全文获取类型
收费全文 | 138555篇 |
免费 | 19996篇 |
国内免费 | 15879篇 |
专业分类
化学 | 73560篇 |
晶体学 | 1219篇 |
力学 | 5986篇 |
综合类 | 703篇 |
数学 | 12778篇 |
物理学 | 40266篇 |
无线电 | 39918篇 |
出版年
2024年 | 567篇 |
2023年 | 3189篇 |
2022年 | 4270篇 |
2021年 | 5411篇 |
2020年 | 5290篇 |
2019年 | 4772篇 |
2018年 | 4500篇 |
2017年 | 4272篇 |
2016年 | 5961篇 |
2015年 | 6353篇 |
2014年 | 7775篇 |
2013年 | 9946篇 |
2012年 | 11584篇 |
2011年 | 11791篇 |
2010年 | 8812篇 |
2009年 | 8698篇 |
2008年 | 8972篇 |
2007年 | 8121篇 |
2006年 | 7733篇 |
2005年 | 6775篇 |
2004年 | 4942篇 |
2003年 | 4100篇 |
2002年 | 3709篇 |
2001年 | 3168篇 |
2000年 | 2901篇 |
1999年 | 2966篇 |
1998年 | 2518篇 |
1997年 | 2184篇 |
1996年 | 2157篇 |
1995年 | 1908篇 |
1994年 | 1623篇 |
1993年 | 1347篇 |
1992年 | 1183篇 |
1991年 | 998篇 |
1990年 | 832篇 |
1989年 | 595篇 |
1988年 | 468篇 |
1987年 | 386篇 |
1986年 | 386篇 |
1985年 | 297篇 |
1984年 | 226篇 |
1983年 | 194篇 |
1982年 | 143篇 |
1981年 | 84篇 |
1980年 | 68篇 |
1979年 | 27篇 |
1978年 | 28篇 |
1976年 | 24篇 |
1975年 | 23篇 |
1957年 | 27篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
铝电解电容器用橡皮塞中铁的测定 总被引:1,自引:0,他引:1
主要研究了用硫氰酸钾作显色剂,用分光光度法测定橡皮塞中铁含量的方法。并对国产和进口橡皮塞做了比较,为铝电解电容器质量水平的提高提供一条新思路。 相似文献
102.
103.
Z P Li C S Tang J Y Su 《Science in China. Series B, Chemistry, life sciences & earth sciences》1991,34(5):599-605
Results from a systematic experiment on isolated perfused rat heart and isolated myocytes of adult rat showed that the mechanism of calcium influx during myocardial ischemia-reperfusion is due to the development of intracellular sodium overload during ischemic period; on reperfusion, the high intracellular Na+ content activated the reverse direction of Na(+)-Ca2+ exchange over myocardial sarcolemma (SL), thus a large quantity of extracellular Ca2+ fluxed over the SL to the intracellular space, forming a condition of intracellular Ca2+ overload, which leads to irreversible damage of the myocardium. 相似文献
104.
Least-squares finite difference (LSFD) method, one of mesh-free methods, is used to solve slider air bearings problem through discritizing the generalized Reynolds equation into nonlinear systems of algebraic equations. Two approximation schemes for the linearization of these equations are presented and compared. And, some new techniques to search supporting points for the reference node in the mesh-free method were proposed and explored. Therefore, these improvements eliminate some potential limitation of the LSFD method previously published and further facilitate its employment in complex slider models. Advanced step slider as an example of negative pressure sliders is simulated and verified using the improved LSFD mesh-free method in head disk systems. 相似文献
105.
J. A. Ratto Paul T. Inglefield R. A. Rutowski K.-L. Li Alan Anthony Jones Ajoy K. Roy 《Journal of Polymer Science.Polymer Physics》1987,25(7):1419-1430
Carbon-13 and proton spin-lattice relaxation times were measured at two field strengths on solutions 10% by weight of two polycarbonates in C2D2Cl4 from ?20 to +120°C. The first polycarbonate is an asymmetrically substituted form with one chlorine on one of the two phenylene aromatic rings of the bisphenol unit, whereas the second polycarbonate is symmetrically substituted with two chlorines on each of the two rings. The nuclear spin relaxation data are interpreted in terms of several local motions likely in these polymers. Segmental motion was described by the Hall–Helfand correlation function. Segmental motion in the monosubstituted polycarbonate is somewhat slower than in unsubstituted polycarbonate, whereas segmental motion in the tetrasubstituted polycarbonate is considerably slower. Phenylene ring rotation is observed in unsubstituted polycarbonate and in the monosubstituted polycarbonate above 40°C. Below 40°C in the monosubstituted species, and at all temperatures in the tetrasubstituted species, ring rotation is replaced by ring libration as the predominant motion contributing to spin lattice relaxation. In addition, the rotational motion of the two types of rings in the asymmetric monosubstituted form are very similar although not identical. The substituted ring is slightly less mobile than the rings of unsubstituted polycarbonate. This indicates a strong coupling of ring motion, although the coupling leads to less than synchronous motion. Methyl group rotation is present in both polymers and is little affected by the various structural modifications. 相似文献
106.
Jian-Shu Li 《Mathematische Annalen》1992,292(1):747-761
Supported in part by NSF grant No. DMS-9003999 相似文献
107.
InAs channel field-effect transistors of 1-μm gate length were grown by molecular beam epitaxy and observed to operate at channel electric fields (20 kV/cm) higher than previously demonstrated and several times greater than the threshold for impact ionization in bulk InAs. Voltage gains on the order of 10 were observed with transconductances as high as 414 mS/mm and output conductances as low as 33 mS/mm. These voltage gains are comparable to those of GaAs-based devices and are the highest observed for InAs channel devices. The results demonstrate the potential for practical room-temperature operation of InAs FETs 相似文献
108.
109.
W. Li J.B. Heroux H. Shao W.I. Wang 《Photonics Technology Letters, IEEE》2005,17(3):531-533
Strain-compensated InGaAsSb-AlGaAsSb quantum-well (QW) lasers emitting near 2.5 /spl mu/m have been grown by solid-source molecular beam epitaxy. The relatively high arsenic composition causing a tensile strain in the Al/sub 0.25/GaAs/sub 0.08/Sb barriers lowers the valence band edge and the hole energy level, leading to an increased hole confinement and improved laser performance. A 60% external differential efficiency in pulsed mode was achieved for 1000-/spl mu/m-long lasers emitting at 2.43 /spl mu/m. A characteristic temperature T/sub 0/ as high as 163 K and a lasing-wavelength temperature dependence of 1.02 nm//spl deg/C were obtained at room temperature. For 2000 /spl times/ 200 /spl mu/m/sup 2/ broad-area three-QW lasers without lateral current confinement, a low pulsed threshold of 275 A/cm/sup 2/ was measured. 相似文献
110.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献