ASAXS study of styrene‐grafted sulfonated poly(vinylidene fluoride) membranes

Small‐angle and wide‐angle X‐ray scattering and anomalous small‐angle X‐ray scattering were used to investigate proton‐conducting membranes prepared by radiation‐induced styrene grafting and sulfonation of commercial poly(vinylidene fluoride) (PVDF‐g‐PS) films. The membranes retain the lamellar and highly oriented structure of the original PVDF films even through excessive grafting and sulfonation. The sulfonate groups aggregate in the central part of the amorphous layers, where they form a weakly ordered structure that does not show any preferred orientation. This structure is suggested to be lamellar with alternate metal‐sulfonated hydrate and PVDF‐g‐PS layers. The lamellar period is 15.1 Å. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 1734–1748, 2000     

Towards a kinetic theory for fermions with quantum coherence

A new density matrix and corresponding quantum kinetic equations are introduced for fermions undergoing coherent evolution either in time (coherent particle production) or in space (quantum reflection). A central element in our derivation is finding new spectral solutions for the 2-point Green's functions written in the Wigner representation, that are carrying the information of the quantum coherence. Physically observable density matrix is then defined from the bare singular 2-point function by convoluting it with the extrenous information about the state of the system. The formalism is shown to reproduce familiar results from the Dirac equation approach, like Klein problem and nonlocal reflection from a mass wall. The notion of the particle number in the presence of quantum coherence is shown to be particularly transparent in the current picture. We extend the formalism to the case of mixing fields and show how the usual flavour mixing and oscillation of neutrinos emerges again from a singular shell structure. Finally, we show how the formalism can be extended to include decohering interactions.     

Minimal technicolor on the lattice

We present results from a lattice study of SU(2) gauge theory with 2 flavors of Dirac fermions in adjoint representation. This is a candidate for a minimal (simplest) walking technicolor theory, and has been predicted to possess either an IR fixed point (where the physics becomes conformal) or a coupling which evolves very slowly, so-called walking coupling. In this initial part of the study we investigate the lattice phase diagram and the excitation spectrum of the theory.     

Average-optimal string matching

The exact string matching problem is to find the occurrences of a pattern of length m from a text of length n symbols. We develop a novel and unorthodox filtering technique for this problem. Our method is based on transforming the problem into multiple matching of carefully chosen pattern subsequences. While this is seemingly more difficult than the original problem, we show that the idea leads to very simple algorithms that are optimal on average. We then show how our basic method can be used to solve multiple string matching as well as several approximate matching problems in average optimal time. The general method can be applied to many existing string matching algorithms. Our experimental results show that the algorithms perform very well in practice.     

Measurement Data-Based Link-Level and System-Level Simulations for Single Carrier SC/MMSE MIMO Turbo Equalization Technique

Current advances in multi-dimensional channel sounding techniques make it possible to evaluate performances of signal processing algorithms in realistic conditions. By using channel impulse response measurement data collected in the real fields, link-level performances of signal transmission techniques in the fields such as bit error rate (BER) and frame error rate (FER) performances can be evaluated. This technique is called link-level simulation. Through statistical analysis of link-level simulation results, system-level performances of the techniques such as geographical distribution of BER and FER in the area of interest can also be evaluated. This technique is called system-level simulation. This paper focuses on link- and system-level performances of a multiple-input multiple-output (MIMO) Turbo Equalizer in real fields. Methodologies for the link- and system-level simulations using field measurement data are first presented. Results of link- and system-level simulations using two-dimensional channel sounding field measurement data collected in Tokyo are then presented. This revised version was published online in August 2006 with corrections to the Cover Date.     

Time-dependent physical spectra of Gaussian Schell-model pulses

The time-dependent physical spectra introduced by Eberly and Wódkiewicz [J. Opt. Soc. Am. 67 (1977) 1252], observable with a photon-counting detector placed behind a Fabry-Perot filter, are evaluated for a class of temporally partially coherent non-stationary fields known as Gaussian Schell-model plane-wave pulses. Numerical comparisons between source spectra and observed spectra are provided and discussed, and several general features such as initial spectral broadening at the arrival of the pulse and a temporal pulse tail are illustrated. Closed-form approximations are obtained for the time evolution of the observable spectrum by evaluating the leading terms in an appropriate series expansion.     

Step-By-Step Atomic Insights into Structural Reordering from 2D to 3D MoS2

Vertically stacked low-dimensional heterostructures are outstanding systems both for exploring fundamental physics and creating new devices. Due to nanometer-scale building blocks, atomic scale phenomena become for them of fundamental importance, including during device operation. These can be accessed in situ in aberration-corrected scanning transmission electron microscopy (STEM) experiments. Here, the dynamics of a graphene-MoS₂ heterostructure are studied under Joule heating, where the graphene serves as a high temperature atomically thin and electron transparent “hot plate” for the MoS₂. Structural dynamics and evolution of the system are shown at the atomic scale, demonstrating that at the highest temperatures (estimated to exceed 2000 K), the continuous 2D MoS₂ transforms into separated 3D nanocrystals, initiated by sulfur vacancy creation and migration followed by formation of voids and clustering at their edges. The resulting nanocrystals exhibit predominantly hexagonal shapes with the 2H and hybrid (2H/3R, 3R/TZ) polytypes. The observed morphology of the crystals is further discussed during and after the transformation, as well as their different edge configurations and stability under electron irradiation. These observations of MoS₂ at extreme temperatures provide insights into the operation of devices based on graphene/MoS₂ heterostructures and ultimately may help device fabrication techniques to create MoS₂-based nanostructures, for example, in hydrogen evolution reaction applications.     

Photoinduced electron transfer in Langmuir-Blodgett monolayers of porphyrin-fullerene dyads

A series of electron donor-acceptor (DA) dyads, composed of a porphyrin donor and a fullerene acceptor covalently linked with two molecular chains, were used to fabricate solid molecular films with the Langmuir-Blodgett (LB) technique. By means of the LB technique, the DA molecules can be oriented perpendicular to the plane of the substrate. In DHD6ee and its zinc derivative hydrophilic groups are attached to the phenyl moieties in the porphyrin end of the molecule; while in the other three dyads, TBD6a, TBD6hp, and TBD4hp, the hydrophilic groups are in the fullerene end of the molecule. This makes it possible to alternate the orientation of the molecules in two opposite directions with respect to the air-water interface and to fabricate molecular assemblies in which the direction of the primary photoinduced vectorial electron transfer can be controlled both by the deposition direction of the LB monolayer and by the selection of the used DA molecule. This was proved by the time-resolved Maxwell displacement charge measurements. The spectroscopic properties of the DA films were studied with the steady-state absorption and fluorescence methods. In addition, the time correlated single photon counting technique was used to determine the fluorescence properties of the dyad films.     

Inkjetting dielectric layer for electronic applications

Printed electronics is expected to increase its market share significantly in near future. The emerging applications include e.g. display applications, RFID tags, and photovoltaic applications. A benefit of printing is the additive character of the process, which means that material is deposited only the amount that is needed. Digital printing increases flexibility of the process, because circuits are manufactured directly from a digital file, which removes need of fixed masks or patterned screens for each layout. Formation of a multilayer circuitry requires printing of conductive and insulative layers. This paper focuses on printing of a dielectric layer with an inkjet printer. Six sigma DMAIC approach was applied during the process characterization and analysis. The study began by defining the process parameters and evaluating their importance to the outputs. Highest rated parameters were taken into consideration and a design of experiments was established. Measured values were analyzed and it was observed which parameters had the highest effect on the outputs. The results were further verified and it was observed that electrically the printed structures were successful.     

High-performance anion-exchange chromatography–mass spectrometry method for determination of levoglucosan, mannosan, and galactosan in atmospheric fine particulate matter

Biomass burning has a strong influence on the atmospheric aerosol composition through particulate organic, inorganic, and soot emissions. When biomass burns, cellulose and hemicelluloses degrade, producing monosaccharide anhydrides (MAs) such as levoglucosan, mannosan, and galactosan. Therefore, these compounds have been commonly used as tracers for biomass burning. In this study, a fast water-based method was developed for the routine analysis of MAs, based on high-performance anion-exchange chromatography with electrospray ionization mass spectrometry detection. This method combines simple sample preparation, fast separation, and the advantages of the selective detection with MS. Analysis run was optimized to the maximum separation of levoglucosan, mannosan, and galactosan with 15-min analysis. The validation results indicated that the method showed good applicability for determination of MA isomer concentrations in ambient samples. The limit of detection was 100 pg for levoglucosan and 50 pg for mannosan and galactosan. Wide determination ranges enabled the analysis of samples of different concentration levels. The method showed good precision, both for standard solutions (3.9–5.9% RSD) and for fine particle samples (4.3–8.5% RSD). Co-elution of internal standard (carbon-13-labeled levoglucosan) and sugar alcohols with levoglucosan decreased the sensitivity of levoglucosan determination. The method was used to determine the MA concentrations in ambient fine particle samples from urban background (Helsinki) and rural background (Hyytiälä) in Finland. The average levoglucosan, mannosan, and galactosan concentrations were 77, 8.8, and 4.2 ng?m^?3 in Helsinki (winter 2008–2009) and 17, 2.3, and 1.4 ng?m^?3 in Hyytiälä (spring 2007), respectively. The interrelation of the three MA isomers was fairly constant in the ambient fine particle samples.