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891.
Kevin Belnap 《世界电子元器件》2010,(2):56-58
便携式医疗设备正不断改进数以百万计患者的医疗保健条件。诸如血糖监测仪、心率检测仪、可吞咽胃肠(GI)道检测仪以及止痛植入物等众多设备都在不断提升慢性或急性疾病患者的生活质量。便携式自动除颤器可以挽救急病患者的生命。运动手表不仅能够无线记录用户的心率、测量距离、进行脚步计数,而且还可实现能最大限度发挥有氧训练优势的其它功能。未来几年中,还将陆续推出众多能显著改善医疗实施及其效果的创新型医疗应用产品。 相似文献
892.
893.
894.
Kevin Grollier Arnaud De Zordo-Banliat Flavien Bourdreux Dr. Bruce Pegot Dr. Guillaume Dagousset Dr. Emmanuel Magnier Dr. Thierry Billard 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(19):6028-6033
The synthesis of molecules bearing (trifluoromethylselenyl)methylchalcogenyl groups is described via an efficient two-step strategy based on a metal-free photoredox catalyzed decarboxylative trifluoromethylselenolation with good yields up to 88 %, which raised to 98 % in flow chemistry conditions. The flow methods allowed also to scale up the reaction. The mechanism of this key reaction was studied. The physicochemical characterization of these emerging groups was performed by determining their Hansch–Leo lipophilicity parameters with high values up to 2.24. This reaction was also extended to perfluoroalkylselenolation with yields up to 95 %. Finally, this method was successfully applied to the functionalization of relevant bioactive molecules such as tocopherol or estrone derivatives. 相似文献
895.
Alessandro Bismuto Patrick Finkelstein Patrick Müller Bill Morandi 《Helvetica chimica acta》2021,104(12):e2100177
In the last twenty years, nickel has successfully imprinted its role in the field of homogeneous catalysis as a valid and complementary alternative to palladium and platinum catalysts. However, compared to those, there are often many different available pathways in nickel catalysis due to the facile access of intermediate oxidation states. Among them, Ni(I) has been increasingly proposed as a key oxidation state in multiple transformations. This oxidation state had already been suggested a long time ago but has only recently undergone a renaissance with extensive ligand design which has led to over 100 isolated Ni(I) complexes. In addition, the analysis of many catalytic cycles has revealed that the Ni(I) species can not only occur as a decomposition product perturbing a Ni(0)–Ni(II) pathway but can also play a key role in alternative Ni(I)–Ni(III) cycles. This behavior is highly dependent on the class of transformation and ligand employed in catalysis. Herein, we concisely describe the journey of this oxidation state, combining the information gathered from inorganic synthesis and mechanistic investigations, from its synthesis to its postulated role in different catalytic cycles. 相似文献
896.
Dr. Uttam Chakraborty Patrick Bügel Lorena Fritsch Dr. Florian Weigend Prof. Dr. Matthias Bauer Prof. Dr. Axel Jacobi von Wangelin 《ChemistryOpen》2021,10(2):265-271
The controlled assembly of well-defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe4, Fe6, and Fe7 nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles. 相似文献
897.
898.
Dr. Ileana-Alexandra Pavel Dr. Gerardo Salinas Dr. Maciej Mierzwa Dr. Serena Arnaboldi Patrick Garrigue Prof. Alexander Kuhn 《Chemphyschem》2021,22(13):1321-1325
Numerous artificial micro- and nanomotors, as well as various swimmers have been inspired by living organisms that are able to move in a coordinated manner. Their cooperation has also gained a lot of attention because the resulting clusters are able to adapt to changes in their environment and to perform complex tasks. However, mimicking such a collective behavior remains a challenge. In the present work, magnesium microparticles are used as chemotactic swimmers with pronounced collective features, allowing the gradual formation of macroscopic agglomerates. The formed clusters act like a single swimmer able to follow pH gradients. This dynamic behavior can be used to spot localized corrosion events in a straightforward way. The autonomous docking of the swimmers to the corrosion site leads to the formation of a local protection layer, thus increasing corrosion resistance and triggering partial self-healing. 相似文献
899.
A benchtop high-resolution time-of-flight mass spectrometer (TOF MS) was evaluated for the determination of key organic microcontaminants. The major advantage of the TOF MS proved to be the high mass resolution of about 0.002 Da (10 ppm). Consequently, the detectability of polar pesticides, polynuclear aromatic hydrocarbons and polychlorinated biphenyls is excellent, and detection limits are in the order of 1–4 pg injected mass. Best mass spectral resolution was obtained for medium-scale peaks. It is a disadvantage that the calibration range is rather limited, viz. to about two orders of magnitude. The high mass spectral resolution was especially useful to improve the selectivity and sensitivity when analyzing target compounds in complex samples and to prevent false-positive identifications. 相似文献
900.
Kefu Fu Kevin Henbest Yufen J. Zhang Shane Valentin Ya-Ping Sun 《Journal of photochemistry and photobiology. A, Chemistry》2002,150(1-3):143-152
Dimeric fullerene macromolecules were prepared via the complexation of two fullerenylated 2,2′:6′,2″-terpyridine ligands with Fe(II) and Co(II) ions. The solubility of these macromolecules in some organic solvents allowed both their structural characterization and a study of their optical properties. The electronic absorption and emission of the macromolecules in solution were evaluated; and the results indicated no meaningful ground-state and excited singlet state intramolecular charge transfer interactions. However, the laser flash photolysis results could be explained in terms of the electron transfer quenching of the excited triplet methanofullerene moiety by the center metal–ligand complex in the macromolecules. The optical limiting properties of the macromolecules in solution were also investigated in comparison with those of the ligands for an evaluation of the complexation effects. 相似文献