Covalent functionalization of multi-walled carbon nanotubes by lipase

Lipase from Candida rugosa was covalently anchored onto acid-treated multi-walled carbon nanotubes (MWNTs) through a self-catalytic mechanism. A variety of characterization techniques including FTIR, Raman spectroscopy, and XPS were employed to demonstrate the formation of the ester linkage between lipase and MWNTs. The MWNTs-lipase biocomposites showed significantly increased solubility in some common-used organic solvents, such as THF, DMF and chloroform. This study may offer a novel and facile route for covalent modification of carbon nanotubes, and expand the potential utilization of both lipases and MWNTs in the fields of biocatalyst and biosensor.     

Specific heat and related thermophysical properties of liquid Fe-Cu-Mo alloy

The specific heat and related thermophysical properties of liquid Fe77.5Cu13Mo9.5 monotectic alloy were investigated by an electromagnetic levitation drop calorimeter over a wide temperature range from 1482 to 1818 K. A maximum undercooling of 221 K (0.13 Tm) was achieved and the specific heat was determined as 44.71 J·mol-1·K-1. The excess specific heat, enthalpy change, entropy change and Gibbs free energy difference of this alloy were calculated on the basis of experimental results. It was found that the calculated results by traditional estimating methods can only describe the solidification process under low undercooling conditions. Only the experimental results can reflect the reality under high undercooling conditions. Meanwhile, the thermal diffusivity, thermal conductivity, and sound speed were derived from the present experimental results. Furthermore, the solidified microstructural morphology was examined, which consists of (Fe) and (Cu) phases. The calculated interface energy was applied to exploring the correlation between competitive nucleation and solidification microstructure within monotectic alloy.     

Thermal conductance for single wall carbon nanotubes

We report a theoretical analysis of the phonon thermal conductance, κ(T), for single wall carbon nanotubes (SWCN). In a range of low temperatues up to 100 K, κ(T) of perfect SWCN is found to increase with temperature, approximately, in a parabolic fashion. This is qualitatively consistent with recent experimental measurements where the tube-tube interactions are negligibly weak. When the carbon-carbon bond length is slightly varied, κ(T) is found to be qualitatively unaltered which implies that the anharmonic effect does not change the qualitative behavior of κ(T). Received 12 June 2001     

类型γ射线能谱指纹的识别机理

放射源的辐射指纹能起到标识和鉴别放射性物体的作用.在涉及核弹头不可逆销毁过程的深度核裁军核查中,核弹头的辐射指纹对标识和鉴别裁减下来的核弹头将起到关键作用.预先研究辐射指纹的有关技术,如识别机理的研究,将有助于深度核裁军的核弹头核查技术发展.以实验室放射源为研究对象,探索了类型γ射线能谱指纹的同一性识别机理.类型γ射线指纹识别机理的研究,就是要找出一种合适的方法,以较高的置信度,描述两个正在进行比较的γ射线指纹是否为同一放射源的指纹.采用了谱形比较法,并用谱相似度概念来描述两个指纹的相似程度.在谱形比较思想的指导下,编制了放射源类型指纹识别软件,并通过放射源同一性的识别实验验证了软件的有效性,同时研究了谱相似度随统计涨落和测量条件,如时间、源强和本底等因素的变化情况.研究结果表明:1)用相似度概念来描述两个指纹的相似程度,回答两个待比较的γ射线能谱是否代表同一类型放射源,是切实可行的;2)该识别机理只具备识别放射源类型的能力,而对同一类型、差异甚微的放射源个体还不能识别 关键词： γ射线能谱指纹 辐射指纹 识别机理 核查技术     

Sharp condition of global existence for second-order derivative nonlinear Schrödinger equations in two space dimensions

This paper discusses a class of second-order derivative nonlinear Schrödinger equations which are used to describe the upper-hybrid oscillation propagation. By establishing a variational problem, applying the potential well argument and the concavity method, we prove that there exists a sharp condition for global existence and blow-up of the solutions to the nonlinear Schrödinger equation. In addition, we also answer the question: how small are the initial data, the global solutions exist?     

X波段双极化有源相控阵天线的设计

机载或星载X波段有源相控阵雷达系统具有很高的分辨率，由于雷达系统使用了大量双极化子阵组成的有源相控阵天线（俯仰面和方位面均需扫描），频率的升高使得子阵馈线网络的可用面积受到了很大的限制。本文着重论述了有源相控阵天线中的双极化阵设计，提出了一系列解决方法，进而叙述了整个天线阵的设计。     

KrF准分子激光激发掺锗光纤折射率扰动的非线性过程

本文采用了一种简单的功率监测法,观察了KrF准分子激光对掺锗光纤折射率影响的非线性过程。观察到子纤芯折射率扰动过程中非稳定现象、饱和现象和折射率扰动的非线性。     

一种新颖的求解离散Gabor展开对偶窗的方法

本文给出了一种新颖的简捷的求解离散Gabor展开最佳对偶窗的方法．首先推导了离散Gabor展开的公式，给出了连续Gabor展开和离散Gabor展开间的关系．最后利用连续展开和离散展开间的关系给出了一求解离散Gabor展开最佳对偶窗的表达式及实例．     

IS—95CDMA系统的容量分析

容量的需求是推动ＣＤＭＡ数字蜂窝移动通信开发的主要动力。系统的容量受许多因素的影响，本文针对ＩＳ－９５ＣＤＭＡ系统在采用了功率控制、话音激活和扇区划分技术的情况下，对系统的容量进行了分析，同时也分析了功率控制精度对容量的影响。     

适合航天电子系统应用的DC－DC变换器

讨论了航天ＤＣ－ＤＣ混合集成电路的拓朴结构。通过对几种电路的性能比较，提出了适合航天应用的ＤＣ－ＤＣ变换器的最佳拓朴结构。论述了ＰＷＭ－ＬＩＮ变换器的控制方法，该方法对于确保二次稳压ＤＣ－ＤＣ变换器较高的效率具有重要意义，亦可大大提高混合集成电路的成品率。