首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   27855篇
  免费   4187篇
  国内免费   3847篇
化学   15498篇
晶体学   350篇
力学   949篇
综合类   247篇
数学   2216篇
物理学   6807篇
无线电   9822篇
  2024年   74篇
  2023年   583篇
  2022年   755篇
  2021年   1005篇
  2020年   1024篇
  2019年   971篇
  2018年   892篇
  2017年   914篇
  2016年   1134篇
  2015年   1312篇
  2014年   1587篇
  2013年   2043篇
  2012年   2378篇
  2011年   2443篇
  2010年   2038篇
  2009年   1876篇
  2008年   2065篇
  2007年   1927篇
  2006年   1709篇
  2005年   1419篇
  2004年   1076篇
  2003年   968篇
  2002年   910篇
  2001年   809篇
  2000年   671篇
  1999年   521篇
  1998年   383篇
  1997年   305篇
  1996年   350篇
  1995年   301篇
  1994年   216篇
  1993年   168篇
  1992年   147篇
  1991年   139篇
  1990年   137篇
  1989年   99篇
  1988年   68篇
  1987年   66篇
  1986年   46篇
  1985年   42篇
  1984年   28篇
  1983年   33篇
  1982年   31篇
  1981年   18篇
  1979年   32篇
  1978年   29篇
  1977年   18篇
  1976年   18篇
  1975年   21篇
  1973年   17篇
排序方式: 共有10000条查询结果,搜索用时 625 毫秒
61.
In this article we report the system structure and test results of an experimental optical burst switching network with three edge router's and one core node. Wavelength-selective switches developed for this system and their characteristics are depicted. The implementation and performance of our new scheme for the just-in-time protocol are described. We also report experimental results of FTP and VOD services on this system. Some parameters, including traffic rate, average burst data length, and assembly time, are studied.  相似文献   
62.
In the title compound, catena‐poly[lithium‐μ3‐ethyl­ene­diphos­phon­ato], [Li(C2H7O6P2)]n, the supra­molecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethyl­ene­diphosphon­ate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand.  相似文献   
63.
This letter presents an unconditionally stable alternating direction implicit finite-difference time-domain (ADI-FDTD) method with fourth order accuracy in time. Analytical proof of unconditional stability and detailed analysis of numerical dispersion are presented. Compared to second order ADI-FDTD and six-steps SS-FDTD, the fourth order ADI-FDTD generally achieves lower phase velocity error for sufficiently fine mesh. Using finer mesh gridding also reduces the phase velocity error floor, which dictates the accuracy limit due to spatial discretization errors when the time step size is reduced further.  相似文献   
64.
Symmetric interference in two-dimensional multimode silicon waveguides is experimentally investigated. For a 100/spl times/100 /spl mu/m/sup 2/ cross section, 2700-/spl mu/m-long waveguide fabricated on silicon-on-insulator substrate, an 8/spl times/8 matrix of replicated images with high contrast ratio is demonstrated for 1530-1570 nm wavelength range. Symmetric interference results in reduced device length, and the actual device length is consistent with the theoretical expectation. The device also exhibits stable imaging in terms of good loss uniformity, and low wavelength and polarization dependencies among the replicated images.  相似文献   
65.
There is growing interest in the use of lidar for remote sensing of vegetation owing to the emergence of reliable and rugged lasers and highly sensitive detectors. Lidar remote sensing has a distinct advantage over conventional techniques in vegetation remote sensing due to its capability for three-dimensional characterization of vegetative targets. The Multiwavelength Airborne Polarimetric Lidar (MAPL) system was developed primarily for vegetation remote sensing applications from an airborne platform of up to 1,000 -m altitude. The lidar system has full waveform capture and polarimetric measurement capability at two wavelengths in the near-infrared (1064 nm) and the green (532 nm) spectral regions. This study presents preliminary ground-based lidar reflectance measurements on a variety of deciduous and coniferous trees under fully foliated conditions with a view towards tree species discrimination. Variations in the reflectance characteristics of selected deciduous trees under unfoliated and fully foliated conditions were also investigated. Our study reveals distinct differences in the reflectance characteristics of various trees.  相似文献   
66.
Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003  相似文献   
67.
In mononuclear HgI2[(C5H4N)3N], mercury is tetrahedrally coordinated by two nitrogen atoms of a tris(2‐pyridyl)amine ligand and two iodides. The coordination moieties are connected by weak intermolecular Hg(II)···I interactions to give a one‐dimensional structure. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
68.
用PowerPoint制作出的幻灯片简洁明快、条理清晰,而且PowerPoint简单易用,非常适合教师上课使用,成为教师制作多媒体课件的工具之一(在我校大部分教师采用PowerPoint制作多媒体课件).在制作多媒体课件过程中,结合适当的媒体技术(动画、声音、文字)不仅能提高课件的直观生动性,激发学生学习兴趣,同时有助于学生对课堂知识的当堂消化和理解,加深记忆.通过我校开展多媒体教学多年的实践发现:对医科学生的基础课、专业基础课和专业课教学中广泛涉及的机能性、原理性的知识适当采用动画其教学效果是传统教学方法无法比拟的.在众多的动画媒体中(avi、mov、mpg、swf、gif、ram等),Flash动画(swf文件)以其作品容量小(单个swf文件通常不到100 K)、质量高和丰富的交互性,特别是近年推出的Flash5同时能结合视频和音频,成为目前最为流行的二维动画.不仅为网页制作增添了活力,同时也为多媒体制作提供了有效的手段,既精巧又实用,素有"闪客"、"动画精灵"之美誉,越来越受到人们的青睐.如果要把Flash制作好的动画插入到PowerPoint制作的课件中,将会使PowerPoint单调的动画增色不少,使课件更具魅力.为此,我校专门开展了一系列Flash动画制作讲座,广大教师都能结合本专业制作Flash动画.如何将Flash动画加入到PowerPoint中,不少教师都是直接通过"超级连接"导入Flash课件,放映时总会出现讨厌的警告信息和警告声音提示,点击确定后打开Flash课件,有时打开的Flash课件窗口还要重新调整,使用十分不便.如何才能更恰当地引入Flash动画呢?不少杂志刊物和网上发表过类似文章,但大都比较复杂,而且在使用中特别是在PowerPoint中放映Flash动画偶尔会出现这样和那样的问题,这也是我们教学工作中经常遇到的问题,具有一定的普遍性.经过与教师们的众多交流和笔者平时反复摸索,找到了较为简便有效的方法,写出来与大家分享.  相似文献   
69.
As artificial enzymes, the binding constants of cyclodextrins (CDs) and their substrates are expected to be high1. For this purpose, many kinds of bridged cyclodextrin dimers2 whose two cyclodextrins are linked by various spacers have been constructed. It was of interest to make the dimers, whose binding constants would exceed 108dm3/mol3. Up to date, the bridged cyclodextrin dimers have been extensively studied as enzyme models and as molecular receptors4-6. Recently, we synthesized a brid…  相似文献   
70.
The bulk polymerization of styrene initiated by ?‐caprolactam (CL) and n‐dodecyl mercaptan (RSH) has been explored. This novel polymerization system shows living characteristics. For example, the molecular weight of the resulting polymers increases with conversion, and the system has the ability to form diblock copolymers and so forth. The polymer chain end contains thiol and lactam structures, which we have investigated with Fourier transform infrared, 1H NMR, and 13C NMR techniques. Electron spin resonance spectra and theoretical calculations by the Hartree–Fock methods have been used to examine the mechanism. The results reveal that the initial polymerization starts from thiol via a chain‐transfer reaction, and the propagation proceeds by the insertion of a monomer between the terminal group and the intermediate structure of lactam. Finally, the polymerization kinetics have been examined. The polymerization rate varies linearly with the concentration of CL and RSH, and this confirms the mechanism. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4976–4993, 2004  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号