Rotational spectra, conformational structures, and dipole moments of thiodiglycol by jet-cooled FTMW and ab initio calculations

The rotational spectra of three low-energy conformers of thiodiglycol (TDG) (HOCH₂CH₂SCH₂CH₂OH) have been measured in a molecular beam using a pulsed-nozzle Fourier-transform microwave spectrometer. To determine the likely conformational structures with ab initio approach, conformational structures of 2-(ethylthio)ethanol (HOEES) (CH₃CH₂SCH₂CH₂OH) were used as starting points together with the consideration of possible intramolecular hydrogen bonding in TDG. Three lower-energy conformers have been found for TDG at the MP2=Full/6311G** level and ab initio results agree nicely with experimentally determined rotational constants. In addition, Stark measurements were performed for two of the three conformers for dipole moment determinations, adding to our confidence of the conformational structure matches between experimental observations and ab initio calculations. Of the three lower-energy conformers, one displays a compact folded-like structure with strong hydrogen bonding between the two hydroxyl groups and the central sulfide atom. Two other conformers have relatively open chain-like structures with hydrogen bonding between each of the hydroxyl groups to the central sulfur atom, of which one has pure b-type dipole moment according to the ab initio results.     

CID-ICP-AES检测煤中不同形态的硫

研究了CID-ICP-AES检测煤中硫酸盐和硫铁矿形态硫的方法。较现有国标方法快速、简便，常见元素不干扰，加标回收率在98．5％-103．0％之间，10次测定的RSD在0．76％-1．59％之间。     

Microwave-assisted Regioselective 1-O-Deacylation of Peracylated Glycopyranoses on Alumina

A facile, rapid and regioselective method for the 1-O-deacylation of peracylated glycopyranoses is described which occurs under mild conditions by absorption onto alumina using microwave irradiation.     

利用预曝光技术制备复合结构光纤光栅传感器

报道利用预曝光技术制备的复合结构光纤光栅传感器。提出利用预曝光技术使某一小段光纤的折射率变大,而后在预曝光部分和未曝光部分的交接处一次性写入光栅,即可得到具有两个透射峰的透射谱。实验研究了该复合结构光纤光栅在温度和应力传感上的应用。实验结果表明,利用该复合结构光纤光栅可以实现温度与应变的同时测量。     

PLC和变频器在空压机节能改造中的应用

针对空压机能耗大，噪音大，自动化程度低等缺点，提出利用可编程控制器和变频嚣实现对螺杆式空压机的节能改造方案。实验结果表明，该方案自动化程度高，节能效果明显，具有很大的实用价值。     

On an Interactive Network Security Measur

The development of the global information highway has brought great impetus and impact to every domain of the world: science, technology, economy and culture as well. Information security of network as an integrated system engineering needs a long period of tackling key problems and planning in such fields as researching and application. The threats to network security can be classified as: hacking, inside attack, computer virus, leak of secret message and modification of key data in network. …     

LaNiO3薄膜热稳定性的研究

LaNiO3导电金属氧化物薄膜在现代应用科学研究中作为电极和过渡阻挡层倍受青睐，它具有很好的导电特性和稳定性。该文采用射频溅射法制备了具有(100)择优取向的赝立方结构LaNiO3-x薄膜，并进行了原位热处理。实验结果表明，在265℃的处理条件下，LaNiO3薄膜表现出不稳定性，晶格中的氧在2h内失去了2.7％。氧的损失对品格结构没有明显影响，但薄膜的导电性能明显下降，折射率和消光系数也具有相同幅度的下降。对薄膜的应用具有一定的影响。该文从LaNiO3薄膜的导电机理方面对实验现象给出了分析和解释。     

PbZr0.52Ti0.48O3薄膜红外椭圆偏振光谱研究

用磁控溅射法在Pt/Ti/SiO2 /Si衬底上制备了PbZr0 .52 Ti0 .4 8O3(PZT)薄膜 .XRD结果表明经过退火后的PZT薄膜呈现多晶结构 .通过红外椭圆偏振光谱仪测量了λ为 2 .5～ 12 .6 μm范围内PZT薄膜的椭偏光谱 ,采用经典色散模型拟合获得PZT薄膜的红外光学常数 ,同时拟合得到未经处理的PZT薄膜和退火后PZT薄膜的厚度分别为 45 4.2nm和 45 0 .3nm .最后通过拟合计算得到结晶PZT薄膜的静态电荷值为 |q|=1.76 9± 0 .0 2 4.这说明在磁控溅射法制备的PZT薄膜中 ,电荷的转移是不完全的 .     

B－ISDN中的拥塞控制技术

Ｂ－ＩＳＤＮ是现代电信网的发展方向，拥塞控制技术则是其中的一个重要问题。由于Ｂ－ＩＳＤＮ采用新的信息传递方式──ＡＴＭ，使传统的拥塞控制方法不再适用。本文依据ＩＴＵ－Ｔ有关建议的最新内容对Ｂ－ＩＳＤＮ拥塞控制的基本思想、工作机制以及其中的主要功能作了较为详细的分析讨论，并提出了一些Ｂ－ＩＳＤＮ拥塞控制技术中尚需进一步研究的问题。     

激光微焊接质量的模糊识别技术研究

讨论了激光微焊点焊接质量的模糊识别的概念，数学模型及其应用方法，并介绍了系统的硬件组成。