Size-selected Ni catalyst islands for single-walled carbon nanotube arrays

Many properties of single-walled carbon nanotube (SWCNT) arrays are determined by the size and surface coverage of the metal catalyst islands from which they are nucleated. Methods using thermal fragmentation of continuous metal films frequently fail to produce size-uniform islands. Hybrid numerical simulations are used to propose a new approach to controlled self-assembly of Ni islands of the required size and surface coverage using tailored gas-phase generated nanocluster fluxes and adjusted surface temperatures. It is shown that a maximum surface coverage of 0.359 by 0.96–1.02 nm Ni catalyst islands can be achieved at a low surface temperature of 500 K. Optimized growth of Ni catalyst islands can lead to fabrication of size-uniform SWCNT arrays, suitable for numerous nanoelectronic applications. This approach is deterministic and is applicable to a range of nanoassemblies where high surface coverage and island size uniformity are required.

     

Development of the Strategy of Active Control of Instability Waves in Unexcited Turbulent Jets

The possibility of controlling instability waves in the mixing layer of a subsonic unexcited jet is studied. These waves can be noise sources in both free jets and jets as parts of configurations. In the study the method of experimental diagnostics of the instability waves in the near field of a jet using an azimuthal multimicrophone array is realized. The data on the near field fluctuations are used for testing the control strategy proposed by the authors. The strategy consists in narrowband sliding filtration of the original signal and the formation of a narrowband controlling action on the basis of the linear principle of signal superposition. The results of the study represent the next step toward the realization of an active control system suppressing natural instability waves in turbulent jets.     

Cancer‐Targeting Graphene Quantum Dots: Fluorescence Quantum Yields,Stability, and Cell Selectivity

Folic acid, due to its high affinity toward folate receptors (FR), is recognized as one of the most promising cancer targeting vectors. However, the inherent defects of low water solubility (1.6 µg mL^?1), high sensitivity toward photo‐bleaching, low fluorescent quantum yields (QYs, <0.5%) seriously limit its practical application. Herein, ultrastable, highly luminescent graphene quantum dots (GQDs) that selectively target diverse cancer cells are prepared and tested. The new GQDs present step changes compared to common folic acid through an ≈6250 times increase in water solubility (to ≈10 mg mL^?1), more than 150 times in QYs (up to ≈77%), while maintaining luminescence stability up to 98% when subjected to UV, visible light, and heating over 360 min. It is shown that the suppression of nonradiative transitions by amino groups pyrolyzed from pterin plays a key role in the mechanism of high QYs and excellent stability. The functional groups that are likely responsible for the selective targeting of cancer cells with different levels of folate receptor expression on the surface are identified. Collectively with these promising properties, the new functional graphene quantum dots may open a new avenue for cancer diagnosis, drug delivery, and therapies.     

Multidimensional Continued Fractions,Dynamical Renormalization and KAM Theory

The disadvantage of ‘traditional’ multidimensional continued fraction algorithms is that it is not known whether they provide simultaneous rational approximations for generic vectors. Following ideas of Dani, Lagarias and Kleinbock-Margulis we describe a simple algorithm based on the dynamics of flows on the homogeneous space (the space of lattices of covolume one) that indeed yields best possible approximations to any irrational vector. The algorithm is ideally suited for a number of dynamical applications that involve small divisor problems. As an example, we explicitly construct a renormalization scheme for the linearization of vector fields on tori of arbitrary dimension.     

A quantification of the interaction and spatial ordering in nano-arrays

This paper reports on the use of a local order measure to quantify the spatial ordering of a quantum dot array (QDA). By means of electron ground state energy analysis in a quantum dot pair, it is demonstrated that the length scale required for such a measure to characterize the opto-electronic properties of a QDA is of the order of a few QD radii. Therefore, as local order is the primary factor that affects the opto-electronic properties of an array of quantum dots of homogeneous size, this order was quantified through using the standard deviation of the nearest neighbor distances of the quantum dot ensemble. The local order measure is successfully applied to quantify spatial order in a range of experimentally synthesized and numerically generated arrays of nanoparticles. This measure is not limited to QDAs and has wide ranging applications in characterizing order in dense arrays of nanostructures.     

Aluminum-assisted crystallization and <Emphasis Type="Italic">p</Emphasis>-type doping of polycrystalline Si

Aluminum-doped p-type polycrystalline silicon thin films have been synthesized on glass substrates using an aluminum target in a reactive SiH₄+Ar+H₂ gas mixture at a low substrate temperature of 300 °C through inductively coupled plasma-assisted RF magnetron sputtering. In this process, it is possible to simultaneously co-deposit Si–Al in one layer for crystallization of amorphous silicon, in contrast to the conventional techniques where alternating metal and amorphous Si layers are deposited. The effect of aluminum target power on the structural and electrical properties of polycrystalline Si films is analyzed by X-ray diffraction, Raman spectroscopy, scanning electron microscopy and Hall-effect analysis. It is shown that at an aluminum target power of 100 W, the polycrystalline Si film features a high crystalline fraction of 91%, a vertically aligned columnar structure, a sheet resistance of 20.2 kΩ/□ and a hole concentration of 6.3×10¹⁸ cm⁻³. The underlying mechanism for achieving the semiconductor-quality polycrystalline silicon thin films at a low substrate temperature of 300 °C is proposed.     

A method for computing the stress fields in a deformable elastic half-space with a polysynthetic twin near the surface

The problem of computing the stress fields around a polysynthetic twin near the surface under the action of a lumped or distributed load on the boundary of an elastic half-space is solved without using the thin twin approximation. It is found that the action of external stresses leads to the stress redistribution such that the stress localization is observed not only in the region of the external load action but also far from the vertices of the twins of the polysynthetic twin.     

Sound radiation by distributed quadrupole sources near rigid bodies

An approach is proposed to describe the multipole structure of the sound field radiated as a turbulent jet streamlines a transverse circular cylinder of small diameter, which makes it possible to study the experimentally revealed effect of the dipole radiation shift. It is shown that different methods of acoustic measurements can lead to different determinations of the dipole radiation shift. It is demonstrated that to correctly describe the effect of the dipole radiation shift it is necessary to take into account the phase characteristics of different sources in the field of a turbulent flow; i.e., taking into account the state of distribution of the source is of fundamental importance for calculating the dipole radiation shift.     

Dislocation model for an incoherent nonthin twin

A condition for the equilibrium of a nonthin twin is obtained from a dislocation model using the approximation of a continuous distribution of twinning dislocations at twin boundaries. The model of a nonthin twin is shown to be applicable to the elastic and inelastic stages of twinning. The theory of a thin twin is found to be a particular case of the developed dislocation model of a nonthin twin.     

Self-organized Au nanoarrays on vertical graphenes: an advanced three-dimensional sensing platform

A three-dimensional surface enhanced Raman scattering (SERS)/plasmonic sensing platform based on plasma-enabled, catalyst-free, few-layer vertical graphenes decorated with self-organized Au nanoparticle arrays is demonstrated. This platform is viable for multiple species detection and overcomes several limitations of two-dimensional sensors.