瞬态荧光方法研究溶剂诱导的三苯胺衍生物的对称性破缺电荷转移动力学

在缺乏特征红外振动的情况下追踪具有四极或八极对称性分子的激发态对称性破缺电荷转移通常是很困难的.本文以一种具有八极对称性的三苯胺衍生物为研究对象,利用飞秒时间分辨瞬态荧光光谱方法获得发光跃迁偶极矩的演化动力学,进而实时表征了其溶剂诱导对称性破缺电荷转移的动力学过程.当该分子处于弱极性甲苯溶液中时,在激发态弛豫过程中其发射偶极矩变化较小;当处于较强极性的四氢呋喃溶液中时,其发射偶极矩在数皮秒内快速减小.在对比单体偶极分子的荧光动力学后,推断八极分子的发光态在强极性溶剂中经历溶剂诱导的结构变化,由激子耦合的八极对称性降低至激发定域的偶极对称性;而在较弱极性的溶剂中,其八极对称性在溶剂化稳定中得以较大程度的保持.     

一种新型二元判定图器件和电路

提出了一种基于二元判定图(BDD)原理的新型逻辑器件和电路．BDD器件以电流模式的开关电流存储器为基本单元，具有符合二元判定图的两向通路的特点．用这种器件按照BDD树形图可以构成任意形式的组合逻辑电路．给出了或门、异或门及四位加法器电路的例子，并使用HSPICE仿真器进行了仿真，验证了这种器件及其电路的正确性．     

边境地区广播电视信号收测研究

无线电频率是宝贵的资源,然而由于“模数同播”和与邻国频率共享等原因,边境地区省份的广播电视频率资源格外紧张.通过开展中俄边境地区广播电视信号收测工作,不但可以掌握无线广播电视频谱的实际使用情况,而且能为边境地区的频率协调工作提供有力的数据支撑.本文详细介绍了中俄边境地区广播电视信号收测工作,并对测试结果进行了分析和总结,对于今后的边境地区广播电视信号收测工作起到示范作用.     

中央广播电视节目无线数字化覆盖工程DTMB频率规划及补点频率方案

由国家新闻出版广电总局牵头组织,和全国各省局配合实施的中央广播电视节目无线数字化覆盖工程标志着我国正式步入了地面数字电视的大规模推广阶段.本文针对覆盖工程中DTMB覆盖网络频率规划策略,频率规划原则、频率规划及补点频率方案展开了系统分析,为全国各级广电部门开展DMTB频率规划工作提供技术参考.     

机载预警雷达天线发展趋势及关键技术

综合性预警探测多功能一体化系统是下一代机载预警雷达的一种必然趋势,它要求天线阵面具备多功能、与平台一体化的特征,实现超宽带、多频段性能,并能在硬件资源上支撑数字智能化的系统体系架构。文中首先分析了机载预警雷达天线阵面的发展趋势和国内外研究现状,继而分析了目前机载预警雷达天线系统的关键技术,阐述了相应的技术实施途径和核心问题,提出部分解决方案。     

微波萃取–高效液相色谱荧光检测法测定食品包装用纸中11种荧光增白剂

采用微波萃取高效液相色谱荧光检测法测定食品包装用纸中11种荧光增白剂含量.将样品剪成约0.5 cm×0.5 cm的碎片,用体积分数为40％的乙腈水溶液(含体积分数为0.6％的三乙胺),于80℃微波萃取15 min,用高效液相色谱仪进行定性定量分析.采用Kromasil 100–5型C18柱(250 mm×4.6 mm,5μm)作为分析柱,荧光激发波长为362 nm,发射波长为410 nm,11种荧光增白剂可以较好的分离.11种荧光增白剂质量浓度线性范围为2～150μg/L,相关系数均不小于0.9996,方法检出限为0.1～0.2 mg/kg,定量限为0.3～0.6 mg/kg.样品加标平均回收率为86.0％～108.4％,相对标准偏差为0.4％～4.9％(n=6).该方法前处理简便,检测高效,灵敏度高.     

Supramolecular Engineering Strategy to Construct BODIPY-Based White Light Emission Materials

Two kinds of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyads BDP-OH containing 4-hydroxystyrene groups and BDP-PY bearing pyridinyl units were prepared. In addition, a naphthalene derivative NAP-PY modified by pyridinyl moieties substituent was made. The above three dyads could be used to construct white-light emission (WLE) material by a supramolecular engineering strategy due to their three primary colors of blue, green and red. The supramolecular correlations between the hydroxyl group of BDP-OH and the pyridinyl groups of NAP-PY and BDP-PY were confirmed by ¹H NMR titration, 2D NOESY and FTIR. A fluorescence monitor application was carried out based on the realization of WLE. This work might be useful for designing other WLE supramolecular systems and image display.     

溶胶-凝胶法制备Pb(Zr1?xTix)O3复合梯度薄摸以及介电与热释电特性

"在Pt/Ti/SiO2/Si基片上用溶胶-凝胶法生长制备了PZT(Pb(Zr1-xTix)O3)复合梯度铁电薄膜． 薄膜最终结构由6层组成,"向上"梯度薄膜在Pt底电极上的第一层从PbZrO3开始,顶层是PZT(50/50),即第一层是PbZrO3,第二层PZT90/10 (10%Ti),第三层是PZT80/20,第四层PZT70/30,第五层PZT60/40,第六层PZT50/50．每一层与此相反的是"向下"梯度PZT薄膜．用X射线衍射、俄歇电子能谱和阻抗分析来研究梯度薄膜的结构与介电特性．600     

Pyrolysis and combustion model of oil sands from non-isothermal thermogravimetric analysis data

Thermogravimetric (TG) data of oil sand obtained at Engineering Research Center of Oil Shale Comprehensive Utilization were studied to evaluate the kinetic parameters for Indonesian oil sand samples. Experiments were carried out at heating rates of 5, 15, and 25 °C min^?1 in nitrogen, 10, 20, and 50 °C min^?1 in oxygen atmosphere, respectively. The extent of char combustion was found out by relating TG data for pyrolysis and combustion with the ultimate analysis. Due to distinct behavior of oil shale during pyrolysis, TG curves were divided into three separate events: moisture release, devolatilization, and evolution of fixed carbon/char, where for each event, kinetic parameters, based on Arrhenius theory, were calculated. Coats–Redfern method, Flynn–Wall–Ozawa method, and distributed activation energy model method have been used to determine the activation energies of degradation. The methods are compared with regard to their characteristics and the ease of interpretation of the thermal kinetics. Activation energies of the samples were determined by three different methods and the results are discussed.