首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   162027篇
  免费   39441篇
  国内免费   38000篇
化学   74635篇
晶体学   2710篇
力学   8044篇
综合类   1656篇
数学   16352篇
物理学   72451篇
无线电   63620篇
  2024年   1124篇
  2023年   2474篇
  2022年   4135篇
  2021年   4053篇
  2020年   3946篇
  2019年   4789篇
  2018年   4685篇
  2017年   6263篇
  2016年   6175篇
  2015年   7974篇
  2014年   8553篇
  2013年   10949篇
  2012年   12051篇
  2011年   13234篇
  2010年   16043篇
  2009年   16259篇
  2008年   10610篇
  2007年   9630篇
  2006年   9101篇
  2005年   8053篇
  2004年   7950篇
  2003年   5924篇
  2002年   5741篇
  2001年   5743篇
  2000年   5067篇
  1999年   3870篇
  1998年   2937篇
  1997年   2583篇
  1996年   2944篇
  1995年   3244篇
  1994年   3247篇
  1993年   3367篇
  1992年   2903篇
  1991年   2534篇
  1990年   2063篇
  1989年   2143篇
  1988年   2037篇
  1987年   1284篇
  1986年   1294篇
  1985年   919篇
  1984年   1051篇
  1982年   928篇
  1981年   769篇
  1980年   809篇
  1979年   568篇
  1978年   543篇
  1977年   639篇
  1976年   1044篇
  1972年   539篇
  1971年   453篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
在实际应用中,常常使用多个重写系统。本文主要讨论重写系统和的合流性,并给出了一个重写系统和具有合流性的充分条件。  相似文献   
42.
43.
    
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e).  相似文献   
44.
A homologous series of azomesogens, 2″-[4-(4′-n-alkoxybenzoyloxy)-2-chlorophenylazo] naphthalenes, with lateral chloro groups was synthesised. All the homologues synthesized exhibit enantiotropic nematic mesophase. The mesomorphic properties of the present series are compared with other structurally related series to evaluate the effect of lateral chloro group and its position on mesomorphism This paper was presented at the 10th National Conference on Liquid Crystals held at Bangalore, India during 9–11 October 2003.  相似文献   
45.
We show that, in dimensions equal or greater than three, classical strings do not join or split. This is part of a no-interaction theorem that is also proved. The quantum theory is considered.  相似文献   
46.
Summary Using a saturated non-boiling hydrocarbon mixture, the influence of two parameters on the results of field ionization mass spectrometry (FI-MS) measurements was studied: (a) the potential difference between the FI emitter and the counterelectrode; (b) the emitter temperature.Variation of the potential difference had only a minor effect on the average molecular mass measured and had no evident effect on the relative ring number distribution in the sample. In contrast, when the emitter temperature was increased, higher average molecular masses were recorded. Moreover, the average molecular masses shifted to higher ring numbers. In order to control the relationship between the described influences during mixture analysis, measuring instructions have been developed that enable the quantitative analysis of unknown saturated samples. However, average molecular mass of the mixture must be known.
Entwicklung einer quantitativen FI-MS-Methode zur Charakterisierung von gesättigten hoch- und nichtsiedenden Kohlenwasserstoffgemischen
  相似文献   
47.
    
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction.  相似文献   
48.
We present all-atom molecular dynamics simulations ofn-hexane on the basal plane of graphite at monolayer and multilayer coverages. In keeping with experimental data, we find the presence of ordered adsorbed layers both at single monolayer coverage and when the adsorbed layer coexists with excess liquid adsorbate. Using a simulation method that does not impose any particular periodicity on the adsorbed layer, we quantitatively compare our results to the results of neutron diffraction experiments and find a structural transition from a uniaxially incommensurate lattice to a fully commensurate structure on increasing the coverage from a monolayer to a multilayer. The zig-zag backbone planes of all the alkane molecules lie parallel to the graphite surface at the multilayer coverage, while a few molecules are observed to attain the perpendicular orientation at monolayer coverage. Dedicated to Professor C N R Rao on his 70th birthday  相似文献   
49.
模糊关系矩阵传递闭包的Warshall算法   总被引:8,自引:2,他引:6  
通过对照关系的传递闭包和模糊关系的传递闭包,把求关系矩阵的传递闭包的算法完整地推广到模糊关系矩阵上。  相似文献   
50.
介绍了一种带USB接口的光的155Mb/s码型发生器。伪随机码和其他格式的码型由PC产生通过USB接口进入双口RAM,再经串并变换后由光发射模块发射。该系统可方便地设定各种格式的码型,并同时具备光接口和电接口,可广泛应用于光通信各种实验中,具有重要的实用价值。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号