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Synergistic effect of cellulose nanowhiskers reinforcement and dicarboxylic acids crosslinking towards polyvinyl alcohol properties 下载免费PDF全文
Amit Kumar Sonker Naveen Tiwari Rajaram Krishna Nagarale Vivek Verma 《Journal of polymer science. Part A, Polymer chemistry》2016,54(16):2515-2525
In the presented work, a significant increase in the tensile strength of the PVA composite material is reported. The obtained best value of 122 MPa and 14.6% swelling shows the excellent synergistic effect of both crosslinker and reinforcement material. The composite films were prepared by simple mechanical dispersion of reinforcement material, bacterial cellulose nanowhiskers (BCNW) into PVA solution followed by crosslinking with diacids, succinic acid (SuA), and adipic acid (AdA). The effect of aliphatic carbon chain length of crosslinker on thermal, mechanical, and water uptake properties is evaluated and discussed in detail. Neat PVA had the strength of 37.3 MPa. With 5% reinforcement of BCNW, that is, without crosslinking, it exhibited 97% increase, that is, 74.5 MPa. With crosslinking of 15 mmol of SuA and AdA PVA films for 2 h had excellent thermal properties with swelling percentage of 19 and 26.6% and tensile strength of 103 and 67 MPa, respectively. The best result obtained was for 5% BCNW–PVA films crosslinked with 15 mmol SuA. These results were explained on the basis of synergetic crosslinking and extended hydrogen bonding between PVA and reinforcement material. The composite films can be used as biological implants, a membrane for pervaporation and filtration system, etc. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2515–2525 相似文献
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Manchuri Krishna Moorthy Shaik Mahammad Ali Gopireddy Venkata Subba Reddy 《Chromatographia》2022,85(2):137-146
Chromatographia - A selective and sensitive novel reverse-phase method was developed and validated successfully using waters acquity ultra-performance liquid chromatography H-class system coupled... 相似文献
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Scott R. Broderick Changwon Suh J Provine Christopher S. Roper Roya Maboudian Roger T. Howe Krishna Rajan 《Surface and interface analysis : SIA》2012,44(3):365-371
We have demonstrated an informatics methodology for finding correlations between the full profile Fourier transform infrared spectra of polycrystalline 3C‐silicon carbide (poly‐SiC) films and their growth conditions, thereby developing high‐throughput structure‐process relationships. Because SiC films are a structural element in photonic sensors, this paper focuses on the interpretation of their optical response, the multivariate tracking of critical processing pathways, and the identification of controlling processing mechanisms. Using principal component analysis, we have developed a data analysis tool to aid in the assessment of the relative contributions of experimental parameters in low‐pressure chemical vapor deposition processes to optical responses on the basis of the size of eigenvalues of the spectral data set. The applied methodology for identifying spectral relationships of stoichiometry, dopant chemistry, and microstructure of poly‐SiC provides more effective guidelines to manipulate optical responses by controlling multiple experimental parameters. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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A new one pot oxidative coupling of methyl arenes with cinnamic acids has been developed for the synthesis of α,β-epoxy ketones using MnO2/TBHP combination. The process involves a co-existing C(sp3)―H activation and decarboxylation under aqueous medium, which makes it practical and attractive. 相似文献
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