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51.
采用热处理方法提高MEH-PPV单层聚合物有机发光二极管发光性能的研究 总被引:2,自引:1,他引:1
对以MEH-PPV为发光层的单层聚合物有机发光二极管(OLED)器件在最佳条件下进行真空热处理,并用金相显微镜观察施加电压后器件的阴极表面形貌。发现处理后的器件阴极表面的气泡及黑斑明显减少。器件的发光性能显著提高。与未经处理的器件相比,最大相对发光强度提高了一个数量级、启亮电压降低了2.0V,半寿命提高了12.7倍。初步分析表明热处理方法提高器件发光性能的主要原因在于有效地减少了器件在工作过程中由于焦耳热产生的某些气体,从而减少阴极表面气泡及黑斑的出现,另一方面,热处理方法也增强了有机发光层与阴极接触界面的结合力,提高电子注入水平。 相似文献
52.
Juan F García-Reyes Pilar Ortega-Barrales Antonio Molina-Díaz 《Analytical sciences》2007,23(4):423-428
A combined approach based on solid-phase optosensing and multicommutation principles has been applied to develop a method for the simultaneous analysis of two pharmaceuticals (naproxen and salicylic acid) in biological fluids. The multicommuted flow-through optosensor was based on direct native fluorescence measurements of both analgesics using a non-polar sorbent (C18 silica gel) as a solid sensing zone. The flow system was controlled by Java-written home-made software and designed using three-way solenoid valves for an independent automated manipulation of sample and carrier solutions. Using an optimized sampling time, the method was calibrated in the range of 1 - 25 and 5 - 200 ng mL(-1). The obtained detection limits were 0.3 and 1.3 ng mL(-1) for naproxen and salicylic acid, respectively, with RSD (%) values of better than 2% for both analytes. The proposed methodology was successfully applied to urine, serum and pharmaceutical preparations. Recovery percentages ranging from 96.1 to 104% were obtained for both analytes. 相似文献
53.
Manuel Barros 《Annals of Global Analysis and Geometry》1992,10(3):219-226
In this paper we deal with the following particular case of a weaker conjecture by B. Y. Chen: Are there 2-type Willmore surfaces in E 3? In particular we prove that the above question has a negative answer when the surface is the image under stereographic projection of a minimal surface in S 3. 相似文献
54.
本利用矩阵对的标准相关分解,得到了矩阵方程(A^TXB,B^TXB)=(C,D)反对称解存在的充分必要条件及通解表达式,同时给出了解关于已知矩阵的最佳逼近. 相似文献
55.
Enrique Bendito ngeles Carmona Andr s M. Encinas 《Applied Numerical Mathematics》2004,50(3-4):343-370
Our aim is to set the foundations of a discrete vectorial calculus on uniform n-dimensional grids, that can be easily reformulated on general irregular grids. As a key tool we first introduce the notion of tangent space to any grid node. Then we define the concepts of vector field, field of matrices and inner products on the space of grid functions and on the space of vector fields, mimicking the continuous setting. This allows us to obtain the discrete analogous of the basic first order differential operators, gradient and divergence, whose composition define the fundamental second order difference operator. As an application, we show that all difference schemes, with constant coefficients, for first and second order differential operators with constant coefficients can be seen as difference operators of the form
for suitable choices of q,
and
. In addition, we characterize special properties of the difference scheme, such as consistency, symmetry and positivity in terms of q,
and
. 相似文献
56.
利用熔融KOH和Co3O4在较低温度(480℃)下反应制备出K0.36CoO2,然后用高锰酸钾溶液和饱和的过硫酸钾溶液进行氧化处理.氧化的同时伴随有水分子嵌入.K0.36CoO2用高锰酸钾和过硫酸钾溶液处理后分别得到K0.12CoO2·0.8H2O和K0.16CO2·0.6H2O.这两种化合物都属于六角晶系,表现出金属行为,脱水后主相变为正交结构并且呈现出半导体特性.K0.16CoO2·0.6H2O在56K附近可能存在自旋玻璃转变行为或其他涨落.随着钾含量的减少和水含量的增多,样品的自旋玻璃行为受到抑制或发生磁性相分离.样品K0.12CoO2·0.8H2O在零场冷却和有场冷却曲线上的分叉现象基本上消失.还讨论了产生KxCoO2与NaxCoO2体系结构和物性差别的原因. 相似文献
57.
Enrique Casanovas 《Mathematical Logic Quarterly》2003,49(5):475-478
We prove a property of generic homogeneity of tuples starting an infinite indiscernible sequence in a simple theory and we use it to give a shorter proof of the Independence Theorem for Lascar strong types. We also characterize the relation of starting an infinite indiscernible sequence in terms of coheirs. 相似文献
58.
First order necessary conditions and duality results for general inexact nonlinear programming problems formulated in nonreflexive
spaces are obtained. The Dubovitskii–Milyutin approach is the main tool used. Particular cases of linear and convex programs
are also analyzed and some comments about a comparison of the obtained results with those existing in the literature are given. 相似文献
59.
Manuel Santos-Trigo 《ZDM》2007,39(5-6):523-536
Research programs in mathematical problem solving have evolved with the development and availability of computational tools. I review and discuss research programs that have influenced and shaped the development of mathematical education in Mexico and elsewhere. An overarching principle that distinguishes the problem solving approach to develop and learn mathematics is to conceptualize the discipline as a set of dilemmas or problems that need to be explored and solved in terms of mathematical resources and strategies. In this context, relevant questions that help structure and organize this paper include: What does it mean to learn mathematics in terms of problem solving? To what extent do research programs in problem solving orient curricular proposals? What types of instructional scenarios promote the students’ development of mathematical thinking based on problem solving? What type of reasoning do students develop as a result of using distinct computational tools in mathematical problem solving? 相似文献
60.
Three novel zinc complexes [Zn(dbsf)(H2O)2] ( 1 ), [Zn(dbsf)(2,2′‐bpy)(H2O)]·(i‐C3H7OH) ( 2 ) and [Zn(dbsf)(DMF)] ( 3 ) (H2dbsf = 4,4′‐dicarboxybiphenyl sulfone, 2,2′‐bpy = 2,2′‐bipyridine, i‐C3H7OH = iso‐propanol, DMF = N,N‐dimethylformamide) were first obtained and characterized by single crystal X‐ray crystallography. Although the results show that all the complexes 1–3 have one‐dimensional chains formed via coordination bonds, unique three‐dimensional supramolecular structures are formed due to different coordination modes and configuration of the dbsf2? ligand, hydrogen bonds and π–π interactions. Iso‐propanol molecules are in open channels of 2 while larger empty channels are formed in 3 . As compared with emission band of the free H2dbsf ligand, emission peaks of the complexes 1–3 are red‐shifted, and they show blue emission, which originates from enlarging conjugation upon coordination. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献