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111.
Detailed pH-dependent steady state and picosecond time-resolved tryptophan fluorescence studies on thiocyanate and azide complexes
of horseradish peroxidase have been carried out. The fluorescence decay of the single tryptophan in these species was fitted
to a discrete three exponential model. Maximum entropy method analysis also gave three distinct regions of lifetime distributions.
The fast subnanosecond lifetime component was found to have > 97% amplitude contribution while other two longer lifetime components
have small contributions. Small contributions from the nanosecond lifetime components possibly arise from apoprotein impurity
or some small amount of disordered heme conformer of the protein. pH dependence of the fast picosecond lifetime components
was found to show a systematic behavior which has been interpreted in the light of obligatory conformation change associated
with activation of the enzyme at low pH. 相似文献
112.
U. Weisbrod R. Gutschke J. Knoth H. Schwenke 《Fresenius' Journal of Analytical Chemistry》1991,341(1-2):83-86
Summary Single layers and layer systems on diverse substrates were measured by Total Reflection X-Ray Fluorescence (TXRF) spectrometry. The angular dependence of the fluorescence intensities at grazing incidence allows the elemental composition, density and thickness of the layers to be evaluated using model calculations. 相似文献
113.
J. Kircher M. Cardona M. Alouani S. Gopalan O. Jepsen O. K. Andersen
E. Kaldis
J. Karpinski S. Rusieki 《Physica C: Superconductivity and its Applications》1992,200(3-4):413-417We report results of ellipsometric measurements of the dielectric tensor of YBa2Cu4O8 as well as calculations employing density functional theory in the local density approximation (LDA). For the computation of the one-electron eigenvalues and states the linear-muffin-tin-orbital method (LMTO) was used. Measured and calculated results show good agreement. In particular, the calculation predicts different band structures for YBa2Cu3O7 and YBa2Cu4O8 in the vicinity of the Fermi energy which lead to significant differences in the optical spectra. One such difference is a region of small ε2 in the near infrared which is a fingerprint of the high (relative to the top of the highest fully occupied band) Fermi energy as compared to the situation in YBa2Cu3O7. Our experimental results confirm the theoretical findings. 相似文献
114.
A broad range echelle spectrograph with a CCD matrix detector is developed for different applications in atomic spectroscopy. The compact optical design in combination with a dispersive entrance slit illumination offers a low stray light level and high throughput in the UV spectral region comparable only with spectrographs of higher focal length. Ray tracing calculations for typical wavelengths and the multi-line spectrum of an iron arc show the excellent overall spectrum quality. The subtraction of two partial spectra of different steel alloys demonstrates the spectra evaluation possibilities of the CCD spectrograph. 相似文献
115.
简要分析了白瓷双列直插外壳的失效模式和失效机理,并进行了模拟实验,通过对实验结果的分析,提出对成品微电路进行二次电镀能够提高其外壳的使用可靠性。 相似文献
116.
开关电流技术:一种新的模拟抽样数据处理方法 总被引:1,自引:0,他引:1
开关电流(SI)技术是一种新的模拟抽样数据处理技术,介绍了开关电流电路的基本单元结构,讨论了目前开关电流技术中存在的问题及其解决方法。对开关电流技术与开关电容技术的一些基本特征进行了比较,SI技术不仅结构简单,而且与标准CMOS工艺兼容,可望替代开关电容电路。 相似文献
117.
桌域网及其新技术的研究 总被引:1,自引:0,他引:1
桌域网是一种适合于多媒体业务需要的小型ATM网 ,是对传统计算机网络的体系结构的一种补充。本文介绍了设计桌域网的基本策略 ,讨论了它的设计目标和特性 ,给出了桌域网的体系结构、网络接入设备及其性能 ,最后提出研究桌域网的几点建议。 相似文献
118.
Summary Observation of fluorescence reactions on TLC plates is a valuable additional tool within the scope of screening procedures for many toxicologically relevant substances commonly encountered in clinical- and forensic-toxicological analysis. The reactions are based on native fluorescence without any treatment and on reactions obtained with an approved derivatization procedure. Due to the enormous sensitivity of the fluorescence detection, the method is also applicable to very low concentrations and small amounts of biological materials. The procedures described in this article have proven their high pragmatic usefulness in many practical cases.Dedicated to Professor Dr. Wilhelm Fresenius on the occasion of his 80th birthday 相似文献
119.
Summary X-ray reflectivity may be used to determine the internal structure of thin polymer films. An electron density difference of 10% for polystyrene and polyisoprene is sufficient to distinguish between a random distribution of lamellae, complete orientation parallel to the substrate surface and a surface induced formation of lamellae. The disappearance of the lamellar Bragg-peaks, with heating of the film, shows the transition into the disordered state. 相似文献
120.
Thermally induced phase conjugation by degenerate four-wave mixing in solutions of Rhodamine 6G in ethanol in the weak absorption region, low-reflectivity regime, and nonosecond time domain is reported. Evidence of oscillatory acoustic modes in the nonlinear medium is presented and existing theories are shown to explain satisfactorily the experimental results. 相似文献