Non-destructive analysis of archeological samples by energy-dispersive X-ray fluorescence

Summary A non-destructive method is described for the determination of major and minor constituents in archeological specimens by energy-dispersive X-ray fluorescence. Homogeneity tests are made by measuring at various sites of the specimen. In the same way, mean values are obtained for inhomogeneous specimen without taking samples. For calibration, powder standards are used. In case of the determination of elements with numbers up to 14 (Si) a vacuum chamber is used and the dimensions of the specimens are limited by the dimensions of that vacuum chamber, whereas for the determination of elements from K up to U specimens of any size, form or weight are suitable.

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Zerstörungsfreie Analyse von archäologischen Proben mit Hilfe der Energie-dispersiven Röntgenfluorescenzanalyse

Zusammenfassung Eine zerstörungsfreie Methode für die Bestimmung von Haupt- und Nebenbestandteilen in archäologischen Proben mit Hilfe der Energie-dispersiven Röntgenfluorescenzanalyse wird beschrieben. Für Homogenitätstests wird an mehreren Stellen der Probe gemessen. In der gleichen Weise werden für inhomogene Proben Mittelwerte erhalten ohne Probenahme. Für die Eichung werden Pulverstandards verwendet. Im Falle der Bestimmung von Elementen mit Ordnungszahlen bis 14 (Si) wird eine Vakuumkammer eingesetzt, und die Dimensionen der Proben sind durch die Dimensionen dieser Vakuumkammer begrenzt, während für die Bestimmung der Elemente K bis U Proben jeder Größe, jeder Form oder jeden Gewichts verwendbar sind.

     

Korrosionstests an magnetischen Schichten und deren Beurteilung mit Hilfe ausgew?hlter oberfl?chenanalytischer Verfahren

Summary Besides functional behaviour of coatings their resistivity against corroding attack is a crucial criterion for quality. The application of special corroding and abrading tests yields after short times predictions about stability of the product in practical use. A number of tests have been applied to thin magnetic storage media. Besides tests of function and visual observations with light- and scanning electron microscopes, AES- and XPS-investigations were applied to discuss corrosion resistivity.     

Characterization of Flow in Intravenous Catheters

The pressure-flow (P-F) relationship in intravenous catheters is shown to be represented by the predictive model P = RLF + RTF2. The pressure loss due to F, calculated from experimental data, was found to equal the expected Poiseuille laminar flow loss. Pressure loss due to F2 was found to be the sum of turbulent P losses due to entrance length flow disturbance, kinetic energy at the outflow, and minor shape change losses. Analysis of the flow capabilities of intravenous catheters can be used to evaluate suitability for specific intravenous infusion needs.     

Spurenbestimmung von Blei, Cadmium und Mangan in Honigen und Zuckern

Ohne Zusammenfassung

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Trace analysis of lead, cadmium and manganese in honey and sugar

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Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung.     

Quadratic differentials in problems of the product of inner radii of nonoverlapping domains

We study applications of the theory of quadratic differentials to the solution of new extremal problems of nonoverlapping domains with free poles on rays and generalize known results to a certain class of open sets. __________ Translated from Neliniini Kolyvannya, Vol. 10, No. 4, pp. 435–442, October–December, 2007.     

UV–visible emission in Tb–Yb codoped tellurite glass on 980-nm excitation

UV–visible upconversion emission from terbium in a Tb–Yb codoped tellurite glass has been observed on 980-nm excitation. The ultraviolet and violet upconversion emissions involve three photons and the blue, green, yellow, and red emissions arise due to two incident photons. The mechanism involved in these emissions is discussed. The effects of doping concentration and of the sample temperature on the upconversion emissions have also been studied. PACS 74.25.Gz; 42.70.Hj; 73.61.Jc; 76.30.Kg; 42.70.Ce     

Thermodynamic study of a series lithium β-diketonates

Thermal behaviour of a series of lithium β-diketonates: Li(dpm) (dpm=dipivaloylmethanate (2,2,6,6-tetramethylheptane-3,5- dionate)), Li(pta) (pta=pivaloyltrifluoracetonate (2,2-dimethyl-6,6,6-trifluoro-3,5-hexanedionate)), Li(tfa) (tfa=trifluoracetylacetonate (1,1,1-trifluoro-2,4-pentandionate)), Li(hfa) (hfa=hexafluoracetylacetonate (1,1,1,5,5,5-hexafluoro-2,4-pentandionate)) has been investigated. Gas phase composition of these complexes has been established. Temperature dependences of vapor pressure of lithium compounds were obtained by static and dynamic methods, and thermodynamic parameters were calculated. Dependence of compound volatility on ligand structure is shown. For Li(dpm) detailed investigation has been done by differential scanning calorimetry (DSC).     

A compact full MMIC module for Ku-band phase-lockedoscillators

A compact Ku-band phase-locked oscillator module has been developed in a full MMIC (monolithic microwave integrated circuit) configuration. The module includes an MMIC voltage-controlled oscillator, an analog frequency divider, and interstage amplifiers. The constituent monolithic chips are integrated in a very small single-package module and operate at the target frequencies without any external trimming or matching network. The oscillator is tuned more than 1 GHz with a constant output amplitude. The frequency-divided output is also obtained over the whole tuning range. Spurious output is not found at any frequency up to 22 GHz. In spite of the very low-Q factor of GaAs monolithic circuitry, the oscillator phase noise exhibited is less than -80 dBc/Hz, due to the high-gain, high-speed phase lock