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221.
222.
Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co+2FeII) and ferricyanides (Co+2FeIII) in an ozone flow. The CN stretching bands occur at 2085 cm–1 for Co+2FeII and at 2160 cm–1 for Co+2FeIII. After the ozonization process of Co+2FeII, an intense band approximately at 2125 cm–1 is detected. This intermediate band must correspond to a mixed valence state of the type: FeII–CN–Co2+–NC–FeIII Mössbauer spectra recorded in situ during the ozonization of Co+2FeII show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co+2FeII after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable. 相似文献
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In this note, we characterize the regular probability measures satisfying the Choquet-Deny convolution equation =* on Abelian topological semigroups for a given probability measure . 相似文献
225.
For eachd1 there is a constantc
d>0 such that any finite setXR
d contains a subsetYX, |Y|[1/4d(d+3)]+1 having the following property: ifEY is an ellipsoid, then |E X|c
d |X|.On leave from the Mathematical Institute of the Hungarian Academy of Sciences, 1364 Budapest, P.O. Box 127, Hungary. Supported by a research fellowship from the Science and Engineering Research Council, U.K., and by Hungarian National Foundation for Scientific Research Grant No. 1812. 相似文献
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A. Jánosi 《Zeitschrift für Physik B Condensed Matter》1990,80(3):393-400
We study the effects of some of the most important and typical structural changes in two-phase systems on selected structural parameters obtained from small-angle x-ray scattering (SAXS) measurements. To limit the present study, it was assumed that the Phase, 1, embedded in the matrix
- is monodispersed and homogeneous,
- possesses one of the three most extreme shapes (spherical, fibrillar or lamellar) and
- changes its behaviour
- through type change (spinodal or nucleotic or coarsening), without changing the shape,
- through a change of the shape only, or
- through a) (type change) and b) (shape change) simultaneously.
- chord lengthl 1 (and/or radius of gyrationR),
- volume partw 1 of the Phase 1, and
- relative inner surfaceS v of the system.
- spinodal change, all three SAXRS parameters are increasing or decreasing simultaneously and proportional to a power of the intensity of the change,
- nucleotic change,l 1 (and/orR) is unchanged, the other two (w 1 andS v ) are increasing or decreasing simultaneously and directly proportional to the intensity,
- coarsening change,w 1 is unchanged and anincreasing ofl 1 is always accompanied by adecreasing ofS v and vice versa.
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Summary Motivated by different mean value properties, the functional equationsf(x) – f(y)/x–y=[(x, y)], (i)xf(y) – yf(x)/x–y=[(x, y)] (ii) (x y) are completely solved when, are arithmetic, geometric or harmonic means andx, y elements of proper real intervals. In view of a duality between (i) and (ii), three of the results are consequences of other three.The equation (ii) is also solved when is a (strictly monotonic) quasiarithmetic mean while the real interval contains 0 and when is the arithmetic mean while the domain is a field of characteristic different from 2 and 3. (A result similar to the latter has been proved previously for (i).) 相似文献