全文获取类型
收费全文 | 2578篇 |
免费 | 481篇 |
国内免费 | 408篇 |
专业分类
化学 | 1164篇 |
晶体学 | 65篇 |
力学 | 51篇 |
综合类 | 25篇 |
数学 | 139篇 |
物理学 | 944篇 |
无线电 | 1079篇 |
出版年
2024年 | 14篇 |
2023年 | 41篇 |
2022年 | 75篇 |
2021年 | 95篇 |
2020年 | 105篇 |
2019年 | 92篇 |
2018年 | 64篇 |
2017年 | 89篇 |
2016年 | 109篇 |
2015年 | 148篇 |
2014年 | 167篇 |
2013年 | 190篇 |
2012年 | 190篇 |
2011年 | 196篇 |
2010年 | 173篇 |
2009年 | 161篇 |
2008年 | 172篇 |
2007年 | 152篇 |
2006年 | 156篇 |
2005年 | 136篇 |
2004年 | 119篇 |
2003年 | 123篇 |
2002年 | 143篇 |
2001年 | 102篇 |
2000年 | 82篇 |
1999年 | 64篇 |
1998年 | 61篇 |
1997年 | 44篇 |
1996年 | 41篇 |
1995年 | 35篇 |
1994年 | 18篇 |
1993年 | 8篇 |
1992年 | 19篇 |
1991年 | 15篇 |
1990年 | 15篇 |
1989年 | 15篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1986年 | 10篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1973年 | 1篇 |
1963年 | 1篇 |
1962年 | 1篇 |
1961年 | 2篇 |
1948年 | 1篇 |
排序方式: 共有3467条查询结果,搜索用时 0 毫秒
81.
82.
在固定床反应器中考察了不同气氛下PBG恒温热解特性的差异,结合XPS与~(13)C NM R等技术手段分析了400℃恒温热解条件下PBG固相产物的化学结构变化。结果表明,PBG在400℃恒温热解时,生物质气化燃气(BAG)与N_2气氛下更易生成焦油,其析出量分别为50.71与37.45 mg/g,而临氧燃气气氛(BAG+2%O_2)下焦油析出量仅为11.96 mg/g,说明适量O_2的存在可有效抑制焦油的生成。进一步进行化学结构分析表明,在燃气(BAG)恒温热解条件下,PBG主要发生以脱氢脱氧为主的芳香化缩聚反应,易形成焦油类的大分子多环芳烃;而在临氧燃气(BAG+2%O_2)恒温热解条件下,PBG表面的有机基团易与O_2发生表面氧化反应,生成表面含氧官能团,在一定程度上抑制了芳香环缩聚反应,进而有利于降低焦油类物质的产率。因此,在生物质气化燃气实际高温过滤过程中适当添加氧(如:2%O_2),可有效降低PBG焦油收率,且不会形成大分子多环芳烃,有助于解决粗燃气过滤的过滤介质堵塞问题。 相似文献
83.
Fuzhong Han Bobo Su Peifang Song Yaqiao Wang Lina Jia Shanshan Xun Minggang Hu Liwei Zou 《Tetrahedron》2018,74(40):5908-5913
A N-bromosuccinimide (NBS) mediated decarboxylative sulfonylation of β-keto acids with sodium sulfinates is developed. The transformation exhibits a broad substrate scope and good functional group tolerance. Preliminary mechanistic studies showed that this reaction is likely to proceed through a nucleophilic substitution of β-keto acid with sulfonyl bromide pathway. All synthesized β-keto sulfones were evaluated the inhibitory effect against human carboxylesterase 1 (CES1). This investigation offers an expedient strategy for efficient synthesis of β-keto sulfones that are widely present in biologically active natural products and pharmaceutical agents. 相似文献
84.
Zirconium–Porphyrin‐Based Metal–Organic Framework Hollow Nanotubes for Immobilization of Noble‐Metal Single Atoms 下载免费PDF全文
Ting He Dr. Shuangming Chen Bing Ni Yue Gong Zhao Wu Prof. Li Song Prof. Lin Gu Prof. Wenping Hu Prof. Xun Wang 《Angewandte Chemie (International ed. in English)》2018,57(13):3493-3498
Single atoms immobilized on metal–organic frameworks (MOFs) with unique nanostructures have drawn tremendous attention in the application of catalysis but remain a great challenge. Various single noble‐metal atoms have now been successfully anchored on the well‐defined anchoring sites of the zirconium porphyrin MOF hollow nanotubes, which are probed by aberration‐corrected scanning transmission electron microscopy and synchrotron‐radiation‐based X‐ray absorption fine‐structure spectroscopy. Owing to the hollow structure and excellent photoelectrochemical performance, the HNTM‐Ir/Pt exhibits outstanding catalytic activity in the visible‐light photocatalytic H2 evolution via water splitting. The single atom immobilized on MOFs with hollow structures are expected to pave the way to expand the potential applications of MOFs. 相似文献
85.
1982年2月24日,世界上第一个股指期货合约——价值线指数期货合约(Value Line Index)在堪萨斯市农产品交易所上市交易.股指期货作为应用最广泛的金融期货之一,已有了近30年的历史.2010年4月16日我国股指期货也正式上市交易,这对我国金融市场来说是具有里程碑意义的.本文以股指期货推出前后沪深300指数普通收益数据和5分钟高频收益数据为样本,从描述性统计量对比和GARCH模型分析两个角度入手,研究我国股指期货对于股票现货市场波动性的影响.得出结论:第一、股指期货推出不会改变股票现货市场的长期趋势;第二、股指期货推出后市场的信息传递速度加快,股指期货发挥了其价格发现功能;第三、股指期货推出在长期减小了现货市场的波动,发挥了其规避风险、稳定市场的功能. 相似文献
86.
葛洵 《纯粹数学与应用数学》2010,26(3)
证明了如果空间类κ为D-空间类或闭遗传不可约空间类,则I(κ)(∈)κ.这一结果对于κ为D空间类和闭遗传不可约空间类,肯定地回答了I(κ)是否包含I2(κ)问题. 相似文献
87.
88.
In this paper, several recursive constructions for directed difference family and perfect directed difference family are presented by means of difference matrix and incomplete difference matrix. Finally the necessary and sufficient conditions for the existence of a (gv, g, 3, λ)-directed difference family in Zgv are established. As a consequence, the necessary and sufficient conditions for the existence of a cyclic directed group divisible design with block size three and type gv are obtained. 相似文献
89.
从湖北、湖南等省的土壤中分离得到14株苏云金芽胞杆菌菌株.血清型分析表明,苏云金芽胞杆菌分离株分别属于30个血清型中的3个血清型,另有两个与所用标准菌株的抗血清无凝集反应的菌株.观察和测定了苏云金芽胞杆菌分离株的形态和毒力,并用十二烷基磺酸钠-聚丙烯酰胺凝胶电泳(SDS-PAGE)分析了菌株的晶体蛋白成分,筛选到2株高效杀鳞翅目害虫的苏云金芽胞杆菌;并用特异性引物PCR检测了这些菌株的杀虫基因. 相似文献
90.
Stability is a fundamental design property of inventory systems. However, the often exploited linearity assumptions in the current literature create a major gap between theory and practice. In this paper the stability of a constrained production and inventory system with a Forbidden Returns constraint (that is, a non-negative order rate) is studied via a piecewise linear model, an eigenvalue analysis and a simulation investigation. The APVIOBPCS (Automatic Pipeline, Variable Inventory and Order Based Production Control System) and EPVIOBPCS (Estimated Pipeline, Variable Inventory and Order Based Production Control System) replenishment policies are adopted. Surprisingly, all kinds of non-linear dynamical behaviours of systems can be observed in these simple models. Exact expressions of the asymptotic stability boundaries and Lyapunovian stability boundaries are derived when actual and perceived transportation lead-time is 1 and 2 periods long respectively. Asymptotically stable regions in the non-linear Forbidden Return systems are identical to the stable regions in its unconstrained counterpart. However, regions of bounded fluctuations that continue forever, including both periodicity and chaos, exist in the parametrical plane outside the asymptotically stable region. Simulation shows a complex and delicate structure in these regions. The results suggest that accurate lead-time information is essential to eliminate inventory drift and instability and that ordering policies have to be designed properly in accordance with the actual lead-time to avoid these fluctuations and divergence. 相似文献