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71.
We report the spontaneous dimerization process of the full-length Aβ42 proteins in water by using unguided, fully atomistic, explicit-water molecular dynamics simulations. Based on the thermodynamic analysis, we demonstrate that Aβ42 dimerization in water occurs via a two-step nucleation-accommodation mechanism driven by water-induced force and by protein internal force, respectively. 相似文献
72.
A family of quadrature rules for integration over tetrahedral volumes is developed. The underlying structure of the rules is based on the cubic close-packed (CCP) lattice arrangement using 1, 4, 10, 20, 35, and 56 quadrature points. The rules are characterized by rapid convergence, positive weights, and symmetry. Each rule is an optimal approximation in the sense that lower-order terms have zero contribution to the truncation error and the leading-order error term is minimized. Quadrature formulas up to order 9 are presented with relevant numerical examples. 相似文献
73.
Byoung S. Ham 《Entropy (Basel, Switzerland)》2022,24(10)
Over the last two decades, quantum memories have been intensively studied for potential applications of quantum repeaters in quantum networks. Various protocols have also been developed. To satisfy no noise echoes caused by spontaneous emission processes, a conventional two-pulse photon-echo scheme has been modified. The resulting methods include double-rephasing, ac Stark, dc Stark, controlled echo, and atomic frequency comb methods. In these methods, the main purpose of modification is to remove any chance of a population residual on the excited state during the rephasing process. Here, we investigate a typical Gaussian rephasing pulse-based double-rephasing photon-echo scheme. For a complete understanding of the coherence leakage by the Gaussian pulse itself, ensemble atoms are thoroughly investigated for all temporal components of the Gaussian pulse, whose maximum echo efficiency is 26% in amplitude, which is unacceptable for quantum memory applications. 相似文献
74.
Telecommunication Systems - Recently, multi-metric routing protocols have been proposed to enhance the performance of the typical single metric routing protocols in mobile ad-hoc networks.... 相似文献
75.
76.
This paper presents a new physical theory of oscillator phase noise. Built around the concept of phase diffusion, this work bridges the fundamental physics of noise and existing oscillator phase-noise theories. The virtual damping of an ensemble of oscillators is introduced as a measure of phase noise. The explanation of linewidth compression through virtual damping provides a unified view of resonators and oscillators. The direct correspondence between phase noise and the Einstein relation is demonstrated, which reveals the underlying physics of phase noise. The validity of the new approach is confirmed by consistent experimental agreement. 相似文献
77.
E. R. Eliel E. W. M. van der Ham Q. H. F. Vrehen G. W. 't Hooft M. Barmentlo J. M. Auerhammer A. F. G. van der Meer P. W. van Amersfoort 《Applied Physics A: Materials Science & Processing》1995,60(2):113-119
The use of a Free-Electron Laser (FEL) allows the study of (non)linear optical properties of materials over unsurpassed large spectral intervals. As an example, we report on the use of a FEL as the infrared source in spectroscopic infrared-visible Sum-Frequency Generation (SFG). Employing the extremely wide tunability of the Free-Electron Laser for Infrared eXperiments (FELIX) at Rijnhuizen, we have studied the frequency dependence of the nonlinear susceptibility for sumfrequency generation in gallium phosphide between 20 and 32 m in great detail. We have developed a shortpulse visible laser system that is highly synchronous with FELIX thereby creating a two-color setup that can be broadly applied. Resonantly enhanced SFG in alphaquartz has been used to study the relative timing stability of FELIX and the synchronized picosecond-laser system.Paper presented at the 129th WE-Hearaeus-Seminar on Surface studies by Nonlinear Laser Spectroscopies, Kassel, Germany, May 30 to June 1, 1994 相似文献
78.
Sehyun Lee Jae Young Jung Injoon Jang Daeil Choi Myeong Jae Lee Dong Wook Lee Jue-Hyuk Jang Jeong Hee Lee Haneul Jin Kyungmin Im Eungjun Lee Seung-hoon Kim Nam Dong Kim Soo-Hyoung Lee Yun Sik Kang Hee-Young Park Dongwon Chun Hyung Chul Ham Kug-Seung Lee Docheon Ahn Pil Kim Sung Jong Yoo 《Advanced functional materials》2021,31(16):2009241
Among the Pt group metals, Pd has been considered the most efficient for application in electrocatalysts as an alternative to Pt. Despite the comparable electrochemical activities of Pd and Pd-metal alloys, they are vulnerable to liquid acidic electrolytes, leading to degradation of catalytic activity. Pd–Ni alloys have been used to enhance catalytic activity because the electronic structure of Pd can be easily changed by adding Ni. In other studies, N atoms have been introduced for more stable M–Ni catalysts by inducing the formation of Ni4N species; however, the structural analysis and the role of nitrogen have not been fully understood yet. Herein, the Pd–Ni alloy nitride with a unique crystal structure shows a promising catalytic activity for oxygen reduction reaction (ORR). The nitride PdNi nanoparticles have a novel monolithic antiperovskite structure of chemical formula (PdxNi1−x)NNi3. The unique antiperovskite crystal (PdxNi1−x)NNi3 possesses superior ORR activity and stability, originating from the downshifted d-band center of the monolayer Pd/antiperovskite surface and the lower formation energy of the antiperovskite core nanocrystal. Consequently, (PdxNi1−x)NNi3, as a Pt-free Pd-based electrocatalyst, overcomes the stability issue of Pd under acidic conditions by achieving 99-times higher mass activity than commercial Pd/C, as shown by the durability test. 相似文献
79.
Kyu‐Seok Shim Jae‐Hyun Ham Baraka D. Sija Myung‐Sup Kim 《International Journal of Network Management》2017,27(5)
Recently, network traffic has become more complex and diverse because of the emergence of new applications and services. Therefore, the importance of application‐level traffic classification is increasing rapidly, and it has become a very popular research area. Although a lot of methods for traffic classification have been introduced in literature, they have some limitations to achieve an acceptable level of performance in real‐time application‐level traffic classification. In this paper, we propose a novel application‐level traffic classification method using payload size sequence signature. The proposed method generates unique payload size sequence signatures for each application using packet order, direction, and payload size of the first N packets in a flow and uses them to identify application traffic. The evaluation shows that this method can classify application traffic easily and quickly with high accuracy and completeness rates, over 99.93% and 93.45%, respectively. Furthermore, the method can classify each application traffic into its respective individual application. The evaluation shows that the method can classify all applications traffic, known and unknown (new) applications into their respective applications, and it can classify applications traffic that use the same application protocol or are encrypted into each other. 相似文献
80.
Cyclopropyl derivative of 2,6-di-tert-butylphenol is synthesized as a probe to investigate the mechanism of base-catalyzed autooxidation of phenol derivatives. Our study indicates that one electron reduction of molecular oxygen from phenolate gives phenoxyl radical 3, a key intermediate of autooxidation. The coupling of phenoxyl radical and superoxide radical gives peroxylate anion 4 and produces the final epoxy alcohol adduct 6. 相似文献