全文获取类型
收费全文 | 490篇 |
免费 | 20篇 |
国内免费 | 14篇 |
专业分类
化学 | 342篇 |
晶体学 | 4篇 |
力学 | 3篇 |
数学 | 6篇 |
物理学 | 114篇 |
无线电 | 55篇 |
出版年
2022年 | 3篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 8篇 |
2016年 | 7篇 |
2015年 | 9篇 |
2014年 | 7篇 |
2013年 | 29篇 |
2012年 | 15篇 |
2011年 | 26篇 |
2010年 | 11篇 |
2009年 | 10篇 |
2008年 | 26篇 |
2007年 | 19篇 |
2006年 | 22篇 |
2005年 | 28篇 |
2004年 | 14篇 |
2003年 | 14篇 |
2002年 | 14篇 |
2001年 | 11篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1993年 | 5篇 |
1992年 | 14篇 |
1991年 | 8篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1985年 | 8篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 12篇 |
1981年 | 7篇 |
1980年 | 12篇 |
1979年 | 9篇 |
1978年 | 7篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 8篇 |
1974年 | 8篇 |
1973年 | 4篇 |
1972年 | 5篇 |
1971年 | 3篇 |
1970年 | 6篇 |
1968年 | 4篇 |
排序方式: 共有524条查询结果,搜索用时 489 毫秒
21.
Nitration of aromatic halides proceeded smoothly in the presence of catalytic amounts of Cu bronze and N,N′-dimethylethylenediamine. Sodium nitrite-18-crown-6, or tetra-n-butylammonium nitrite (n-Bu4NNO2) turned out to be efficient nitrating agents. The aromatic nitro compounds were synthesized under essentially neutral conditions. 相似文献
22.
McFarland KS Naples D Arroyo CG Auchincloss P de Barbaro P Bazarko AO Bernstein RH Bodek A Bolton T Budd H Conrad J Drucker RB Harris DA Johnson RA Kim JH King BJ Kinnel T Koizumi G Koutsoliotas S Lamm MJ Lefmann WC Marsh W McNulty C Mishra SR Nienaber P Nussbaum M Oreglia MJ Perera L Quintas PZ Romosan A Sakumoto WK Schumm BA Sciulli FJ Seligman WG Shaevitz MH Smith WH Spentzouris P Steiner R Stern EG Vakili M Yang UK 《Physical review letters》1995,75(22):3993-3996
23.
Zilong Zhang Wen Zhao Guo Chen Masaya Toda Satoshi Koizumi Yasuo Koide Meiyong Liao 《Advanced functional materials》2023,33(27):2300805
Electrically integrable, high-sensitivity, and high-reliability magnetic sensors are not yet realized at high temperatures (500 °C). In this study, an integrated on-chip single-crystal diamond (SCD) micro-electromechanical system (MEMS) magnetic transducer is demonstrated by coupling SCD with a large magnetostrictive FeGa film. The FeGa film is multifunctionalized to actuate the resonator, self-sense the external magnetic field, and electrically readout the resonance signal. The on-chip SCD MEMS transducer shows a high sensitivity of 3.2 Hz mT−1 from room temperature to 500 °C and a low noise level of 9.45 nT Hz−1/2 up to 300 °C. The minimum fluctuation of the resonance frequency is 1.9 × 10−6 at room temperature and 2.3 × 10−6 at 300 °C. An SCD MEMS resonator array with parallel electric readout is subsequently achieved, thus providing a basis for the development of magnetic image sensors. The present study facilitates the development of highly integrated on-chip MEMS resonator transducers with high performance and high thermal stability. 相似文献
24.
Akimoto Tachibana Masahiko Koizumi Iwao Okazaki Hiroyuki Teramae Tokio Yamabe 《Theoretical chemistry accounts》1987,71(1):7-19
The non- and fluorine-substituted singlet carbonyl ylides are studied by using ab initio MCSCF calculations. The thermodynamic stability of the carbonyl ylides and the intramolecular stability to isomerization or fragmentation reaction coordinates is demonstrated in terms of the topological structure of the ab initio potential energy surfaces. The allylic resonance is found to be dynamically unstable, considering out-of-plane vibrational mode. The instability is studied by the symmetries of the low-lying excitations out of the MCSCF wave function. 相似文献
25.
26.
27.
Ikuta A Mizuta N Kitahata S Murata T Usui T Koizumi K Tanimoto T 《Chemical & pharmaceutical bulletin》2004,52(1):51-56
Six novel branched beta-cyclodextrins (betaCDs) having beta-D-galactose residues on the non-reducing terminal of the sugar side chains, namely 6(1),6(4)-di-O-(beta-D-galactosyl)-betaCD (10), 6-O-(beta-D-galactosyl)-betaCD (11), 6(1),6(4)-di-O-(beta-lactosyl)-betaCD (14), 6-O-(beta-lactosyl)-betaCD (15), 6(1),6(4)-di-O-(4'-O-beta-D-galactosyl-beta-lactosyl)-betaCD (18), and 6-O-(4'-O-beta-D-galactosyl-beta-lactosyl)-betaCD (19), were chemically synthesized using the trichloroacetimidate method. The reaction products were separated by HPLC on an amino column into dibranched and monobranched betaCDs. Their structures were confirmed by mass spectrometry (MS) and two-dimensional (2D) NMR spectroscopic analysis. To study the length of the sugar side chains attached to the CD ring, which leads to differences in the functions of the branched CDs, interactions of these compounds with peanut (Arachis hypogaea) agglutinin (PNA) were investigated using an optical biosensor and an inhibition assay based on hemagglutination. The results showed that all branched betaCDs interacted with PNA, and the binding affinity was 18>14>10 and 19>15>11 when the derivatives were compared on the basis of side chain length. 相似文献
28.
Yoshitsugu Arai Shū-ichi Kuwayama Yoshio Takeuchi Toru Koizumi 《Tetrahedron letters》1985,26(50):6205-6208
The Diels-Alder reaction of a novel chiral dienophile, alkyl ()-2--tolylsulfinylacrylates 1 with anthracene and cyclopentadiene showed high diastereoselectivity under the chelation controlled condition. 相似文献
29.
M. Yamanaka Y. Takeda S. Tanigawa A. Nishizawa N. Noda J. Fujita M. Takai M. Shimobayashi Y. Hayashi T. Koizumi K. Nagasaka S. Okajima Y. Tsunawaki A. Nagashima 《International Journal of Infrared and Millimeter Waves》1980,1(1):57-76
A twin optically-pumped far-infrared CH3OH laser has been constructed for use in plasma diagnostics. The antisymmetric doublet due to the Raman-type resonant two-photon transition is reproducibly observed at 118.8 m. With the 118.8-m line, it is obtained from the frequency separation of the anti-symmetric doublet that CH3OH absorption line center is 16±1 MHz higher than the pump 9.7-m P(36) CO2 laser line center. It is shown that the Raman-type resonant two-photon transition is useful in order to get several-MHz phase modulation for the far-infrared laser interferometer. Some preliminary performances of this twin laser for the modulated interferometer are described.This work was carried out under the collaborating research program at the Institute of Plasma Physics, Nagoya University, Nagoya 464, Japan. 相似文献
30.