Anomalous thermal expansion of InSe layered semiconductors in the low-temperature region

The temperature dependence of the linear thermal expansion coefficient (TEC) of an InSe single crystal in the (001) plane is measured in the temperature range 7–50 K. A peak in the thermal expansion is detected near T = 10 K, after which the sample shrinks upon heating. The effect of an external magnetic field of up to 6 T, which is parallel to the (001) plane, on the TEC is investigated. The observed partial suppression of the peak and crystal compression by the field indicates the relation of these anomalies to possible electron ordering in InSe layers.     

Influence of the demagnetizing field on the structure of a Bloch wall in a (001) plate of a magnetically ordered cubic crystal

The planar Bloch wall is considered in an infinite (001) plate of a cubic crystal with a negative first magnetic anisotropy constant for various values of the ratio between the magnetocrystalline-anisotropy and demagnetization energy densities of the sample. The energy and structure of the Bloch wall are shown to depend on this ratio and on the orientation of a vector equal to the difference between the magnetization vectors of the neighboring domains.     

Hybrid Metal Halides with Multiple Photoluminescence Centers

Very little is known about the realm of solid‐state metal halide compounds comprising two or more halometalate anions. Such compounds would be of great interest if their optical and electronic properties could be rationally designed. Herein, we report a new example of metal halide cluster‐assembled compound (C₉NH₂₀)₉[Pb₃Br₁₁](MnBr₄)₂, featuring distinctly different anionic polyhedra, namely, a rare lead halide cluster [Pb₃Br₁₁]^5? and [MnBr₄]^2?. In accordance with its multinary zero‐dimensional (0D) structure, this compound is found to contain two distinct emission centers, 565 nm and 528 nm, resulting from the formation of self‐trapped excitons and ⁴T₁‐⁶A₁ transition of Mn²⁺ ions, respectively. Based on the high durability of (C₉NH₂₀)₉[Pb₃Br₁₁](MnBr₄)₂ upon light and heat, as well as high photoluminescence quantum yield (PLQY) of 49.8 % under 450 nm blue light excitation, white light‐emitting diodes (WLEDs) are fabricated, showcasing its potential in backlight application.     

Zinc and Cobalt Aqua Complexes with Cucurbit[6]uril: Syntheses and Crystal Structures

Russian Journal of Coordination Chemistry - Supramolecular complexes [Zn(H2O)4(C36H36N24O12)](NO3)2 · 6.5H2O (I), [Zn(H2O)4-(C36H36N24O12)](NO3)2 · 7H2O (II), and...     

Electronic absorption spectrum of Cs<Subscript>2</Subscript>ZnI<Subscript>4</Subscript> thin films

The absorption spectrum of Cs₂ZnI₄ thin films in the energy range 3–6 eV at temperatures from 90 to 340 K has been investigated. It is established that this compound belongs to direct-gap insulators. Low-frequency exciton excitations are localized in ZnI₄ structural elements of the lattice. Phase transitions at 280 K (paraelectric phase ? incommensurate phase), 135 K (incommensurate phase ? monoclinic ferroelastic phase), and 96 K (monoclinic phase ? triclinic ferroelastic phase) have been found from the temperature dependences of the spectral position and halfwidth of the low-frequency exciton band. Additional broadening of the exciton band is observed for ferroelastic phases; it is likely to be due to exciton scattering from strain fluctuations near domain walls.     

Supramolecular chemistry of macrocyclic cavitand cucurbit[7]uril with isoleucine

Russian Chemical Bulletin - The l-isoleucine — cucurbit[7]uril system in solution was studied at various concentrations by NMR spectroscopy. The 1H NMR spectra of the L-isoleucine complex...     

Thermal expansion of niobium diselenide in the basal plane at low temperatures

The thermal expansion of a high-quality 2H-NbSe₂ single crystal is precisely measured in the basal plane and the temperature range 5.7–50 K. An anomaly of the thermal expansion in the basal plane is detected, and it is found to be caused by a superconducting transition. The change in thermal expansion coefficient α _ab is used to calculate the pressure derivative of the critical temperature (dT _c /dp _ab ) = (19.0 ± 2.0) × 10^?9 K/Pa, and this derivative agrees well with the reported data. An additional anomaly, which indicates a phase transition, is also detected in the pretransition range. The nature of the detected phase transition is discussed.     

Structure of Water Microemulsion Particles: Study by Optical Methods

Physics of Wave Phenomena - It is shown by optical methods using light scattering intensity and shift of the stimulated low- frequency Raman scattering line that emulsion particles of the Emulson...     

Highly Emissive Self‐Trapped Excitons in Fully Inorganic Zero‐Dimensional Tin Halides

The spatial localization of charge carriers to promote the formation of bound excitons and concomitantly enhance radiative recombination has long been a goal for luminescent semiconductors. Zero‐dimensional materials structurally impose carrier localization and result in the formation of localized Frenkel excitons. Now the fully inorganic, perovskite‐derived zero‐dimensional Sn^II material Cs₄SnBr₆ is presented that exhibits room‐temperature broad‐band photoluminescence centered at 540 nm with a quantum yield (QY) of 15±5 %. A series of analogous compositions following the general formula Cs_4?xA_xSn(Br_1?yI_y)₆ (A=Rb, K; x≤1, y≤1) can be prepared. The emission of these materials ranges from 500 nm to 620 nm with the possibility to compositionally tune the Stokes shift and the self‐trapped exciton emission bands.