Self-heating and trapping effects on the RF performance of GaN MESFETs

RF power performances of GaN MESFETs incorporating self-heating and trapping effects are reported. A physics-based large-signal model is used, which includes temperature dependences of transport and trapping parameters. Current collapse and dc-to-RF dispersion of output resistance and transconductance due to traps have been accounted for in the formulation. Calculated dc and pulsed I-V characteristics are in excellent agreement with the measured data. At 2 GHz, calculated maximum output power of a 0.3 /spl mu/m/spl times/100 /spl mu/m GaN MESFET is 22.8 dBm at the power gain of 6.1 dB and power-added efficiency of 28.5% are in excellent agreement with the corresponding measured values of 23 dBm, 5.8 dB, and 27.5%, respectively. Better thermal stability is observed for longer gate-length devices due to lower dissipation power density. At 2 GHz, gain compressions due to self-heating are 2.2, 1.9, and 0.75 dB for 0.30 /spl mu/m/spl times/100 /spl mu/m, 0.50 /spl mu/m/spl times/100 /spl mu/m, and 0.75 /spl mu/m/spl times/100 /spl mu/m GaN MESFETs, respectively. Significant increase in gain compression due to thermal effects is reported at elevated frequencies. At 2-GHz and 10-dBm output power, calculated third-order intermodulations (IM3s) of 0.30 /spl mu/m/spl times/100 /spl mu/m, 0.50 /spl mu/m/spl times/100 /spl mu/m, and 0.75 /spl mu/m/spl times/100 /spl mu/m GaN MESFETs are -61, -54, and - 45 dBc, respectively. For the same devices, the IM3 increases by 9, 6, and 3 dBc due to self-heating effects, respectively. Due to self-heating effects, the output referred third-order intercept point decreases by 4 dBm in a 0.30 /spl mu/m/spl times/100 /spl mu/m device.     

Early voltage in double heterojunction bipolar transistors

The Early voltage for abrupt double heterojunction bipolar transistors (DHBTs) has been calculated by using an effective junction velocity (S_c) at the base-collector heterojunction. S_c is obtained by self-consistently partitioning thermionic and quantum mechanical tunneling currents. Unlike single heterojunction bipolar transistors (SHBTs), the Early voltage varies very rapidly at low reverse bias and approaches the SHBT-limit at sufficiently high reverse bias. This is attributed to the presence of an energy barrier at the b-c heterojunction     

Interaction of a Surface-Active Ionic Liquid with an Antidepressant Drug: Micellization and Spectroscopic Studies

The interaction of the antidepressant drug nortriptyline hydrochloride (NOT) with the surface-active ionic liquid (SAIL), 1-decyl-3-methylimidazolium chloride, [C₁₀mim][Cl], has been studied using multiple techniques, including conductometric titration, tensiometric, fluorometric, dynamic light scattering and UV–visible spectrophotometric measurements. There is a significant decrease in the cmc of SAIL on the addition of the drug NOT, indicating adsorption of drug molecules in the outer portion of the micelle. In the present study, the values of the packing parameter, P, lie in the range of 0–0.3, which suggests that the micelles formed are spherical in nature. More negative values of the standard Gibbs energy of adsorption, \( \Delta G_{\text{ad}}^{ \circ } \), compared to \( \Delta G_{\text{m}}^{ \circ } \) support our contention that adsorption of SAIL on the air-solution interface is relatively more favorable than its micellization in the presence of NOT. Fluorescence and DLS studies indicate that the aggregation number, N_agg, and hydrodynamic radius of SAIL increase with increase in concentration of NOT. The UV–visible spectroscopic study confirms the formation of a new complex between SAIL and NOT; this is also supported by the negative Gibbs energy of complexation.     

Effect of intercell interference on cell boundary users in three‐cell and seven‐cell HetCN

Indoor and cell‐edge coverage has been a major issue of concern for predeployed traditional macrocell (MC)–based homogeneous cellular network. Moreover, with the extensive increase of mobile users and developments of smart and highly specified devices, user demands and activities have led to huge cellular traffic. The key solutions to these that include network upgradation, overlaying of small cells (SCs), and scaling of resources have turned out to be the major causes for intercell interference (ICI) and energy‐efficiency degradation in heterogeneous cellular networks (HetCNs). In this paper, authors have tried to analyze the downlink performance metrics of cell boundary users with MCs overlaying SCs for three‐cell circular and seven‐cell sectorized networks through frequency reuse (FR) schemes. This paper also discusses the impact of ICI being encountered by users and the effect of SCs on the energy efficiency of the network. The locations for SCs are perceived where user density is large and demands high data rate such as at hot‐spot (HS) areas, railway stations, shopping malls, working farms, and organization. The performance metrics sum rate, average user throughput, and energy efficiency are compared by employing FR‐1 (full spectrum) and FR‐3 (three subbands) among MCs and deployed SCs. For both scenarios, simulation results and analyses depict that without SCs, utilization of FR‐1 results in performance degradation due to ICI effects. However, the downlink performance of cell boundary user and energy efficiency of the network could be enhanced by overlaying SCs near cell boundaries of preexisting MCs along with the allocation of FR‐1.     

Ethyl (6aRS,8RS,12bRS)‐6‐oxo‐8‐phenyl‐6a,7,8,12b‐tetra­hydro‐6H‐benzo­[b]naphtho­[1,2‐d]­pyran‐6a‐carboxylate

In the title compound, C₂₆H₂₂O₄, the pyran­one ring adopts a twisted boat conformation, while the cyclo­hexane ring is close to an envelope conformation. The dihedral angle between the mean planes of the coumarin and naphthalene systems is 78.8 (1)°. The attached phenyl ring is in an equatorial position with respect to the cyclo­hexane ring.     

Potentiometric determination of free acidity and uranium in uranyl nitrate solutions

Free acid and uranium in uranyl nitrate solutions have been determined potentiometrically using Na₂SO₄–NaOH, Na₂SO₄–Na₂CO₃ and (NH₄)₂SO₄–NaOH complexant-titrant combinations. The overall recovery of nitric acid varies in the range of 95.25 to 118.5%, depending upon the acid as well as the total uranium present, while that of uranium always a positive bias ranging from 100.2 to 106.4%. The results have been discussed in light of recent available data. It has been concluded that all the complexant-titrant combinations studied provide similar results.     

Calculating binary and ternary multiphase equilibria: extensions of the integral area method

The area method was proposed in 1992 to calculate binary and ternary 2-phase equilibria. In its integral form, the method provides both the necessary and sufficient conditions required for the determination of the global minimum reduced Gibbs energy of mixing (Φ). The method has since been applied to the calculation of both pure component and ternary multiphase equilibria in a differential form. However, the extension of the original (2 point) integral area method to the direct calculation of both binary and ternary multiphase equilibria has not been completed. Direct 3 point and modified 2 point search methods have therefore been developed here and used to estimate the phase compositions of a representative binary vapour-liquid-liquid system. The 2 point area method principle has been extended and applied to the calculation of ternary multiphase equilibria using a net volume approach. However, this volume method was found to fail due to an underlying inconsistency in the bounding of the integrated Φ surface by the trial 3-phase region. A new method is proposed that overcomes this problem by minimising the area of intersection between a tangent plane and the Φ surface. This new method has successfully calculated the 3-phase compositions of two simple test systems from a variety of initial mixture starting points.     

A ternary complex of aqua(18‐crown‐6)bis(o‐nitrophenolato)barium(II), the triaqua(18‐crown‐6)(o‐nitrophenolato)barium(II) cation and the o‐nitrophenolate anion

In the title compound [systematic name: tri­aqua(1,4,7,10,13,16‐hexaoxa­cyclo­octa­decane‐κ⁶O)(2‐nitro­phenolato‐κO)­barium(II)–aqua(1,4,7,10,13,16‐hexaoxa­cyclo­octa­decane‐κ⁶O)‐ bis(2‐nitro­phenolato‐κ²O,O′)­barium(II)–2‐nitro­phenolate (1/1/1)], [Ba(C₁₂H₂₄O₆)(C₆H₄NO₃)(H₂O)₃][Ba(C₁₂H₂₄O₆)(C₆H₄NO₃)₂(H₂O)](C₆H₄NO₃), the two Ba^II atoms encapsulated by the 18‐crown‐6 rings have different coordinations. Although both Ba^II atoms are coordinated to the six O atoms of the crowns, in the neutral moiety, the Ba^II atom is coordinated to one terminal O atom from a water mol­ecule, two phenolate O atoms and two nitro‐group O atoms, while in the cationic moiety, the Ba^II atom is coordinated to three terminal O atoms from water mol­ecules and one phenolate O atom. Both the crowns are eclipsed and translated along the b direction. In the asymmetric unit, the three components are interconnected by four O—H?O interactions. The packing is stabilized by two intermolecular C—H?O interactions and by one O—H?O interaction.     

Wedges I

The wedge problem, that is, the propagation of radiation or particles in the presence of a wedge, is examined in different contexts. Generally, the paper follows the historical order from Sommerfeld's early work to recent stochastic results—hindsights and new results being woven in as appropriate. In each context, identifying the relevant mathematical problem has been the key to the solution. Thus each section can be given both a physics and a mathematics title: Section 2: diffraction by reflecting wedge; boundary value problem of differential equations; solutions defined on mutiply connected spaces. Section 3: geometrical theory of diffraction; identificiation of function spaces. Section 4: path integral solutions; path integration on multiply connected spaces; asymptotics on the boundaries of function spaces. Section 5: probing the shape of the wedge and the roughness of its surface; stochastic calculus. Several propagators and Green functions are given explicitly, some old ones and some new ones. They include the knife-edge propagator for Dirichlet and Neumann boundary conditions, the absorbing knife edge propagator, the wedge propagators, the propagator for a free particle on a -sheeted Riemann surface, the Dirichlet and the Neumann wedge Green function.Supported in part by NSF grant PHY84-04931.Supported in part by SERC grant GR/D 15911.Supported in part by a NSERC (Canada) Fellowship.Supported in part by SERC grant B/83301669.