比较.理论推导表明,RFST技术保证各发射站点发射信号频谱特性一致.而仿真结果和实验网测试结果表明,RFST技术有效降低误码率,因此此中、小功率覆盖的方式可为小区域覆盖提供了更优性能的组网方案.     

热红外高光谱成像技术的研究现状与展望

高光谱成像具有精细的光谱分辨能力,在热红外谱段实施高光谱成像对目标探测与识别有显著效果.与国外相比,我国在该领域的研究还相对薄弱,应用部门的研究主要基于国外数据,国内尚未有成熟的仪器.对国内外研究现状进行了详细调研,并结合目前国内已经布局的研究项目对该领域未来的发展进行了展望,对我国发展高性能空间红外光谱成像技术具有一定意义.     

非对称In0.53Ga0.47As/In0.52Al0.48As量子阱的零场自旋分裂能与高场g因子

我们研究了非对称In_0.53Ga_0.47As/In_0.52Al_0.48As量子阱中二维电子气的磁输运性质,所测量的样品的径向磁阻Rxx的Shubinikov-de Haas振荡没有呈现出拍频的特征。通过测量样品的弱局域效应提取了其零场自旋分裂能并通过对自旋分裂的Rxx双峰间距随倾斜角度theta的依赖关系的拟合提取了高场下的有效g因子。样品的Dingle plot图呈现非线性和特征,这可以归因于来自样品衬底附近的掺杂Be原子的长程势散射效应。     

恶劣环境下图像的缺陷补偿

在分析介质(环境)对成像质量影响的基础上,建立了介质中图像衰减模型,提出了一种同时适用于过暗、过亮、有雾和水下四种恶劣环境下的衰减补偿算法.图像的主观评价和客观评价的实验表明运用此衰减补偿算法处理后的图像拥有更好的视觉效果,并在处理速度上有较大的提升.     

一类多氟负介电液晶单体的合成及性能研究

为了满足液晶母体在各种情况下的参数要求,合成了6种新型的具有2个或2个以上的2,3-二氟苯基的有较大负介电各向异性的化合物。以2,3-二氟丙基苯或2,3-二氟苯乙醚为原料,通过一系列反应合成了目标液晶单体。经过核磁共振、元素分析和质谱等方法确定了分子结构;利用示差扫描量热仪、阿贝折射仪和电容电抗测试仪等测试手段对其进行测定。实验表明,这类多氟化合物有着较大的光学各向异性(Δn=0.22~0.33)和较大负值的介电各向异性(Δε=-7.63~-12.02)。该类型的多氟化合物可以用于液晶母体的调配并且改善其部分性能。这类多氟化合物原料易得、收率较高(总收率50%),极易实现工业量产。     

IPX网络互连方案研究

本文介绍了IPX的基本功能和特点,对IPX服务商与客户以及IPX服务商之间的网络互连方案进行了研究。     

Preparation of PEO-b-PPO-b-PEO/α-cyclodextrin supramolecular hydrogels hybridized with exfoliated graphite nanoplates

Abstract

In this work, an effective method was developed to prepare novel PEO-b-PPO-b-PEO (EPE)/α-cyclodextrin (α-CD) supramolecular hydrogels containing exfoliated graphite nanoplates (xGNPs) by mixing an aqueous solution of α-CD with an aqueous dispersion of xGNPs at the presence of amphiphilic EPE copolymer. The EPE copolymer played three important roles in the preparation process: (1) as an exfoliating agent to break expanded graphites into xGNPs under ultrasonication, (2) as a dispersant to stabilize xGNPs in the aqueous solution, and （3）as a component to form the inclusion complexes with α-CD. The resultant xGNPs/EPE/α-CD hybridized hydrogels were characterized by scanning electron microscopy, wide-angle X-ray diffraction, differential scanning calorimetry, and Fourier transform infrared spectroscopy, which confirmed not only the formation of supramolecular hydrogel structure but also the homogenous dispersion of xGNPs in the hydrogel matrix. It was found that the existence of xGNPs can accelerate the speed of gel formation in comparison with that of the native EPE/α-CD hydrogel. Additionally, the water-retention ability and the release behavior of vancomycin hydrochloride for the xGNPs/EPE/α-CD hybridized hydrogels were investigated.     

中药柴胡总皂苷急性肝毒性的代谢组学研究

运用UPLC-MS联用技术对空白对照组、柴胡总皂苷(SS)组大鼠在给药后第3天和第5天的尿液样本进行分析检测,获得了以质荷比和保留时间为变量的矩阵数据。据此建立各组大鼠的尿液代谢轮廓图,并利用主成分分析(PCA)建立了SS的代谢组学毒性模型。结合肝组织病理,探讨了柴胡总皂苷的急性肝毒性。对于SS组与正常组,大鼠尿液代谢轮廓图表现出了一定的差异。在代谢组学毒性模型中,给药第3天和第5天的PCA分类均偏离正常组,而第5天的偏离程度强于第3天。同时,在第5天的肝组织病理切片中发现了组织病变。由此表明,给药组大鼠的代谢组偏离了正常组,这种偏离正是肝急性毒性的表现,且给药到第5天的肝毒性强于第3天,表明肝毒性与给药累积剂量呈正相关,表现出了明显的急性和累积肝毒性。     

A Trinuclear Ni(Ⅱ) Mixed-ligand Complex Containing Pentadentate N-butylsalicylhydrazide and Monodentate Imidazole:Synthesis, Characterization and Crystal Structure

A novel trinuclear nickel(Ⅱ) complex [Ni3(bushz)2(Himdz)2(H2O)2]?2DMF (1, bushz=N-butylsalicylhydrazide, Himdz=imidazole, DMF=N,N-dimethyl-formamide) has been synthesized and characterized by X-ray single-crystal diffraction characterization. Complex 1 crystallizes in the monoclinic system, space group P21/c with a=7.706(7), b=14.882(6), c=18.639(6) , β=108.08(2)o, V=2032(1) 3, Dc=1.525 g/cm3, Mr=932.95, Z=2, F(000)=972, μ=1.442 mm-1, the final R=0.0359 and wR=0.0771. The three nickel(Ⅱ) atoms in 1 are arranged in a strictly linear structure and exhibit alternating square-planar and octahedral geometries. The complex is connected to form a supramolecule with an infinite three-dimensional network through intermolecular hydrogen bonds. The electrochemical studies reveal that redox of Ni3+/Ni2+ in the complex is a quasi-reversible process. The thermal stability of the title complex was also studied.     

Syntheses and Crystal Structures of Two New Macrocyclic Compounds

Two new macrocyclic compounds, [Cu2(L)2](ClO4)4·2CH3OH (1) and [Cu(L)](ClO4)2·2H2O (2) (L = 1,3,10,12,15,18-hexaazatetracyclodocosane) were synthesized by condensation reactions involving amines and formaldehyde in the presence of copper anion. Compound 1 crystallizes in triclinic, space group Pí with a = 10.442(2), b = 14.197(3), c = 17.388(4), α = 91.218(4), β = 90.69(3), γ = 93.756(4)o, V = 2520.4(9)3, Z = 2, F(000) = 1260, Dc = 1.589 Mg/m3, Mr = 1205.92, μ = 1.137 mm-1, λ = 0.71073, the final R = 0.0668 and wR = 0.1573 for 9703 observed reflections with I > 2σ(I). Compound 2 crystallizes in monoclinic, space group C2/c with a = 16.911(2), b = 11.4172(15), c = 27.059(4), β = 107.787(2)o, V = 4974.7(12)3, Z = 8, F(000) = 2504, Dc = 1.610 Mg/m3, Mr = 602.92, μ = 1.155 mm-1, λ = 0.71073 , the final R = 0.0419 and wR = 0.1131 for 4374 observed reflections with I > 2σ(I).