Determination of mechanical properties of historical paper based on NIR spectroscopy and chemometrics – a new instrument

Due to sampling restrictions in the analysis of cultural heritage materials, non-destructive approaches are intensively sought for. While NIR spectrometry has rarely been used for this purpose due to the complexity of the spectra, chemometric methods can be used to extract the necessary information. For the purpose of determination of mechanical properties of historical paper, partial least squares approach was used and it is shown that tensile strength, and tensile strength after folding, can be estimated based on NIR spectra. As the mechanical properties of paper-based objects define their accessibility, a new dispersive portable instrument was built, which will enable us to rapidly survey the condition of library and archival collections. PACS  82.80.Gk; 28.52.Fa; 28.52.Lf     

Complexes of DOTA-bisphosphonate conjugates: probes for determination of adsorption capacity and affinity constants of hydroxyapatite

The adsorption on hydroxyapatite of three conjugates of a bisphosphonate and a macrocycle having C1, C2, and C3 spacers and their terbium complexes was studied by the radiotracer method using 160Tb as the label. The radiotracer-containing complex of the conjugate with the C3 spacer was used as a probe for the determination of the adsorption parameters of other bisphosphonates that lack a DOTA unit. A physicochemical model describing the competitive adsorption was successfully applied in the fitting of the obtained data. The maximum adsorption capacity of bisphosphonates containing bulky substituents is determined mainly by their size. For bisphosphonates having no DOTA moiety, the maximum adsorption capacity is determined by the electrostatic repulsion between negatively charged bisphosphonate groups. Compounds with a hydroxy or amino group attached to the alpha-carbon atom show higher affinities. Macrocyclic compounds containing a short spacer between the different bisphosphonic acid groups and the macrocyclic unit exhibit high affinities, indicating a synergic effect of the bisphosphonic and the macrocyclic groups during adsorption. The competition method described uses a well-characterized complex and allows a simple evaluation of the adsorption behavior of bisphosphonates. The application of the macrocycle-bisphosphonate conjugates allows easy radiolabeling via complexation of a suitable metal isotope.     

A 4.0 GHz 291 Mb Voltage-Scalable SRAM Design in a 32 nm High-k + Metal-Gate CMOS Technology With Integrated Power Management

This paper introduces a high-performance voltage-scalable SRAM design in a 32 nm strain-enhanced high-k + metal-gate logic CMOS technology. The 291 Mb SRAM design features a 0.171 ?m² six-transistor bitcell that supports a broad range of operating voltages for low-power and high-frequency embedded applications. The tileable 128 kb SRAM subarray achieves 72% array efficiency with 4.2 Mb/mm² bit density, and consumes 5 mW of leakage power at the supply voltage of 1 V. The design provides 4 GHz and 2 GHz of operating frequencies at the supply voltages of 1.0 V and 0.8 V, respectively. The integrated power management scheme features close-loop memory array leakage control, floating bitline, and wordline driver sleep transistor, resulting in a 58% reduction in subarray leakage power consumption.     

Phase relations in the system Bi2O3CdO

Phase relations in the system Bi₂O₃CdO were studied in the composition range from 90-30 mole% Bi₂O₃. A new phase, Bi₂O₃ · CdO, was found to exist up to 925 K. At this temperature it decomposes to form CdO and the 5Bi₂O₃ · 3CdO phase. The 5Bi₂O₃ · 3CdO phase is stable between 925 and 963 K and melts incongruently. Below 925 K it decomposes to Bi₂O₃ · CdO and 6Bi₂O₃ · CdO. The phase 5Bi₂O₃ · 3CdO has cubic symmetry. The Sillenite-type bcc phase 6Bi₂O₃ · CdO forms above 897 K from oxide mixtures in the solid state or from fused oxide mixtures, but the compound could never be prepared as a single phase.     

Transformations of the pyrido[1,2-a]pyrazine ring system into imidazo[1,2-a]pyridines,imidazo[1,2-a]pyrimidines and 2-oxa-6a, 10c-diazaaceanthrylenes

Transformations of methyl 3-dimethylamino-2-(1-methoxycarbonyl-4-oxo-4H-pyrido[1,2-a]pyrazin-3-yl)acrylate with some cyanomethylenecarbonyl group containing compounds or cyanamide into imidazo-[1,2-a]pyridines, irmdazo[1,2-a]pyrimidines and 2-oxa-6a, 10c-diazaaceanthrylenes are described.     

A novel three-phase utility interface minimizing line currentharmonics of high-power telecommunications rectifier modules

Based on the combination of a three-phase diode bridge and a DC/DC boost converter, a new three-phase three-switch three-level pulsewidth modulated (PWM) rectifier system is developed. It can be characterized by sinusoidal mains current consumption, controlled output voltage, and low-blocking voltage stress on the power transistors. The application could be, e.g., for feeding the DC link of a telecommunications power supply module. The stationary operational behavior, the control of the mains currents, and the control of the output voltage are analyzed. Finally, the stresses on the system components are determined by digital simulation and compared to the stresses in a conventional six-switch two-level PWM rectifier system