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951.
Iuliana P. Maria Bryan D. Paulsen Achilleas Savva David Ohayon Ruiheng Wu Rawad Hallani Aniruddha Basu Weiyuan Du Thomas D. Anthopoulos Sahika Inal Jonathan Rivnay Iain McCulloch Alexander Giovannitti 《Advanced functional materials》2021,31(14):2008718
Conjugated polymers with mixed ionic and electronic transport are essential for developing the complexity and function of electrochemical devices. Current n-type materials have a narrow scope and low performance compared with their p-type counterparts, requiring new molecular design strategies. This work presents two naphthalene diimide-bithiophene (NDI-T2) copolymers functionalized with hybrid alkyl-glycol side chains, where the naphthalene diimide unit is segregated from the ethylene glycol (EG) units within the side chain by an alkyl spacer. Introduction of hydrophobic propyl and hexyl spacers is investigated as a strategy to minimize detrimental swelling close to the conjugated backbone and balance the mixed conduction properties of n-type materials in aqueous electrolytes. It is found that both polymers functionalized with alkyl spacers outperform their analogue bearing EG-only side chains in organic electrochemical transistors (OECTs). The presence of the alkyl spacers also leads to remarkable stability in OECTs, with no decrease in the ON current after 2 h of operation. Through this versatile side chain modification, this work provides a greater understanding of the structure-property relationships required for n-type OECT materials operating in aqueous media. 相似文献
952.
Shuyu Bao Yue Wang Khaw Lina Li Zhang Bing Wang Wardhana Aji Sasangka Kenneth Eng Kian Lee Soo Jin Chua Jurgen Michel Eugene Fitzgerald Chuan Seng Tan Kwang Hong Lee 《半导体学报》2021,42(2):83-102
The heterogeneous integration of Ⅲ-Ⅴ devices with Si-CMOS on a common Si platform has shown great promise in the new generations of electrical and optical systems for novel applications,such as HEMT or LED with integrated control cir-cuitry.For heterogeneous integration,direct wafer bonding(DWB)techniques can overcome the materials and thermal mis-match issues by directly bonding dissimilar materials systems and device structures together.In addition,DWB can perform at wafer-level,which eases the requirements for integration alignment and increases the scalability for volume production.In this paper,a brief review of the different bonding technologies is discussed.After that,three main DWB techniques of single-,double-and multi-bonding are presented with the demonstrations of various heterogeneous integration applications.Mean-while,the integration challenges,such as micro-defects,surface roughness and bonding yield are discussed in detail. 相似文献
953.
Kenneth Hoffman 《Acta Mathematica》1962,108(1):271-317
954.
Melvyn Rowen Churchill David George Churchill My Hang Vo Huynh Kenneth J. Takeuchi 《Journal of chemical crystallography》2000,30(1):17-21
The complex cis-[Ru(bpy)2{PMe(o-tol)2}Cl+][ClO–
4] crystallizes in space group P21/c witha = 9.375(2) Å, b = 22.019(7) Å, c = 16.153(4) Å, = 90.83(2)°, V = 3333.9(16) Å3 and D(calc'd) = 1.547 g/cm3 for Z = 4. The Ru-PMe(o-tol)2 bond length of 2.357(3) Å is significantly longer than distances of Ru-PMe2(o-tol) = 2.324(2) Å and Ru-PMe3 = 2.310(2) Å in analogous complexes. The corresponding Ru-P(o-tol)3 complex has eluded synthesis, probably due to steric hindrance. 相似文献
955.
Melvyn Rowen Churchill Charles H. Lake Lisa F. Szczepura Kenneth J. Takeuchi 《Journal of chemical crystallography》1996,26(7):489-495
The title complex crystallizes in the centrosymmetric monoclinic space group C2/c (No. 15) withZ=8. The structure was refined toR=4.49% for those 2745 independent reflections with 2=5–50o and |F
|>6(F). Ruthenium-ligand distances are as follows: Ru-P=2.284(2) and 2.286(2) Å, Ru-NO2=2.049(6) Å and Ru-C(Cp)=2.210(10)-2.246(9) Å. Bond lengths within the nitro ligand are N(1)-O(1)=1.226(10) Å and N(1)-O(2)=1.244(10) Å. The methanol of solvation is ordered but is subject to large thermal vibrational motions. 相似文献
956.
John C. Huffman Norman J. Wells Kenneth G. Caulton 《Journal of chemical crystallography》1984,14(6):581-587
The crystal structure of FeH2(PMePh2)4 shows this to exist as thecis isomer in the solid state with major distortions of the FeP4 skeleton:cis P-Fe-P angles 98.1(1)–107.2(1)° andtrans P-Fe-P angle 143.3(1)°. All hydrogen atoms were refined, and the mean Fe-H separation is 1.59 Å. Long Fe-P distances, 2.187(3)–2.251(3) Å, emphasize the crowding in this molecule. Crystallographic data:a=11.684(4) Å,b=37.793(17),c=9.765(3),=90.81(1)°, andZ=4 in space groupP21/n (No. 14).R(F)=6.3% andR
w
(F)=6.0% for 2585 observed reflections collected at —162°C. 相似文献
957.
Melvyn Rowen Churchill Ronald F. See Carol A. Bessel Kenneth J. Takeuchi 《Journal of chemical crystallography》1996,26(8):543-551
The complexmer,trans-[Ru(NO2)(trpy)(PPr3)
2
+
][ClO
4
–
]crystallizes in the centrosymmetric orthorhombic space group Pnma withZ=4. Both the ruthenium(II) cation and the perchlorate ligand lie about crystallographic mirror planes. The nitro ligand is not coplanar with the Ru(trpy) moiety and suffers from two fold disorder about its Ru–N bond such that the two sets of oxygen atoms have symmetry-related sites above or below the crystallographic mirror plane. The n-propyl groups within the PPr3 ligands suffer from disorder of their C() and C() atoms but share common C() sites. Ruthenium-ligand distances are: Ru–PPr3=2.398(2)Å, Ru–NO2=2.053(7) Å, Ru–N(trpy, outer)=2.078(6) and 2.092(6) Å and Ru–N(trpy, central) =1.965(6) Å. 相似文献
958.
Extreme Two‐Phase Cooling from Laser‐Etched Diamond and Conformal,Template‐Fabricated Microporous Copper
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James W. Palko Hyoungsoon Lee Chi Zhang Tom J. Dusseault Tanmoy Maitra Yoonjin Won Damena D. Agonafer Jess Moss Farzad Houshmand Guoguang Rong Joshua D. Wilbur Derrick Rockosi Ihor Mykyta Dan Resler David Altman Mehdi Asheghi Juan G. Santiago Kenneth E. Goodson 《Advanced functional materials》2017,27(45)
This paper reports the first integration of laser‐etched polycrystalline diamond microchannels with template‐fabricated microporous copper for extreme convective boiling in a composite heat sink for power electronics and energy conversion. Diamond offers the highest thermal conductivity near room temperature, and enables aggressive heat spreading along triangular channel walls with 1:1 aspect ratio. Conformally coated porous copper with thickness 25 µm and 5 µm pore size optimizes fluid and heat transport for convective boiling within the diamond channels. Data reported here include 1280 W cm?2 of heat removal from 0.7 cm2 surface area with temperature rise beyond fluid saturation less than 21 K, corresponding to 6.3 × 105 W m?2 K?1. This heat sink has the potential to dissipate much larger localized heat loads with small temperature nonuniformity (5 kW cm?2 over 200 µm × 200 µm with <3 K temperature difference). A microfluidic manifold assures uniform distribution of liquid over the heat sink surface with negligible pumping power requirements (e.g., <1.4 × 10?4 of the thermal power dissipated). This breakthrough integration of functional materials and the resulting experimental data set a very high bar for microfluidic heat removal. 相似文献
959.
Molecular recognition of sugars and a practical method to detect and discriminate among a large number of such similar analytes remain substantial scientific challenges. We report here a low-cost, simple colorimetric sensor array capable of identification and quantification of sugars and related compounds. Fifteen different monosaccharides, disaccharides, and artificial sweeteners were differentiated without error in 80 trials. Limits of detection at pH 7.4 for glucose were <1 mM, which is below physiologically important levels. 相似文献
960.
Schweinfurth D Hardcastle KI Bunz UH 《Chemical communications (Cambridge, England)》2008,(19):2203-2205
The copper catalyzed 1,3-dipolar cycloaddition of 4-butoxyphenylazide with 2-, 3- or 4-ethynylpyridine furnishes 1,4-diaryltriazoles, which display turn-on fluorescence upon addition of metal cations. 相似文献