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961.
Jie Chao Yinan Zhang Dan Zhu Bing Liu Chengjun Cui Shao Su Chunhai Fan Lianhui Wang 《中国科学:化学(英文版)》2016,59(6):730-734
Hetero-assembling of spherical building blocks with well-defined spatial distribution holds great significance in developing chiral nanostructures. Herein, a strategy for hetero-assembling of gold nanoparticles(Au NPs) was demonstrated using rigid bifacial DNA origami as templates. By tuning the sizes and the fixed location of Au NPs on DNA origami, right-handed and left-handed Au NPs nanostructures were respectively constructed. Gel electrophoresis indicated the formation of the DNA origami-Au NPs complex and transmission electron microscopy(TEM) visually displayed the arrangement of Au NPs in these two chiral structures. The spatial configuration and 3D geometry of Au NPs were further illustrated by the stereographic TEM with tilting angles from ?30° to 30°. This strategy provides a universal approach to construct the asymmetrical 3D geometries, which may have potential applications in biomimicking and nanophotonics. 相似文献
962.
This paper describes the use of graphene oxide/silica modified with nitro‐substituted tris(indolyl)methane as a solid‐phase extraction sorbent for the determination of organic acids. The resultant graphene oxide/silica modified with nitro‐substituted tris(indolyl)methane was characterized by FTIR spectroscopy and adsorption experiments. Solid‐phase extraction parameters such as sorbent type, sample solution pH, sample loading rate, eluent salt concentration, eluent methanol concentration, elution rate, sample loading, and elution volume were optimized. The method showed good precision, accuracy, sensitivity, and linear response for organic acids analysis over a concentration range of 1–100 μg/L for benzoic acid, p‐methoxybenzoic acid, and salicylic acid and 5–100 μg/L for the remaining organic acids (cinnamic acid, p‐chlorobenzoic acid, and p‐bromobenzoic acid) with coefficients of determination (r2) of higher than 0.9957. Limits of detection from 0.50 to 1.0 μg/L for six organic acids were achieved. The developed method was successfully applied to determine organic acids in real samples. 相似文献
963.
A Colorimetric and Fluorimetric Chemodosimeter for Copper Ion Based on the Conversion of Dihydropyrazine to Pyrazine
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Dr. Junbo Li Shao Chen Pian Zhang Zilong Wang Guankui Long Dr. Rakish Ganguly Dr. Yongxin Li Prof. Dr. Qichun Zhang 《化学:亚洲杂志》2016,11(1):136-140
In this research, we successfully synthesized and fully characterized the new compound 5,8,13,16,21,24‐hex‐(triisopropylsilyl)ethynyl)‐6,23‐dihydro‐6,7,14,15,22,23‐hexaza‐trianthrylene ( HHATA , brown color in a mixed solvent of CH2Cl2/CH3CN 1:1, v/v, weakly blue fluorescent), which can be easily oxidized to 5,8,13,16,21,24‐hex‐(triisopropylsilyl)ethynyl)‐6,7,14,15,22,23‐hexazatrianthrylene ( HATA ) (yellow color in CH2Cl2/CH3CN 1:1, v/v), red fluorescent) by Cu2+ ions. This reaction only proceeds efficiently in the presence of Cu2+ ions when compared with other common metal ions such as Fe3+, Co2+, Mn2+, Hg2+, Ni2+, Pb2+, Ag+, Mg2+, Ca2+, K+, Na+, and Li+. Our result suggests that this reaction can be developed as an effective method for the detection of Cu2+ ions. 相似文献
964.
Hierarchical NiCo2S4 Nanotube@NiCo2S4 Nanosheet Arrays on Ni Foam for High‐Performance Supercapacitors
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Dr. Haichao Chen Si Chen Hongyan Shao Dr. Chao Li Dr. Meiqiang Fan Dr. Da Chen Dr. Guanglei Tian Prof. Dr. Kangying Shu 《化学:亚洲杂志》2016,11(2):248-255
Hierarchical NiCo2S4 nanotube@NiCo2S4 nanosheet arrays on Ni foam have been successfully synthesized. Owing to the unique hierarchical structure, enhanced capacitive performance can be attained. A specific capacitance up to 4.38 F cm?2 is attained at 5 mA cm?2, which is much higher than the specific capacitance values of NiCo2O4 nanosheet arrays, NiCo2S4 nanosheet arrays and NiCo2S4 nanotube arrays on Ni foam. The hierarchical NiCo2S4 nanostructure shows superior cycling stability; after 5000 cycles, the specific capacitance still maintains 3.5 F cm?2. In addition, through the morphology and crystal structure measurement after cycling stability test, it is found that the NiCo2S4 electroactive materials are gradually corroded; however, the NiCo2S4 phase can still be well‐maintained. Our results show that hierarchical NiCo2S4 nanostructures are suitable electroactive materials for high performance supercapacitors. 相似文献
965.
A series of novel tetrahydroimidazo[1,2-a]pyridine-5(1H)-one derivatives containing a electronegative pharmacophore(=CNO2) were synthesized via practical aza-ene reaction and characterized by 1H NMR, 13C NMR, 19F NMR and HRMS. Preliminary bioassays showed that some of the target compounds exhibited good insecticidal activity against brown planthopper(Nilaparvata lugens) and cowpea aphids(Aphis craccivora) at 500 mg L-1. Among them, compound 11h was active against brown planthopper at 100 mg L-1. The insecticidal activities varied significantly depending on the types and patterns of the substituents, which provided guidance for further investigation on structure modifications. 相似文献
966.
Lijuan Zhang Yuming Shi Hua Shao Qiuling Huang 《Journal of Difference Equations and Applications》2016,22(11):1747-1759
This paper focuses on chaos induced by weak A-coupled-expansion of non-autonomous discrete systems in compact subsets of metric spaces and in bounded and closed subsets of complete metric spaces, separately. A new concept of weak A-coupled-expansion for non-autonomous discrete systems, whose condition is weaker than that of A-coupled-expansion, is introduced, and several new criteria of chaos induced by weak A-coupled-expansion of non-autonomous discrete systems are established. By applying some close relationships between chaotic dynamical behaviours of the original system and its induced systems, two criteria of chaos are established. One example is provided for illustration. 相似文献
967.
Lanthanide‐Catalyzed Reversible Alkynyl Exchange by Carbon–Carbon Single‐Bond Cleavage Assisted by a Secondary Amino Group
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Yinlin Shao Fangjun Zhang Prof. Dr. Jie Zhang Prof. Dr. Xigeng Zhou 《Angewandte Chemie (International ed. in English)》2016,55(38):11485-11489
Lanthanide‐catalyzed alkynyl exchange through C?C single‐bond cleavage assisted by a secondary amino group is reported. A lanthanide amido complex is proposed as a key intermediate, which undergoes unprecedented reversible β‐alkynyl elimination followed by alkynyl exchange and imine reinsertion. The in situ homo‐ and cross‐dimerization of the liberated alkyne can serve as an additional driving force to shift the metathesis equilibrium to completion. This reaction is formally complementary to conventional alkyne metathesis and allows the selective transformation of internal propargylamines into those bearing different substituents on the alkyne terminus in moderate to excellent yields under operationally simple reaction conditions. 相似文献
968.
Superior Electrical Conductivity in Hydrogenated Layered Ternary Chalcogenide Nanosheets for Flexible All‐Solid‐State Supercapacitors
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Dr. Xin Hu Wei Shao Xudong Hang Dr. Xiaodong Zhang Prof. Wenguang Zhu Prof. Yi Xie 《Angewandte Chemie (International ed. in English)》2016,55(19):5733-5738
As the properties of ultrathin two‐dimensional (2D) crystals are strongly related to their electronic structures, more and more attempts were carried out to tune their electronic structures to meet the high standards for the construction of next‐generation smart electronics. Herein, for the first time, we show that the conductive nature of layered ternary chalcogenide with formula of Cu2WS4 can be switched from semiconducting to metallic by hydrogen incorporation, accompanied by a high increase in electrical conductivity. In detail, the room‐temperature electrical conductivity of hydrogenated‐Cu2WS4 nanosheet film was almost 1010 times higher than that of pristine bulk sample with a value of about 2.9×104 S m?1, which is among the best values for conductive 2D nanosheets. In addition, the metallicity in the hydrogenated‐Cu2WS4 is robust and can be retained under high‐temperature treatment. The fabricated all‐solid‐state flexible supercapacitor based on the hydrogenated‐Cu2WS4 nanosheet film shows promising electrochemical performances with capacitance of 583.3 F cm?3 at a current density of 0.31 A cm?3. This work not only offers a prototype material for the study of electronic structure regulation in 2D crystals, but also paves the way in searching for highly conductive electrodes. 相似文献
969.
970.
Shao Li Di Zhang Min Wang Saige Ma Jihong Liu Yufen Zhao Yong Ye 《Journal of fluorescence》2016,26(3):769-774
A novel FRET-based probe LS3 was designed and synthesized. As expected, it exhibited high selectivity and sensitivity for detecting Cu2+ over other commonly coexistent metal ions. The detection limit was measured to be 0.0423 μM for Cu2+, which can meet the selective requirements for practical application. In addition, the newly synthesized compound 3a/b have potential value of further synthesizing more analogous FRET-based probes. 相似文献