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101.
102.
A Phosphorescent Platinum(II) Bipyridyl Supramolecular Polymer Based on Quadruple Hydrogen Bonds
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Fang‐Wei Liu Dr. Li‐Ya Niu Prof. Yong Chen Prof. Vaidhyanathan Ramamurthy Prof. Li‐Zhu Wu Prof. Chen‐Ho Tung Prof. Yu‐Zhe Chen Prof. Qing‐Zheng Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(50):18132-18139
A platinum(II) bipyridyl complex bearing bis‐ureidopyrimidinone (Pt‐bisUPy) has been designed and its self‐assembling behavior has been thoroughly investigated by 1H NMR, DOSY NMR, Ubbelohde viscometry analysis, UV/Vis, and emission spectroscopies. Pt‐bisUPy underwent concentration‐dependent ring‐chain polymerization in apolar solvents. Hydrogen‐bonding interactions play an important role during the formation of the supramolecular polymers. Hydrogen‐bonded supramolecular polymers were transformed to nanoparticles in water through the miniemulsion method. These nanoparticles showed strong π–π excimeric emission. Metal‐metal‐to‐ligand charge transfer (MMLCT) from Pt–Pt interactions was not significant in the emission spectrum. The phosphorescence of the nanoparticle persisted even under aerobic conditions. The triplet state of these phosphorescent nanomaterials were long‐lived and possessed moderate emission quantum yields. Furthermore, the low toxicity of these materials promises a place for them in in vitro and in vivo bioimaging. 相似文献
103.
Cong-Hua Xie Wei-Wei Qiao Zhe Liu Wen-Hao Ying 《Signal, Image and Video Processing》2017,11(4):705-712
Haze is one of the major factors that degrade outdoor images, and dehazing becomes an important issue in many applications. In order to address the problems of being unsmooth and the absence of neighbor information for the transmission estimation under Dark Channel Prior (DCP) framework, we proposed a new improved method using Kernel Regression Model (KRM) on local neighbor data. Firstly, the initial transmission in atmospheric light model is estimated by DCP. Secondly, the transmission is refined according to KRM. Experimental results on synthetic and real images show that our method can address this problem and has better dehazing results than several state-of-the-art methods. 相似文献
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This paper puts forward a new method to solve the electromagnetic parabolic equation (EMPE) by taking the vertically-layered inhomogeneous characteristics of the atmospheric refractive index into account. First, the Fourier transform and the convo- lution theorem are employed, and the second-order partial differential equation, i.e., the EMPE, in the height space is transformed into first-order constant coefficient differential equations in the frequency space. Then, by use of the lower triangular characteristics of the coefficient matrix, the numerical solutions are designed. Through constructing ana- lytical solutions to the EMPE, the feasibility of the new method is validated. Finally, the numerical solutions to the new method are compared with those of the commonly used split-step Fourier algorithm. 相似文献
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Lei Yang Zhe Chen Fuliang Yin 《AEUE-International Journal of Electronics and Communications》2012,66(1):89-92
In this paper, a cyclo-energy detector is proposed for the spectrum sensing problem based on the cyclostationary signal analysis. The proposed detector can determine the existence of primary user by estimating the primary user's received power according to the cyclostationarity features of the secondary user. By using this detector, the secondary user does not need to stop transmitting signals when sensing the frequency spectrum. Simulation results are presented to confirm the performance of the proposed detector. 相似文献
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In this paper, we study the system of strong vector quasi-equilibrium problems without assuming that the dual of the ordering cone has a weak* compact base. We show the existence and essential components of solution set for system of strong vector quasi-equilibrium problems by defining the best-reply mapping. 相似文献