One-pot Synthesis of 2, 5-Disubstituted Oxazoles Using Poly[styrene（iodosodiacetate）]

2,5-Disubstituted oxazoles were prepared conveniently by treatment of aromatic α-methyl ketones and nitriles with poly[styrene(iodosodiacetate)] in one-pot process.     

Synthesis of New 13-O-Acylavermectin Bl Aglycones

Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae.     

The Isoelectric Point and the Points of Zero Charge of Fe-Al-Mg Hydrotalcite-like Compounds

The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations.     

Nickel Chloride Promoted Glaser Coupling Reaction in Hot Water

A Glaser coupling reaction of terminal alkynes in the presence of nickel chloride withoutany organics and bases in hot water has been developed, which produces the correspondinghomo-coupling products in good yields.     

The First and Facile Synthesis of (±) Syringaresinol

The first and facile synthesis of (±)syringaresinol was described.     

晶体微观结构的数值计算

晶体微观结构是晶体材料在特定物理条件下其多个能量极小平衔态在空间形成的某种微尺度的规则分布．几何非线性的连续介质力学理论可以用能量极小化原理来解释晶体微观结构的形成，并用Young测度来刻画平衡态各变体在空间的概率分布．定性的理解与定量地分析和计算晶体材料的微观结构对于发展和改进高级晶体功能材料，如形状记忆合金、铁电体、磁至伸缩材料等，有重要的意义．本文回顾了近年来晶体微观结构数值计算方面的最新进展．介绍了计算晶体微观结构的几种数值方法及有关的数值分析结果。     

三维具弱阻尼Schrdinger-Boussinesq方程组的周期解(英文)

§ 1.　Introduction　　InthelaserandplasmaphysicsundertheinteractionofanonlinearcomplexSchr dingerfieldandarealBoussinesqfield ,thedynamicsisdescribedbythefollowingequationsiεt +Δε=nε ,( 1 .1 )ntt -Δn+γΔ2 n-Δf(n) -Δ｜ε｜2 =0 ,( 1 .2 )whereεrepresentsthecomplexSchr dingerfieldandnrepresentstherealBoussinesqfield .Theseequationshavemanyinterestingproperties,suchasafour parameterfamilyofsolitonso lutionsandLangmuircollapse(see [1— 4]) .Thustheydrawmuchattentionofmanyphysicistandmath…     

Birkhoff系统的Hojman定理的几何基础

研究了Birkhoff系统的Hojman定理的几何基础.建立了系统的运动微分方程和Hojman守恒 定理，利用现代微分几何给出了Birkhoff系统的Hojman定理的一个证明. 关键词： Birkhoff系统 Hojman定理 对称性 微分几何     

微模塑法制备PMMA/SiO2二氧化硅杂化材料微结构

以摩尔比为 1∶1的甲基丙烯酸甲酯 (MMA)、甲基丙烯酸 (3 三乙氧基硅烷基 )丙酯 (ESMA)单体、0 .2 %(单体总量的质量分数 )的偶氮二异丁腈AIBN引发剂和四氢呋喃 (THF)溶剂 ,及 2 0 % (总质量分数 )的正硅酸乙酯TEOS合成出PMMA/SiO2 有机 无机杂化的杂化溶胶 .将溶胶在洗净的普通光学玻璃基片表面甩膜 .利用软刻蚀中的微模塑法 ,把有机硅弹性印章复制有精细图纹一面轻放在杂化溶胶膜上进行微模塑 ,外加 1N压力于12 0℃下处理 2h使溶胶凝胶化 .印章剥离后在基片表面就形成了PMMA/SiO2 有机 无机杂化材料的微图纹结构 .从微图纹的光学显微镜照片可以看出微模塑方法制备杂化材料复制的图纹精细度高 ,操作简单易行 ,是一类比较理想的微细图纹结构加工的方法 .     

Local Prediction of Chaotic Time Series Based on Support Vector Machine

Based on phase space delay-coordinate reconstruction of a chaotic dynamics system, we propose a local prediction of chaotic time series using a support vector machine （SVM） to overcome the shortcomings of traditional local prediction methods. The simulation results show that the performance of this proposed predictor for making onestep and multi-step prediction is superior to that of the traditional local linear prediction method and global SVM method. In addition, it is significant that its prediction performance is insensitive to the selection of embedding dimension and the number of nearest neighbours, so the satisfying results can be achieved even if we do not know the optimal embedding dimension and how to select the number of nearest neighbours.