An Efficient Method for the Synthesis of Acyl-diazenes Using NaNO_2/NaHSO_4·H_2O

Azo compounds are widely utilized as analytic reagents and dyes1, they can also be used in material of non-linear optics, material of optics information storing in laser disks, and dyes with oil solubility in photochromy in modern technology2. Recently, many noteworthy studies have shown that some azo compounds possess excellent optical memory and photoelectric properties3,4. For example, polymer scaffolds bearing azobenzene-potential are useful for optical information storage, azo-dye doped…     

Molecular Recognition of Bridged Bis(β-cyclodextrin)s Linked by Phenylenediseleno Tether on the Primary or Secondary Side with Fluorescent Dyes

A Novel β-cyclodextrin dimer,2,2′-o-phenylenediseleno-bridgedbis(β-cyclodextrin)(2),has been synthesized by reaction ofmono-[2-O-(p-tolylsulfonyl)]-β-cyclodextrin and poly(o-phenylenediselenide).The complexation stability constants(K_s)and Gibbs free energy changes(-ΔG°)of dimer 2 with fourfluorescence dyes,that is,ammonium 8-anilino-1-naphthalene-sulfonate(ANS),sodium 6-(p-toluidino)-2-naphthalenesul-fonate(TNS),Acridine Red(AR)and Rhodamine B(RhB)have been determined in aqueous phosphate buffer solution(pH=7.2,0.1 mol·L~(-1)at 25℃ by means of fluorescence spec-     

Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)_2(CH_2=CH-CH_2-SO_3)·H_2O

ET is one of the most famous electron-donor molecules, which forms charge-transfer complexes (abbr. CT-complexes) with various types of counterions. These complexes have received intense attention because a wide range of physical properties such as conductivity and superconductivity1, ferromagnetism2-4 and nonlinear optical properties5 was found in these materials. Although the majority of the ET-based CT-complexes were prepared by combining with inorganic counterions, CT-complexes with o…     

Synthesis, Structure and Characterization of [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O40(H2)]·4H2O

An organic-inorganic compound [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O4o(H2)]·4H2O (Mr = 4048.00) was prepared from the hydrothermal reaction of Na2WO4·2H2O, CuCl2·2H2O,2,2'-bipyridine (2,2'-bpy) and H2O at 160 ℃ for 4 days. The compound crystallizes in the monoclinic system, space group P21/n with a = 18.9196(8), b = 20.4212(8), c = 21.8129(9)(A), β=96.992(3)°, V= 8365.0(6) (A)3, Dc= 3.214 g/cm3, Z = 4,μ(MoKα) = 17.269 mm-1 and F(000) = 7324.Of the 119837 total reflections, 17315 were unique (Rint = 0.0489). The final R = 0.0385 and wR =0.0770 for 11142 observed reflections with I ＞ 2σ(I). Single-crystal X-ray diffraction reveals that the structure is composed of [{Cu(2,2'-bpy)2}2W12O40(H2)]2- anions, discrete [Cu(2,2'-bpy)2]2 cations and lattice water molecules, and the anion is made up of a {W12O40(H2)}6- α-Keggin core decorated with two {Cu(2,2'-bpy)2}2 groups through bridging oxygen atoms.     

基于FrFT的欠采样LFM信号分离与参数估计

基于分数阶傅里叶变换，本文提出了一种欠采样条件下的宽带与窄带线性调频信号分离与参数估计方法。该方法先由延迟相乘和牛顿迭代算法估计信号的调频斜率，然后在分数阶傅立叶变换域进行滤波，实现信号分离。最后对欠采样信号解频率模糊，估计信号的初始频率。仿真表明了该方法分离宽带与窄带线性调频信号的可行性与分离后信号参数估计的有效性。     

离散分数随机变换域的脆弱性图像水印算法

用于多媒体真伪鉴别的脆弱性数字水印作为水印技术的一个重要分支,仍是一个未成熟的研究领域.本文基于离散分数随机变换,提出一种新的嵌入水印的算法.该算法同时对原始图像和水印进行离散分数随机变换,然后将水印的离散分数随机变换谱直接叠加到原始图像的离散分数随机变换谱上,最后再进行逆变换得到水印图像.此算法的主要特点是:离散分数随机变换本身就是算法的密钥,而且稍微对水印图像进行篡改就能被检测出来.并对该水印算法进行脆弱性分析,数值试验结果表明该算法具有良好的脆弱性和安全性.     

数字电视多频道延时直播系统的设计和实现

基于DVB标准设计直播系统,通过视频服务器方式进行延时直播,通过软件方法从多节目复用流中提取出多个单独的节目传输流,从而支持多个频道同时进行直播.可与硬盘播出系统进行系统集成.初步实现系统基本功能,按照相关标准进行传输流的技术指标检测,并对测试结果进行分析.     

基于Multisim7的电机习题仿真求解

《电机学》是各类学校电气类专业学生的一门必修课，同学们在学习时往往感到抽象、难于理解，在做习题时无从下手。作者根据Multisim7软件强大的仿真功能，提出了一种基于该电路仿真软件的电机习题求解方法，仿真效果良好，并得到了实验验证，已在教学中使用，受到了学生们的普遍欢迎。     

浅海底瞬变电磁探测系统关断沿影响因素研究

运用电路理论对发射线圈进行了建模分析;讨论了采用多匝小线圈进行浅海底瞬变电磁探测时,发射电流关断沿时间与电流幅值和发射线圈匝数之间的关系;给出了在保证发射磁矩的前提下,合理确定发射电流幅值与发射线圈匝数以缩短发射电流关断沿的原则,并通过实验进行了验证.     

激光通道传输热特性对远场光束质量的影响

 通过仿真计算分析了激光在光束控制系统通道内传输所产生的热效应及其对远场光束质量的影响。激光传播由近轴波方程描述，用快速傅里叶变换技术求解；激光热效应引起的流场密度变化采用完全Navier-Stokes方程计算。计算给出了不同波长、不同吸收系数条件下的远场光斑情况。计算结果表明，在典型的工作条件和状态下，较高能量激光在光束控制系统通道内产生的热效应影响不容忽视，它会明显降低远场目标处的能量集中度，增大光斑的发散。