全文获取类型
收费全文 | 3188篇 |
免费 | 563篇 |
国内免费 | 671篇 |
专业分类
化学 | 1745篇 |
晶体学 | 92篇 |
力学 | 77篇 |
综合类 | 28篇 |
数学 | 259篇 |
物理学 | 849篇 |
无线电 | 1372篇 |
出版年
2024年 | 16篇 |
2023年 | 52篇 |
2022年 | 108篇 |
2021年 | 103篇 |
2020年 | 116篇 |
2019年 | 109篇 |
2018年 | 93篇 |
2017年 | 130篇 |
2016年 | 118篇 |
2015年 | 160篇 |
2014年 | 154篇 |
2013年 | 223篇 |
2012年 | 272篇 |
2011年 | 247篇 |
2010年 | 235篇 |
2009年 | 304篇 |
2008年 | 282篇 |
2007年 | 278篇 |
2006年 | 268篇 |
2005年 | 238篇 |
2004年 | 154篇 |
2003年 | 132篇 |
2002年 | 124篇 |
2001年 | 112篇 |
2000年 | 99篇 |
1999年 | 62篇 |
1998年 | 34篇 |
1997年 | 23篇 |
1996年 | 30篇 |
1995年 | 17篇 |
1994年 | 19篇 |
1993年 | 16篇 |
1992年 | 19篇 |
1991年 | 16篇 |
1990年 | 15篇 |
1989年 | 7篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 9篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有4422条查询结果,搜索用时 406 毫秒
41.
IntroductionRecently ,thecompoundscontaining 1H 1,2 ,4 tria zolegrouphaveattractedmuchinterestbecausetheyex hibitsomefungicidalactivity ,plantgrowthregulatingac tivity ,1antibacterialactivityagainstPucciniareconditeandrootsgrowthregulationforcucumber .2 Also ,suchcom poundsareincreasinglybeingstudiedbecauseofthecoor dinationchemistryoftriazolesactingasligandsintransi tionmetalcompounds .Asamatteroffact ,thetriazolederivativeshavebeenextensivelyusedasterminalandbridgingligands ,andtheyleadto… 相似文献
42.
HanMingDING LiPingWANG YongKuiSHAN MingYuanHE 《中国化学快报》2003,14(8):852-855
Deposition of inorganic-organic nano-hybrid ultrathin films onto mesoporous silicate materials has been proven possible by using layer-by-layer assembly method. In combination with sol-gel method, titania, subsequently dye molecules (or polymer) were successfully fabricated onto the inner wall of SBA-15. Their structures were preliminarily characterized by FTIR and solid-state UV-Vis spectroscopy, thermal analysis, and BET surface area measurements,respectively. 相似文献
43.
44.
45.
Li J Hong X Li D Zhao K Wang L Wang H Du Z Li J Bai Y Li T 《Chemical communications (Cambridge, England)》2004,(15):1740-1741
Highly luminescent water-soluble CdTe nanorods were prepared with the assistance of the mixed ligand system of cysteine and thioglycolic acid; the aspect ratio and photoluminescence of the CdTe nanorods could be controlled by the refluxing time. 相似文献
46.
用高效疏水色谱法对多种脲变α-淀粉酶折叠中间体的研究 总被引:1,自引:0,他引:1
用高效疏水色谱法对用脲变性的α-淀粉酶的体外折叠中间体进行了分离,发现脲变α-淀粉酶折叠至少有19个中间体,而且,这些中间体在色谱流出液中可稳定一周.这一结论已由电泳、离子交换色谱和体积排阻色谱法证实.此外,还用紫外吸收光谱和荧光发射光谱研究了这些折叠中间体与天然α-淀粉酶构象之间的差异. 相似文献
47.
Several novel N′-[(1-ferrocenylethylidene)amino]-N′-β-D-glycopyranosylthioureas have been efficiently synthesized via a six-step procedure, utilizing three monosaccharides (D-glucose, D-galactose and D-xylose) as starting materials, respectively. They have been preliminarily determined to display biological activity against certain fungi. The target compounds have been unambiguously characterized by spectroscopic method and elemental analysis. An initially alternative synthetic route, which was seemingly reasonable, has been excluded due to its inefficiency. 相似文献
48.
Developing low-cost but efficient hydrogen evolution reaction(HER)electrocatalysts over whole pH values is a significant but daunting task for the large-scale application of electrochemical hydrogen production.Herein,we develop,for the first time,a scalable MOF-assisted strategy for the fabrication and microstructural optimization of multi-shelled hollow N-doped carbon nanosheet arrays with confined Co/CoP heterostructures on carbon cloth(Co/CoP@NC/CC)for boosting HER performances.The key to this strategy is the step-by-step epitaxial growth of unprecedented multilayer ZIF-L arrays on carbon cloth,which are subsequently pyrolyzed and controllably phosphorized to achieve the precise control over the shell number and nanoarchitectures of the Co/CoP@NC/CC.Impressively,the HER performances can be significantly enhanced by increasing hollow shell number,and the optimal triple-shelled hollow Co/CoP@NC/CC exhibits low overpotentials of 86,78 and 145 mV in acidic,alkaline and neutral media to deliver a current density of 10 mA cm-2,respectively,ranking as one of the best Co-based HER electrocatalysts over whole pH values.Further DFT calculations suggest that the Co/CoP heterostructures can effectively boost the cleavage of H–OH to generate protons and optimize the adsorption energy of hydrogen(ΔGH*),which,together with the large electrode/electrolyte interface and accelerated charge/mass transfer of multi-shelled hollow array structure as well as the good conductivity and dispersity,are responsible for the remarkably improved HER performances.This study not only provides a new toolbox for enriching the family of multi-shelled nanoarchitecture materials,but also points out a general and effective route to develop highly efficient self-supported electrode materials for energy-related applications and beyond. 相似文献
49.
50.
With the assistance of HPLC-ESI-MS/MS, the self-assembly products of serine and histidine penta-coordinated phosphorus compound were separated and identified. The expectative product was seryl-histidine dipeptide, but it was found that there was almost equimolar amount of histidyl-histidine dipeptide as well as seryl-histidine dipeptide. The mechanism was speculated that there was iigand exchange between penta-coordinated phosphoryl serine and histidine in the reaction process. As a result,two types of dipeptide were produced. 相似文献