A scheme of access service recommendation for the Social Internet of Things

The rapid increase in the complexity and the extent of personalization of services in the Internet of Things (IoT) has led to a greater demand for frequent collaboration among heterogeneous devices. Moreover, with the inseparable relations between human and devices, the paradigm of Social IoT (SIoT) is gaining popularity in recent years. How to effectively facilitate the access to quality services and credible devices in large‐scale networks via defining, establishing, and managing social architectures among things has become a critical issue. In this paper, a scheme of access service recommendation for the SIoT is presented with the understanding of inherent constraints and factors that influence the security and stability of IoT networks. In which, timeliness properties are considered in each transaction for dynamic performance enhancements. With the benefits of promoting service discovery and composition, social relationships among things are introduced in the proposed scheme. An energy‐aware mechanism is also utilized as a restrictive factor in trustworthiness evaluation. Finally, the recommendation is based not only on the past performance but also on the social relationship and the energy status of nodes. Simulation experiments demonstrate the effectiveness and benefits of our scheme from three aspects including rating accuracy, dynamic behavior, and network stability. Copyright © 2015 John Wiley & Sons, Ltd.     

Design,Synthesis, and Versatile Processing of Indolo[3,2‐b]indole‐Based π‐Conjugated Molecules for High‐Performance Organic Field‐Effect Transistors

A series of indolo[3,2‐b]indole (IDID) derivatives comprising the core unit of N,N‐dihexyl‐IDID with different aromatic and aliphatic substituents at 2‐ and 7‐position are designed and synthesized to construct high‐performance organic semiconductors by different processing routes. Structure‐property relationship of the derivatives is comprehensively studied in terms of their photophysical, electrochemical, structural, and electrical characteristics. IDID derivatives are either evaporated in vacuum or dissolved in common organic solvents to ensure applicalbility in different processing routes toward outstanding p‐type semiconductor films. Among others, the excellently soluble compound 4H4TIDID (with 2‐ and 7‐substituents of 5‐hexyl‐2,2′‐bithiophene moiety, solubility >20 wt% in chloroform), shows the highest field‐effect hole mobility of 0.97 cm² V^?1 s^?1 in a device constructed by vacuum‐deposition and 0.18 cm² V^?1 s^?1 in device cosntructed by spin‐coating, respectively. The 2D grazing incidence X‐ray diffraction of 4H4TIDID films in both devices identically show the 2D molecular orientation favorable for the high transistor mobility.     

Subsurface Space‐Charge Dopant Segregation to Compensate Surface Excess Charge in a Perovskite Oxide

Since the first prediction by Frenkel, many follow‐up studies have been carried out to show the presence of subsurface space‐charge layers having the opposite sign to that of the excess charge at the surface, producing overall neutrality in ionic crystals. However, no precise experimental evidence demonstrating how the aliovalent solutes segregate in the space‐charge region beneath the surface has been provided over the past several decades. By utilizing atomic‐scale imaging and chemical probing in a perovskite oxide, the origin of the surface excess charge at the topmost surface and the position of segregated dopants in the space‐charge region is precisely determined. The impact of the space‐charge contribution to the dopant distribution near the surface in oxide crystals is explored.     

Ultra fast symmetry and SIMD-based projection-backprojection (SSP) algorithm for 3-D PET image reconstruction

Remarkable progress in positron emission tomography (PET) development has occurred in recent years, in hardware, software, and computer implementation of image reconstruction. Recent development in PET scanners such as the high-resolution research tomograph (HRRT) developed by CTI (now Siemens) represents such a case and is capable of greatly enhanced resolution as well as sensitivity. In these PET scanners, the amount of coincidence line data collected contains more than 4.5 x 10(9) coincidence lines of response generated by as many nuclear detectors as 120 000. This formidable amount of data and the reconstruction of this data set pose a real problem in HRRT and have also been of the major bottle neck in further developments of high resolution PET scanners as well as their applications. In these classes of PET scanners, therefore, obtaining one set of reconstructed images often requires many hours of image reconstruction. For example, in HRRT with full data collection in a normal brain scan (using SPAN 3), the image reconstruction time is close to 80 min, making it practically impossible to attempt any list-mode-based dynamic imaging since the image reconstruction time would take many days (as much as 43 h or more for 32-frame dynamic image reconstruction). To remedy this data-handling problem in image reconstruction, we developed a new algorithm based on the symmetry properties of the projection and backprojection processes, especially in the 3-D OSEM algorithm where multiples of projection and back-projection are required. In addition, the single-instruction multiple-data (SIMD) technique also allowed us to successfully incorporate the symmetry properties mentioned above, thereby effectively reducing the total image reconstruction time to a few minutes. We refer to this technique as the symmetry and SIMD-based projection-backprojection (SSP) technique or algorithm and the details of the technique will be discussed and an example of the application of the technique to the HRRT's OSEM algorithm will be presented as a demonstration.     

Soluble and easily crystallized anthracene derivatives: precursors of solution-processable semiconducting molecules

New soluble anthracene derivatives containing thiophene and phenylenevinylene derivatives were synthesized via well-known synthetic routes. TIPS derivatives were added at the 9,10-positions of anthracene for the solubility and crystallinity. Both of the molecules were found to be promising for high charge mobility and stable organic semiconductors. The soluble anthracene core (TIPSAnt) is a potential precursor for the synthesis of novel semiconducting materials.     

On-chip erythrocyte deformability test under optical pressure

This paper presents a novel method for an on-chip erythrocyte deformability test under optical pressure, especially to enhance the level of sensitivity with respect to the detection of cancerous diseases. To demonstrate the performance and sensitivity of the combined method, we introduce the concept of transit velocity, a modified elongation index, and shape recovery time of individual erythrocytes in a strictly confined region (2 microm deep, 4 microm wide, and 100 microm long). Finally, we investigate a synergy or convergence effect due to the combination of these parameters for in situ detection of cancerous diseases under optical pressure.     

Linear solvation energy parameters for model tropospheric aerosol surfaces

Excited-state absorption spectra for several coumarin derivatives adsorbed to aerosol particles provide linear solvation energy (LSE) relationships for the aerosol surfaces. This study focuses on NaCl and (NH4)2SO(4) particles as models for tropospheric aerosol. We investigate several others, including NH(4)Cl, NaBr, KI, Na(2)SO(4), NaNO(3), Al(2)O3, and CaCO(3), to establish trends and understand the factors that control polarity for surfaces. The Kamlet-Taft dipolarity/polarizability parameter, pi*, for these particles ranges from 0.73 to 1.69. The values are high compared to most homogeneous molecular solvents and are attributable to ion-dipole forces, especially at defect sites. We also find that the smaller values of pi* (1.01 for (NH4)2SO(4) and 0.73 for NH(4)Cl) correlate with appreciable hydrogen bond donor acidity in the surface (alpha = 0.23 and 1.06, respectively). Strong hydrogen bonds with the surface lead to a drop in overall polarity either by making interaction with very polar defect sites less likely or orienting the probe molecule away from the surface. Adsorbed water layers mainly alter the alpha value of the surface, but can have indirect effects on pi* by changing the interaction of the adsorbed molecule with the surface.     

Tautomerization of adenine facilitated by water: computational study of microsolvation

We present calculations for the mechanism and the barrier heights of tautomerization of adenine. We find various pathways for the 9(H) <--> 7(H) and 9(H) <--> 3(H) tautomerization. One mechanism for the 9(H) --> 7(H) tautomerization involves an sp(3)- or carbene-type intermediate, whereas the other proceeds via imine intermediates. Tautomerization from the 9(H) tautomer to 7(H) or 3(H) is predicted to occur with a very large activation barrier (60-70 kcal/mol), indicating that the processes may not occur readily in the gas phase. Interactions with the water molecule(s) are found to lower the barrier tremendously. We suggest that dramatic lowering of the 9(H) --> 3(H) and 9(H) --> 7(H) barriers by microsolvating water molecules may facilitate the formation and observation of the 7(H) and 3(H) tautomers in the solution phase.