基于串联式一维神经网络的毫米波雷达动态手势识别方法

现有的基于雷达传感器的手势识别方法,大多先利用雷达回波对手势的距离、多普勒和角度等信息进行参数估计,得到各种数据谱图,然后再利用卷积神经网络对这些谱图进行分类,实现过程较为复杂。该文提出一种基于串联式1维神经网络(1D-ScNN)的毫米波雷达动态手势识别方法。首先基于毫米波雷达获取动态手势的原始回波,然后利用1维卷积和池化操作对手势特征进行提取,并将这些特征信息输入1维Inception v3结构。最后在网络的末端接入长短期记忆(LSTM)网络来聚合1维特征,充分利用动态手势的帧间相关性,提高识别准确率和训练收敛速度。实验结果表明,该方法实现过程简单,收敛速度快,识别准确率可以达到96.0%以上,高于现有基于数据谱图的手势分类方法。     

一种快速瞬态响应无片外电容LDO

针对无片外电容LDO,在误差放大器与功率管之间添加缓冲器,采用频率补偿的方法,提高了环路稳定性。通过检测负载瞬态变化引起的误差放大器输出电压变化,增加对功率管栅极电容的充放电电流,提升了系统的快速瞬态响应能力。基于TSMC 0.18 μm标准CMOS工艺,设计了一种输入电压范围为1.92~3.60 V、输出电压为1.8 V的LDO。结果表明,负载在1 μs内从0变化到100 mA时,输出最大下冲电压为37.2 mV,响应时间为1.12 μs;负载在1 μs内从100 mA变化到0时,输出最大过冲电压为40.1 mV,响应时间为1.1 μs。     

一种缓冲器阻抗动态调整的LDO

提出了一种缓冲器阻抗动态调整的LDO结构。采用并联负反馈和阻抗动态调整技术,显著降低了缓冲级的输出阻抗,没有增加额外的静态电流,功率管栅极极点始终远在单位增益带宽之外,对稳定性没有影响。该缓冲级增大了功率管栅极的摆率,提高了LDO瞬态响应性能。基于TSMC 0.18 μm 3.3 V CMOS工艺进行设计,该LDO的输出电压为1.8 V,压差电压为0.2 V,最大输出电流为100 mA。仿真结果显示,LDO的静态电流只有5 μA,当负载电流在10 ns内从0 mA跳变到100 mA时,输出欠冲和过冲电压分别为88.2 mV和34.8 mV。     

一种CMOS超高速主从式采样/保持电路

基于65 nm CMOS工艺,设计了一种新型的CMOS主从式采样/保持电路。采用全差分开环主从式的双通道采样结构,提高了电路的线性度。采用负电压产生技术,解决了纳米级工艺下电源电压低的问题。采用Cadence Spectre软件对电路进行仿真分析。仿真结果显示,在1.9 V电源电压、相干采样下,当输入频率为1.247 5 GHz,峰-峰值为0.4 V的正弦波信号,采样率为2.5 GS/s,负载为0.8 pF时,电路的无杂散动态范围(SFDR)为78.31 dB,总谐波失真(THD)为－75.69 dB,有效位为11.51位,可用于超高速A/D转换器中。     

Synthesis and Crystal Structure of Tetra（o-cyanobenzyl）tin

The tetra（o-cyanobenzyl）tin compound has been synthesized by the reaction of cyanobenzyl chloride with tin, and its molecular structure was characterized by elemental analysis, IR spectra, ^1H NMR and X-ray diffraction. Crystal data for this compound： monoclinic, space group C2/c, Mr = 583.24, a = 1.9629（2）, b = 1.05967（13）, c = 1.41249（18） nm, β= 118.180（2）^o, V = 2.5898（5） nm^3, Z = 4, Dc =1.496 g/cm^3, μ（MoKa） = 1.015 cm^-1, F（000） = 1176, R = 0.0189, wR = 0.0497 （observed reflections with I 〉 20（I）） and R = 0.0218, wR = 0.0513 （all reflections）. The molecular structure adopts a distorted tetrahedral geometry around the tin atom. The Sn＇＂N weak interaction between the Sn and N atoms of cyano forms an intermolecular H-bonding, and the bond length is 0.3570 nm; the interaction between hydrogen of methylene and benzene ring of benzyl forms C-H…C with its bond length of 0.2817 nm; and the interaction among hydrogen of benzene ring and carbon of cyano forms Ph-H…C bond （0.2897 nm） Of the σ…π interaction. A 3D chain structure is formed by the above weak intermolecular interactions.     

外端为偶氮苯基团的聚酰胺-胺树枝状分子对光和H~+的响应行为

合成了1到5代外端修饰有偶氮苯基团的聚酰胺-胺(PAMAM)树枝状分子.H-NMR、FTIR和元素分析等表明得到了目标产物,外端接枝率在70%~90%.结构分析表明经修饰的PAMAM分子在3代和4代之间存在一个结构转变.UV-Vis和H-NMR分析结构显示,在中性条件下,Gn-azo表现出类似于小分子偶氮苯基团的光响应行为.而在酸性条件下,偶氮苯基团的顺反异构转化率较质子化前低.包裹及释放实验表明,虽然G4-azo包裹水杨酸分子的能力弱于G4PAMAM,但它对于客体小分子具有缓释作用,光照使偶氮苯基团发生由反式到顺式的异构转化之后,缓释效应更明显.     

Mg助剂对Co/Mg/HZSM-5催化剂结构及其催化甲烷部分氧化制合成气性能的影响

采用XRD、TEM、H2-TPR、Raman、XPS和活性评价等方法, 研究了Mg助剂对Co/Mg/HZSM-5催化剂物理化学性质和甲烷部分氧化(POM)制合成气反应性能的影响. 研究发现, 在Co/HZSM-5催化剂中添加Mg助剂, 可有效地提高催化剂的催化活性和稳定性. 在750 ℃和空速1.0×10⁵ mL·h^-1·g^-1反应条件下, Co/Mg/HZSM-5在连续反应30 h的实验时间内催化活性稳定不变, 而Co/HZSM-5因其活性中心Co0转化生成CoAl2O4非活性相, 反应10 h后即迅速失活. 催化剂表征结果表明, 在Co/Mg/HZSM-5催化剂中钴物种除以Co3O4存在外, 一部分钴物种还与Mg助剂发生强相互作用生成较难还原的MgCo2O4, 由此导致还原后钴金属的分散度较高. 关联催化剂表征和活性评价结果, 讨论了催化剂结构与性能之间的关系.     

一维链状锰配位聚合物{[Mn(4，4′-bipy)(2，4，6-TMBA)2(H2O)2]·(H2O)2·(4，4′-bipy)}n的合成、晶体结构及电化学性质

配位聚合物由于其具有明确有序的一维或多维微观结构以及优异独特的宏观特性,在催化、光学材料、信息存储等领域具有广泛潜在的应用前景[1～3].     

A Microporous Hydrogen-Bonded Organic Framework Based on Hydrogen-Bonding Tetramers for Efficient Xe/Kr Separation

Hydrogen-bonded organic frameworks (HOFs) have been emerging as a new type of very promising microporous materials for gas separation and purification, but few HOFs structures constructed through hydrogen-bonding tetramers have been explored in this field. Herein, we report the first microporous HOF (termed as HOF-FJU-46) afforded by hydrogen-bonding tetramers with 4-fold interpenetrated diamond networks, which shows excellent chemical and thermal stability. What's more, activated HOF-FJU-46 exhibits the highest xenon (Xe) uptake of 2.51 mmol g⁻¹ and xenon/krypton (Kr) selectivity of 19.9 at the ambient condition among the reported HOFs up to date. Dynamic breakthrough tests confirmed the excellent Xe/Kr separation of HOF-FJU-46a, showing high Kr productivity (110 mL g⁻¹) and Xe uptake (1.29 mmol g⁻¹), as well as good recyclability. The single crystal X-ray diffraction and the molecular simulations revealed that the abundant accessible aromatic and pyrazole rings in the pore channels of HOF-FJU-46a can provide the multiple strong C−H⋅⋅⋅Xe interactions with Xe atoms.     

Continuous-Time Independent Edge-Markovian Random Graph Process

In this paper, the continuous-time independent edge-Markovian random graph process model is constructed. The authors also define the interval isolated nodes of the random graph process, study the distribution sequence of the number of isolated nodes and the probability of having no isolated nodes when the initial distribution of the random graph process is stationary distribution, derive the lower limit of the probability in which two arbitrary nodes are connected and the random graph is also connected, and prove that the random graph is almost everywhere connected when the number of nodes is sufficiently large.