The role of excited species in ultraviolet-laser materials ablation III. Non-stationary ablation of organic polymers

The role of non-stationary effects in nano-second ultraviolet (UV) excimer-laser ablation of organic polymers is discussed. The model includes reversible changes in absorption related to darkening and bleaching effects. Comparison of calculations and experimental data for polyimide demonstrates that the photophysical model describes the ablation kinetics quite well.     

Chemical processing with lasers: Recent developments

Chemical processing of materials with lasers is a new and interdisciplinary field with many already realized and potential applications in different areas of technology. This overview summarizes some recent developments in this rapidly expanding field.     

Verification of X-ray line coincidences by high-resolution spectroscopy

Photo-resonant pumping of X-ray lasers requires close coincidence of a strong emission line with a suitable absorbing transition. We use a high-resolution crystal spectrometer to verify five coincidences, one of which has apparently not yet appeared in published work. All but one of the coincidences are found to lie within one linewidth. With respect to X-ray laser photo-pumping three of the five coincidences seem to be promising candidates.     

Optisch aktive N.N-bis[phosphinomethylen]-aminosäureester und deren molybdäncarbonyl-komplexe

Aminoacidesters and hydroxymethylphosphines form the title compounds, which react as bidentate ligands with Mo (CO)₆ to give the cyclic Mo (CO)₄ -complexes.     

Crystallization of amorphous metal films within and without magnetic field

Assuming that the conduction electrons of an amorphous metal contribute to the binding, we investigate whether a magnetic field will influence the transition from the amorphous to the crystalline state. Measurements taken on amorphous Bi, Ga and Yb films show no change in the crystallization temperatures within an accuracy of ±0.1 K due to a magnetic field of 18.5 T parallel to the surface of the films.Dedicated to Prof. Dr. W. Buckel on the occasion of his 60th birthday     

A study of multimode fibre attenuation measurement using a precision spectral radiometer and the near-field filtration technique

Based on the near-field filtration formulation, the paper identifies and quantifies the most important sources of interlaboratory error in multimode fibre attenuation measurements. Measures are proposed for the reduction of these errors, and it is estimated that a lower bound of about 0.04 dB should be possible under certain assumptions.     

Nonlinear wave propagation along periodic-loaded transmission line

A high frequency transmission line periodically loaded with varactor diodes is presented to study nonlinear wave propagation. The nonlinearity and dispersion characteristics are experimentally and theoretically analysed. Experimental results on shock wave formation and harmonic frequency generation are found to be in good agreement with theoretical predictions. The influence of dispersion on second-harmonic frequency generation is particularly discussed yielding large values of the efficiency.     

A variable metric algorithm for unconstrained minimization without evaluation of derivatives

Summary This paper presents a modification of the BFGS-method for unconstrained minimization that avoids computation of derivatives. The gradients are approximated by the aid of differences of function values. These approximations are calculated in such a way that a complete convergence proof can be given. The presented algorithm is implementable, no exact line search is required. It is shown that, if the objective function is convex and some usually required conditions hold, the algorithm converges to a solution. If the Hessian matrix of the objective function is positive definite and satisfies a Lipschitz-condition in a neighbourhood of the solution, then the rate of convergence is superlinear.     

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