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141.
García-Álvarez J Díez J Gimeno J Seifried CM 《Chemical communications (Cambridge, England)》2011,47(22):6470-6472
Carbonyl rhenium(I) complexes are efficient catalysts for the regioselective isomerization of terminal propargylic alcohols into α,β-unsaturated aldehydes or ketones which can be used as an unprecedented recyclable catalytic system (up to 10 consecutive runs) in the ionic liquid [BMIM][PF(6)]. 相似文献
142.
Roselló-Merino M Díez J Conejero S 《Chemical communications (Cambridge, England)》2010,46(48):9247-9249
Pyridinium 2-carboxylates decompose thermally in the presence of a variety of late transition metal precursors to yield the corresponding 2-pyridylidene-like complexes. The mild reaction conditions and structural diversity that can be generated in the heterocyclic ring make this method an attractive alternative for the synthesis of 2-pyridylidene complexes. IR spectra of the Ir(i) carbonyl compounds [IrCl(NHC)(CO)(2)] indicate that these N-heterocyclic carbene ligands are among the strongest σ-electron donors. 相似文献
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Glria Esquius Josefina Pons Ramn Yez Josep Ros Xavier Solans Merc Font‐Bardia 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(2):m133-m134
In the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as μ‐bridges. The coordination of each RhI cation is completed by one cyclooctadiene (COD) ligand. It is shown that the average Rh—C(COD) distance is linearly dependent on the Rh—N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing. 相似文献
147.
Josefina CASASAYAS Patrícia FAISCA Ana NUNES 《NoDEA : Nonlinear Differential Equations and Applications》2003,10(1):119-131
148.
Luminescent Thermochromism of 2D Coordination Polymers Based on Copper(I) Halides with 4‐Hydroxythiophenol
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Dr. Javier Troyano Dr. Josefina Perles Dr. Pilar Amo‐Ochoa Dr. Jose Ignacio Martínez Prof. Maria Concepción Gimeno Dr. Vanesa Fernández‐Moreira Dr. Félix Zamora Prof. Salomé Delgado 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(50):18027-18035
Solvothermal reactions between copper(I) halides and 4‐mercaptophenol give rise to the formation of three coordination polymers with general formula [Cu3X(HT)2]n (X=Cl, 1 ; Br, 2 ; and I, 3 ). The structures of these coordination polymers have been determined by X‐ray diffraction at both room‐ and low temperature (110 K), showing a general shortening in Cu?S, Cu?X and Cu?Cu bond lengths at low temperatures. 1 and 2 are isostructural, consisting of layers in which the halogen ligands act as μ3‐bridges joining two Cu1 and one Cu2 atoms whereas in 3 the iodine ligands is as μ4‐mode but the layers are quasi‐isostructural with 1 or 2 . These compounds show a reversible thermochromic luminescence, with strong orange emission for 1 and 2 , but weaker for 3 at room temperature, whereas upon cooling at 77 K 1 and 2 show stronger yellow emission, and 3 displays stronger green emission. DFT calculations have been used to rationalize these observations. These results suggest a high potential for this novel and promising stimuli‐responsive materials. 相似文献
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Xavier Cetó Josefina Capdevila Anna Puig‐Pujol Manel del Valle 《Electroanalysis》2014,26(7):1504-1512
The application of an Electronic Tongue for the classification of cava samples based on their different ageing times is reported. As such, voltammetric responses were obtained from an array of six bulk‐modified graphite‐epoxy electrodes, which exhibited marked mix‐responses towards the different samples. Obtained responses were then preprocessed employing FFT and the resulting coefficients were input to a LDA model which allowed the classification of the samples according to its vintage time. Besides, a quantitative model employing ANNs was built for the prediction of the total amount of sugar present in the samples, a parameter also used to classify cava samples. 相似文献