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991.
Dr. Byung Gyu Park Dr. Dae Ho Hong Dr. Ho Yong Lee Milim Lee Prof. Dr. Dongwhan Lee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(19):6610-6616
Multichromophore arrays allow for cascade energy transfer. As an isoelectronic analogue of indacenyl, bis(triazolo)benzene features a fused tricyclic skeleton that rigidly places two π‐extended triazoles in close proximity. Such triazole‐based fluorophores behave as electronically independent modules in the ground states, but become tightly coupled upon photoexcitation for highly efficient excitation energy transfer (EET) that can be gated by external stimuli. Taking this donor–acceptor fluorophore system a step further, we have designed and implemented a cascade EET. Here, the initial excitation takes part in a circular relay to arrive at the longest‐wavelength emitting site as the final destination. Modularly constructed triazoloarenes should serve as versatile platforms for chemically controlled optical signaling. 相似文献
992.
Pd nanoparticles immobilized on PNIPAM–halloysite: highly active and reusable catalyst for Suzuki–Miyaura coupling reactions in water
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Myeng Chan Hong Hyunseok Ahn Myung Chan Choi Yongwoo Lee Jongsik Kim Hakjune Rhee 《应用有机金属化学》2014,28(3):156-161
Poly(N‐isopropylacrylamide)–halloysite (PNIPAM‐HNT) nanocomposites exhibited inverse temperature solubility with a lower critical solution temperature (LCST) in water. Palladium (Pd) nanoparticles were anchored on PNIPAM‐HNT nanocomposites with various amounts of HNT from 5 to 30 wt%. These Pd catalysts exhibited excellent reactivities for Suzuki–Miyaura coupling reactions at 50–70 °C in water. In particular, Pd anchored PNIPAM/HNT (95:5 w/w ratio) nanocomposites showed excellent recyclability up to 10 times in 96% average yield by simple filtration. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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995.
Xiang-Yao Wu Bo-Jun Zhang Xiao-Jing Liu Hong Li Si-Qi Zhang Jing Wang Yi-Heng Wu Jing-Wu Li 《International Journal of Theoretical Physics》2013,52(2):549-558
In this paper, we study two-photon ghost interference with the approach of photon quantum theory, and calculate the coincidence counts of D 1 and D 1 detectors. With specific attention to the two-photon interference experiment carried out by Milena D’Angelo et al. (Phys. Rev. Lett. 87:013602, 2001), and find the theoretical result is accordance with experiment data. 相似文献
996.
�� �֣�Ƚ �죬��������˴ϣ��� �����α�� 《核聚变与等离子体物理》2018,38(3):334-338
为了了解聚变实验堆真空室壳体表面残余应力的分布以及退火工艺对残余应力的影响,通过模拟分析和实验检测两种方式对不锈钢316LN冷压曲面和热压曲面残余应力进行研究,获得退火前后曲面表面残余应力的大小,得到冷压曲面和热压曲面残余应力的分布以及退火工艺对残余应力分布的影响。研究结果为分析成型工艺提供数据支撑,对中国聚变工程实验堆真空室的研究与制造具有重要意义。 相似文献
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998.
Musammir Khan Yakai Feng Dazhi Yang Wei Zhou Hong Tian Ying Han Li Zhang Wenjie Yuan Jin Zhang Jintang Guo Wencheng Zhang 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3166-3176
The synthetic polycations are ideal candidates as antimicrobial agents, because they resemble natural antimicrobial peptides, but to render hemocompatibility to these materials is a great challenge. Herein, we used 2‐(tert‐butyl‐aminoethyl) methacrylate (TBAEMA), to synthesize its homopolymer and pegylated random and diblock copolymers with polyethyleneglycol methacrylate (PEGMA, Mn = 360 Da) by single‐electron transfer–living radical polymerization (SET‐LRP). In the second step, the secondary amino groups in the precursor polymers were quaternized with iodomethane and bromohexane, to obtain three series of quaternized polymers. The antimicrobial properties of these quaternized polymers were evaluated against Escherichia coli (E. coli), by studying the minimum inhibitory concentrations (MICs) which ranged between 32 and 200 mg L?1 and showed higher values for the quaternized random than the diblock copolymers. In addition to, we have also demonstrated the grafting of these polycations onto polycarbonate urethane film surfaces, which showed good killing efficacy against E. coli. Furthermore, the hemolysis of these materials was investigated against human red blood cells, which indicated that except the quaternized homopolymers that showed highest hemolysis, all other amphiphilic polycations exhibited very low hemolytic activity. Therefore, our designed materials with controlled structures and functionality, synthesized from cheaply available resources could serve as useful agents in the field of biomedicines and implantable materials. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3166–3176 相似文献
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1000.
锶原子单态和三重态间的互组跃迁(5s2)1S0-(5s5p)3P1辐射率远小于一般的电偶极跃迁,共振跃迁荧光信号微弱。介绍了一种应用于探测该互组跃迁荧光谱的直流偏置探测器。该探测器选用极低输入偏置电流运算放大器作为前置放大,具有信噪比高、增益高、偏置可调等优点。此探测器探测增益为106 V/W量级,-3dB带宽为1MHz。实验中利用该探测器对锶原子互组跃迁(5s2)1S0-(5s5p)3P1微弱共振荧光进行探测,获得信噪比很好的共振荧光谱,且无直流偏置,并由此获得高信噪比的鉴频曲线。应用该探测器观测到了饱和荧光谱线以及对应的鉴频曲线,可用于689nm激光锁频,应用于锶光钟系统。 相似文献