全文获取类型
收费全文 | 972篇 |
免费 | 129篇 |
专业分类
化学 | 915篇 |
晶体学 | 4篇 |
力学 | 10篇 |
数学 | 39篇 |
物理学 | 85篇 |
无线电 | 48篇 |
出版年
2024年 | 2篇 |
2023年 | 18篇 |
2022年 | 19篇 |
2021年 | 38篇 |
2020年 | 42篇 |
2019年 | 51篇 |
2018年 | 35篇 |
2017年 | 24篇 |
2016年 | 59篇 |
2015年 | 74篇 |
2014年 | 63篇 |
2013年 | 68篇 |
2012年 | 96篇 |
2011年 | 92篇 |
2010年 | 53篇 |
2009年 | 35篇 |
2008年 | 61篇 |
2007年 | 46篇 |
2006年 | 40篇 |
2005年 | 30篇 |
2004年 | 15篇 |
2003年 | 14篇 |
2002年 | 12篇 |
2001年 | 8篇 |
2000年 | 21篇 |
1999年 | 10篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 7篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1985年 | 3篇 |
1983年 | 2篇 |
1981年 | 2篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1969年 | 2篇 |
1959年 | 2篇 |
1958年 | 1篇 |
1957年 | 1篇 |
1943年 | 1篇 |
1937年 | 2篇 |
1936年 | 2篇 |
1925年 | 1篇 |
排序方式: 共有1101条查询结果,搜索用时 15 毫秒
31.
32.
33.
Beyond Cognitive Framing Processes: Anger Mediates the Effects of Responsibility Framing on the Preference for Punitive Measures
下载免费PDF全文
![点击此处可从《The Journal of communication》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A new stream of research indicates that framing effects are based on emotional as well as cognitive processes. However, it is not entirely clear whether emotions mediate framing effects and what the moderators of emotional mediation processes are. To address these questions, we conducted an experiment in which the framing of responsibility for a social problem was manipulated (ambivalent vs. high‐responsibility frame). We find that the high‐responsibility frame increased the preference for punitive measures by increasing responsibility beliefs and eliciting anger. Furthermore, we find that trait anger moderates the framing effect on anger and that responsibility beliefs are positively associated with anger intensity. The significance of these findings for framing research and suggestions for future studies are discussed. 相似文献
34.
The Effect of Gradual Fluorination on the Properties of FnZnPc Thin Films and FnZnPc/C60 Bilayer Photovoltaic Cells
下载免费PDF全文
![点击此处可从《Advanced functional materials》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Michael Brendel Stefan Krause Andreas Steindamm Anna Katharina Topczak Sudhakar Sundarraj Peter Erk Steffen Höhla Norbert Fruehauf Norbert Koch Jens Pflaum 《Advanced functional materials》2015,25(10):1565-1573
Motivated by the possibility of modifying energy levels of a molecule without substantially changing its band gap, the impact of gradual fluorination on the optical and structural properties of zinc phthalocyanine (FnZnPc) thin films and the electronic characteristics of FnZnPc/C60 (n = 0, 4, 8, 16) bilayer cells is investigated. UV–vis measurements reveal similar Q‐ and B‐band absorption of FnZnPc thin films with n = 0, 4, 8, whereas for F16ZnPc a different absorption pattern is detected. A correlation between structure and electronic transport is deduced. For F4ZnPc/C60 cells, the enhanced long range order supports fill factors of 55% and an increase of the short circuit current density by 18%, compared to ZnPc/C60. As a parameter being sensitive to the organic/organic interface energetics, the open circuit voltage is analyzed. An enhancement of this quantity by 27% and 50% is detected for F4ZnPc‐ and F8ZnPc‐based devices, respectively, and is attributed to an increase of the quasi‐Fermi level splitting at the donor/acceptor interface. In contrast, for F16ZnPc/C60 a decrease of the open circuit voltage is observed. Complementary photoelectron spectroscopy, external quantum efficiency, and photoluminescence measurements reveal a different working principle, which is ascribed to the particular energy level alignment at the interface of the photoactive materials. 相似文献
35.
Dr. Sylvain Achelle Dr. Jean‐Pierre Malval Dr. Stéphane Aloïse Dr. Alberto Barsella Dr. Arnaud Spangenberg Dr. Loic Mager Dr. Huriye Akdas‐Kilig Dr. Jean‐Luc Fillaut Prof. Bertrand Caro Prof. Françoise Robin‐le Guen 《Chemphyschem》2013,14(12):2725-2736
The nonlinear properties and the photophysical behavior of two π‐conjugated chromophores that incorporate an electron‐deficient pyrimidine core (A) and γ‐methylenepyrans as terminal donor (D) groups have been thoroughly investigated. Both dipolar and quadrupolar branching strategies are explored and rationalized on the basis of the Frenkel exciton model. Even though a cooperative effect is clearly observed if the dimensionality is increased, the nonlinear optical (NLO) response of this series is moderate if one considers the nature of the D/A couple and the size of the chromophores (as measured by the number of π electrons). This effect was attributed to a disruption in the electronic conjugation within the dyes’ scaffold for which the geometry deviates from planarity owing to a noticeable twisting of the pyranylidene end‐groups. This latter structural parameter also has a strong influence on the excited‐state dynamics, which leads to a very efficient fluorescence quenching. 相似文献
36.
Stefan Asam Katharina Habler Michael Rychlik 《Analytical and bioanalytical chemistry》2013,405(12):4149-4158
The content of tenuazonic acid in human urine was determined by a stable isotope dilution assay (SIDA) that was recently developed for the analysis of food commodities and extensively re-validated for urine matrix in this study. Linearity of the response curve was proven between molar ratios n(labeled standard)/n(analyte) of 0.02–100. The limits of detection and determination were 0.2 and 0.6 μg/L, respectively. The mean recovery of the stable isotope dilution assay was 102?±?3 % in the range between 1.0 and 100 μg/L. Interassay precision was 6.7 % (relative standard deviation of three triplicate analyses of a human urine sample during 3 weeks). The method was applied to two studies dealing with urinary excretion of tenuazonic acid: In the first study, tenuazonic acid was quantified in the 24-h urine of six volunteers from Germany (three female, three male) in a concentration range of 1.3–17.3 μg/L or 2.3–10.3 ng/mg?1 creatinine, respectively. In the second study, two volunteers (one female, one male) ingested 30 μg tenuazonic acid by consumption of naturally contaminated whole meal sorghum infant cereals and tomato juice, respectively. The urinary excretion of the ingested tenuazonic acid was 54–81 % after 6 h, depending on matrix and volunteer. After 24 h, 87–93 % of the ingested amount of tenuazonic acid was excreted, but the fate of the remaining about 10 % is open. Thus, it is not possible to exclude potential health hazards for the consumer, completely. Figure
Urinary excretion of tenuazonic acid (TA) by two volunteers (A and B) after ingestion of sorghum infant cereals [1] and tomato juice [2] 相似文献
37.
38.
Laurent Mirolo Tobias Schmidt Dr. Sonja Eckhardt Prof. Dr. Markus Meuwly Prof. Dr. Katharina M. Fromm 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(5):1754-1761
Artificial implants and biomaterials lack the natural defense system of our body and, thus, have to be protected from bacterial adhesion and biofilm formation. In addition to the increasing number of implanted objects, the resistance of bacteria is also an important problem. Silver ions are well‐known for their antimicrobial properties, yet not a lot is known about their mode of action. Silver is expected to interact on many levels, thus the development of silver resistance is very difficult. Nevertheless, some bacteria are able to resist silver, even at higher concentrations. One such defense mechanism of bacteria against heavy‐metal intoxication includes an efflux system. SilE, a periplasmic silver‐binding protein that is involved in this defense mechanism, has been shown to possess numerous histidine functions, which strongly bind to silver atoms, as demonstrated by ourselves previously. Herein, we address the question of how histidine binds to silver ions as a function of pH value. This property is important because the local proton concentration in cells varies. Thus, we solved the crystal structures of histidine–silver complexes at different pH values and also investigated the influence of the amino‐acid configuration. These results were completed by DFT calculations on the binding strength and packing effects and led to the development of a model for the mode of action of SilE. 相似文献
39.
Philipp Bissinger Prof. Dr. Holger Braunschweig Dr. Alexander Damme Dr. Rian D. Dewhurst Dr. Katharina Kraft Thomas Kramer Dr. Krzysztof Radacki 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(40):13402-13407
The synthesis of base‐stabilized boryl and borylene complexes is reported. An N‐heterocyclic carbene (NHC)‐stabilized iron–dihydroboryl complex was prepared by two different routes including methane liberation and salt elimination. A range of base‐stabilized iron–dichloroboryl complexes was prepared by addition of Lewis bases to boryl complexes. Base‐stabilized, cationic monochloroborylene complexes were synthesized from these boryl complexes by halide abstraction by using weakly coordinating anions. 相似文献
40.
Fanzhi Yang Karsten Rauch Katharina Kettelhoit Lutz Ackermann 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(42):11467-11470
Versatile ruthenium(II) complexes allow for site‐selective C H oxygenations with weakly‐coordinating aldehydes. The challenging C H functionalizations proceed with high chemoselectivity by rate‐determining C H metalation. The new method features an ample substrate scope, which sets the stage for the step‐economical preparation of various bioactive heterocycles. 相似文献