Efficient PFD-Based Networking and Buffering Models for Improving Video Quality over Congested Links

Video traffic over the Internet becomes increasingly popular and is expected to comprise the largest proportion of the traffic carried by wired and wireless networks. On the other hand, videos are usually compressed by exploiting spatial and temporal redundancy for the reason of increasing the number of video streams that can be simultaneously carried over links. Unfortunately, receiving high-quality video streaming over the Internet remains a challenge due to the packet loss encountered in the congested wired and wireless links. In addition, the problem is more apparent in wireless links due to not only employing limited system capacity, but also some of the major drawbacks of wireless networks, out of which the bandwidth limitations and link asymmetry which refers to the situation where the forward and reverse paths of a transmission have different channel capacities. Therefore, the wireless hops may be congested which result in dropping many video frames. Additionally, as a result of compressing videos, dependencies among frames and within a frame arise. Consequently, the overall video quality tends to be degraded dramatically. The main challenge is to support the growth of video traffic while keeping the perceived quality of the delivered videos high. In this paper, we extend our previous work concerning improving video traffic over wireless networks through professionally studying the dependencies between video frames and their implications on the overall network performance. In other words, we propose very efficient network and buffer models proportionately to novel algorithms that aim to minimize the cost of aforementioned possible losses by selectively discarding frames based on their contribution to picture quality, namely, partial and selective partial frame discarding policies considering the dependencies between video frames. The performance metrics that are employed to evaluate the performance of the proposed algorithms include the rate of non-decodable frames, peak signal-to-noise ratio, frameput, average buffer occupancy, average packet delay, as well as jitter. Our results are so promising and show significant improvements in the perceived video quality over what is relevant in the current literature. We do not end up to this extent, but rather the effect of producing different bit-stream rates by the FFMPEG codecs on aforementioned performance metrics has been extensively studied.     

New video discarding policies for improving UDP performance over wired/wireless networks

Multimedia communication over wired and wireless networks becomes a compulsory need for many recent applications. To effectively react to the tremendous demand of video streaming over the Internet, videos are usually compressed by utilizing spatial and temporal redundancy. It is noteworthy to mention that compressing videos may degrade their quality if it is not investigated properly. In other words, as a consequence of exploiting redundancies, frame dependencies emanate, which make discarding frames, because of occupying the whole capacity of network elements, have severe implications on the video quality. Furthermore, transmitting videos over capacity‐limited links owing to error‐prone channels, power constraints and bandwidth variations will severely affect the video quality. Additionally, as the current coding schemes are characterized by being able to afford high compression efficiency, sensitivity to packet losses becomes untolerated. Therefore, insuring the perceived quality of the delivered videos to be always high in spite of aforementioned challenges is the primary focus of current researchers. In this paper, we propose efficient and novel video discarding policies that mainly aim to reduce the number of frames being lost through substitution of those frames that are very difficult or even impossible to decode at the receiver side. This is accomplished by controlling and maintaining the buffer occupancy of network elements. Our proposed policies are evaluated in terms of frameput, rate of non‐decodable frames, peak signal‐to‐noise ratio, structural similarity index and average buffer occupancy. Our proposed policies behave very well and achieve a remarkable enhancement over what is closely connected in the literature. Copyright © 2015 John Wiley & Sons, Ltd.     

Radioactivity of plutonium isotopes, <Superscript>137</Superscript>Cs and their ratio in sediment,seawater and biota from the east coast of Peninsular Malaysia

This study with sampling expeditions of marine sediment, seawater and biota were performed at 30 stations within Malaysian Exclusive Economic Zone (EEZ). A total of >400 samples were collected to determine the activity concentration of anthropogenic radionuclides (^239+240Pu, ¹³⁷Cs) and their activity ratio (^239+240Pu/¹³⁷Cs) in sediments, seawater and biota. The purpose of this study was to determine the concentration levels for these radionuclides and to evaluate any occurrence of radioactive contamination. Sediment cores were obtained using multicorer device, while water samples via co-precipitation techniques and biota was purchased from local fishermen. The activity concentrations of ^239+240Pu in sediment, seawater and biota were ranged 0.21–0.45 Bq/kg dry wt., 2.33–7.95 mBq/m³ and <0.008 Bq/kg fresh wt., respectively. Meanwhile, the values of ¹³⁷Cs were ranged <1.00–2.71 Bq/kg dry wt. in sediment, 3.40–5.89 Bq/m³ in seawater and <0.05–0.41 Bq/kg fresh wt. in biota, respectively. Activity ratios of ^239+240Pu to ¹³⁷Cs obtained seem to confirm that these artificial radioactivities were mainly due to global nuclear fallout.     

Intercomparison of techniques for estimation of sedimentation rate in the Sabah and Sarawak coastal waters

A total of eight sediment cores with 50 cm length were taken in the Sabah and Sarawak coastal waters using a gravity corer in 2004 to estimate sedimentation rates using four mathematical models of CIC, Shukla-CIC, CRS and ADE. The average of sedimentation rate ranged from 0.24 to 0.48 cm year^?1, which is calculated based on the vertical profile of ²¹⁰Pb_ex in sediment core. The finding also showed that the sedimentation rates derived from four models were generally shown in good agreement with similar or comparable value at some stations. However, based on statistical analysis of paired sample t-test indicated that CIC model was the most accurate, reliable and suitable technique to determine the sedimentation rate in the coastal area.     

Synthesis and Characterization of Antimony(III) Complexes of Thioamides,and Crystal Structure of {[Sb(Imt)2Cl2]2((2‐Imt)}Cl2(Imt=Imidazolidine‐2‐thione)

Antimony(III) complexes of thioamides [thioamides=thiourea (Tu), N,N′‐dimethylthiourea (Dmtu), tetramethylthiourea (Tmtu), imidazolidine‐2‐thione (Imt) and diazinane‐2‐thione (Diaz)] with the general formulae, Sb(thione)_nCl₃ (n=1, 2, 2.5, 3) were prepared and characterized by elemental analysis, IR and NMR (¹H, ¹³C) spectroscopic methods. The spectral data of the complexes are consistent with the coordination of the thiones to antimony(III). The crystal structure of one of them, {[Sb(Imt)₂Cl₂]₂(μ₂‐Imt)}Cl₂ ( 1 ), was determined by X‐ray crystallography, which shows that the complex is dinuclear consisting of two [Sb(Imt)₂Cl₂] units bridged by an Imt molecule. In 1 , the antimony atom is bonded to two chlorine atoms, two sulfur atoms of coordinated Imt molecules and one sulfur atom of a bridging Imt molecule. The antimony environment can be considered to be distorted octahedral with one Cl^? ion weakly bound to antimony.     

Theoretical investigation into competing unimolecular reactions encountered in the pyrolysis of acetamide

Motivated by the necessity to understand the pyrolysis of alkylated amines, unimolecular decomposition of acetamide is investigated herein as a model compound. Standard heats of formation, entropies, and heat capacities, are calculated for all products and transition structures using several accurate theoretical levels. The potential energy surface is mapped out for all possible channels encountered in the pyrolysis of acetamide. The formation of acetamedic acid and 1-aminoethenol and their subsequent decomposition pathways are found to afford the two most energetically favored pathways. However, RRKM analysis shows that the fate of acetamedic acid and 1-aminoethenol at all temperatures and pressures is to reisomerize to the parent acetamide. 1-Aminoethenol, in particular, is predicted to be a long-lived species enabling its participation in bimolecular reactions that lead to the formation of the major experimental products. Results presented herein reflect the importance of bimolecular reactions involving acetamide and 1-aminoethenol in building a robust model for the pyrolysis of N-alkylated amides.     

A note on warped product submanifolds of Kenmotsu manifolds

Warped product manifolds are known to have applications in Physics. For instance, they provide an excellent setting to model space-time near a black hole or a massive star (cf. [HONG, S. T.: Warped products and black holes, Nuovo Cimento Soc. Ital. Fis. B 120 (2005), 1227–1234]). The studies on warped product manifolds with extrinsic geometric point of view are intensified after B. Y. Chen’s work on CR-warped product submanifolds of Kaehler manifolds. Later on, similar studies are carried out in the setting of Sasakian manifolds by Hasegawa and Mihai. As Kenmotsu manifolds are themselves warped product spaces, it is interesting to investigate warped product submanifolds of Kenmotsu manifolds. In the present note a larger class of warped product submanifolds than the class of contact CR-warped product submanifolds is considered. More precisely the existence of warped product submanifolds of a Kenmotsu manifold with one of the factors an invariant submanifold is ensured, an example of such submanifolds is provided and a characterization for a contact CR-submanifold to be a contact CR-warped product submanifold is established.     

A decision support system for order acceptance/rejection in hybrid MTS/MTO production systems

In this paper, we present a novel decision support system for order acceptance/rejection in a hybrid Make-to-Stock/Make-to-Order production environment. The proposed decision support system is comprised of five steps. At the first step, the customers are prioritized based on a fuzzy TOPSIS method. Rough-cut capacity and rough-cut inventory are calculated in the second step and in case of unavailability in capacity and materials, some undesirable orders are rejected. Also, proper decisions are made about non-rejected orders. At the next step, prices and delivery dates of the non-rejected orders are determined by running a mixed-integer mathematical programming model. At the fourth step, a set of guidelines are proposed to help the organization negotiate over price and due date with the customers. In the next step, if the customer accepts the offered price and delivery date, the order is accepted and later considered in the production schedule of the shop floor, otherwise the order is rejected. Finally, numerical experiments are conducted to show the tractability of the applied mathematical programming model.     

Catalyst-free one-pot synthesis of 1,4,5-trisubstituted pyrazoles in 2,2,2-trifluoroethanol

A simple, efficient and three component one-pot synthesis of 1,4,5-trisubstituted pyrazoles by condensation of β-dicarbonyls, N,N-dimethylformamide dimethyl acetal (DMFDMA) and hydrazine derivatives in 2,2,2-trifluoroethanol without using any catalyst and activation, is described.