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21.
Charge distribution study in the alpha-particle induced fission of232Th+ effect of excitation energy
Ramaswami A. Srivastava B. K. Sahakundu S. M. Manohar S. B. Prakash Satya Ramaniah M. V. 《Journal of Radioanalytical and Nuclear Chemistry》1986,102(2):499-506
The fractional cumulative yields of135I,138Xe and140Ba in the particle (30 MeV) induced fission of232Th have been determined following the growth and decay of135gXe,138gCs and140La, respectively, employing high resolution gamma ray spectroscopy. The fractional cumulative yield values are 0.766±0.02, 0.813±0.03 and 0.991±0.004, respectively. The analysis of the data indicates a broader width of charge distribution () compared to the normally observed =0.56±0.06 for thermal neutron fission of235U. 相似文献
22.
Summary NTA (nitrilo triacetic acid) has been used as an impregnating agent for an efficient TLC separation of twelve metal ions, using a mixture of 5% aq ammonia, ethanol acetone and acetic acid as the solvent system and dithizone (0.5% in chloroform) for visualization. 相似文献
23.
A solid membrane electrode made with titanium arsenate as membrane material and "Araldite" as binder has been used to measure the activity of lead in the concentration range from 0.1 M to 5 x 10(-6)M. The electrode is unaffected by many cations, nitrate and acetate. The response time is 40-60 sec over the whole concentration range (in a static system) and the electrode has a working life of at least four months. The electrode can work in the pH range 2-5 and is tolerant of ethanol up to a content of 30% v v . It has been successfully used for end-point indication in potentiometric titration of lead. A membrane treated with cationic surfactant exhibits better selectivity. 相似文献
24.
25.
Charles L. Watkins Larry K. Krannich Colacot J. Thomas Dileep Srivastava 《Polyhedron》1994,13(24):3299-3307
The reactions of (Me2AlH)3 with Me2AsNMe2, MeAs(NMe2)2, and As(NMe2)3 were investigated as a function of time at room temperature and over the temperature range −90 to 24°C by use of 1H and 13C NMR spectroscopy. (Me2AlH)3 was found to be very reactive toward the aminoarsines, even at −90°C, and no stable Me2AlH-aminoarsine adducts were observed. Instead, the initial stages of the reactions involved AS---N bond cleavage with the generation of highly reactive AlN- and AsH-bonded species. The subsequent course of each reaction and the final arsenic-containing product distribution depended upon the original AL:N stoichiometric ratio and the respective aminoarsine. When the Al:N ratio was 1:1, the reactions were straightforward for each aminoarsine. However, in every case, [Me2AlNMe2]2 was the final AlN-containing product. Independent reactions were carried out to verify many of the proposed decomposition pathways that lead to thermodynamically stable products. The results of this study are compared with those of the analogous, previously reported (Me3Al)2-aminoarsine systems. Additionally, a new synthetic route to [Me2AlAsMe2]3 has been established from the reaction of (Me2AlH)3 with Me2AsH. 相似文献
26.
The adsorption of maleic anhydride on the Si(001) surface has been investigated using the first-principles pseudopotential formalism. Our total-energy calculations suggest that maleic anhydride (C2H2-C2O3) adsorbs preferentially through a [2+2] cycloaddition of the C=C bond ([2+2]) with an adsorption energy of around 42 kcal/mol. Besides the [2+2] configuration we have also considered other possible coverages and adsorption models, including the adsorption on inter-row and intrarow dimer sites. Based on the analysis of the relative stability of different adsorption models, we propose the formation of mixed domains, containing the [2+2] unit and an interdimer unit. The comparison of our calculated electronic band structure, vibrational modes, and scanning tunneling microscopy images for the [2+2] and the favored interdimer adsorbed structures corroborate our proposed mixed domain model. 相似文献
27.
Pal R Yang M Lin R Johnson BN Srivastava N Razzacki SZ Chomistek KJ Heldsinger DC Haque RM Ugaz VM Thwar PK Chen Z Alfano K Yim MB Krishnan M Fuller AO Larson RG Burke DT Burns MA 《Lab on a chip》2005,5(10):1024-1032
An integrated microfluidic device capable of performing a variety of genetic assays has been developed as a step towards building systems for widespread dissemination. The device integrates fluidic and thermal components such as heaters, temperature sensors, and addressable valves to control two nanoliter reactors in series followed by an electrophoretic separation. This combination of components is suitable for a variety of genetic analyses. As an example, we have successfully identified sequence-specific hemagglutinin A subtype for the A/LA/1/87 strain of influenza virus. The device uses a compact design and mass production technologies, making it an attractive platform for a variety of widely disseminated applications. 相似文献
28.
J. K. Srivastava G. Jéhanno K. Muraleedharan J. A. Kulkarni V. R. Marathe V. S. Darshane R. Vijayaraghavan 《Hyperfine Interactions》1986,28(1-4):519-523
Mössbauer measurements in mixed spinel ferrite Gax Fe1–x Ni Cr O4 (0x0.8), carried out between 4.2 and 298°K, show the presence of entropic spins in this system. Recent Monte Carlo calculations /4/ have predicted the presence of such spins in a frustrated spin glass lattice. 相似文献
29.
R. K. Nigam B. P. Hajela S. Sengupta B. C. Srivastava K. M. Gupta 《Hyperfine Interactions》1986,28(1-4):935-939
The effect of pigments on the development of corrosion products between the painting system and metal surface when exposed to marine environments has been discussed. The pigments studied were; Red Mud Zinc chromate, Zinc chromate, Red oxide Zinc Phosphate, Manganese Phosphate Barium chromate and Basic Lead Silico Chromate. Mossbauer Spectroscopy revealed that the upper rust layer in all the cases consisted of-Fe203,-FeOOH and-FeOOH. The lower rust layer immediately in contact with the metal surface consisted of an asymmetrical doublet due to -FeOOH. 相似文献
30.
T. N. Srivastava R. C. Srivastava Mala Singh 《Journal of organometallic chemistry》1978,160(2):449-454
Iodine monohalides (ICl, IBr), cyanogen halides (CNBr, CNI) and thiocyanogen (SCN)2 add oxidatively to diaryltellurium(II), R2Te (R = Ph, p-Ch3OC6H4) under mild conditions (
°C). The resulting organotellurium(IV) derivatives react metathetically with silver pseudohalides to yield several new diaryltellurium(IV) pseudohalide derivatives. 相似文献