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51.
A novel and effective approach to sensitively determine serotonin, known as 5-hydroxytryptamine (5-HT), has been proposed based on a 5,5-ditetradecyl-2-(2-trimethylammonioethyl)-1,3-dioxane bromide (DTDB) self-assembled lipid bilayer membrane modified glassy carbon electrode (DTDB/GCE). A DTDB/GCE shows the strong electrocatalysis for the oxidation of 5-HT, with the peak potential shifted to less positive value of 0.376 V vs. SCE, and effectively eliminates the interference from ascorbic acid (AA), even in the presence of 100-fold concentration of AA. Differential pulse voltammetry (DPV) gave a linear current for 5-HT from 2.0 x 10(-7) to 1.0 x 10(-5) M. At the DTDB/GCE, the oxidation of 5-HT was controlled by the adsorption process; for 5-HT coexisting with DA, the competitive adsorption was observed. 相似文献
52.
The structure, morphology, and isothermal and nonisothermal crystallization of isotactic polypropylene/low‐molecular‐mass hydrocarbon resin blends (iPP/HR) (up to 20% in weight of HR) have been studied, using optical and electron microscopy, wide‐ and small‐angle X‐ray and differential scanning calorimetry. New structures and morphologies can be activated, using appropriate preparation and crystallization conditions and blend composition. For every composition and crystallization condition, iPP crystallizes in α‐form, with a spherulitic morphology. The size of iPP spherulites increases with resin content, whereas the long period decreases. In the range of crystallization temperatures investigated, HR modifies the birefringence of iPP spherulites, favoring the formation of radial lamellae and changing the ratio between tangential and radial lamellae. Spherulitic radial growth rates, overall crystallization rates, and melting temperatures are strongly affected by resin, monotonically decreasing with resin content. This confirms miscibility in the melt between the two components of the blends. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3368–3379, 2004 相似文献
53.
YAN Xiaomin ZHAO Lin SHAO Jianhui TAN Xin SONG Zhengxiao School of Chemical Engineering Technology Tianjin University Tianjin China Slichem Liquid Material Co. Ltd. Shijiazhuang China 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION Methionine, namely 2-amido-4-thiomethyl butyric acid with a structure of CH3SCH2CH2CHCOOH, is one of the essential amino acids and has two natural enantionmers, D and L-methionine. The mixture of L- and D-isomers can be used as analeptics or nutritive additives to maintain the equilibrium of amino acids of feed [1,2]. L-methionine can release active methyl and accelerate the synthesis of choline, which further speeds up the conversion of the lipid accumulated in liv… 相似文献
54.
NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
55.
Baker‘s yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently differentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products. 相似文献
56.
Thermal oxidation of polyethylene filled with dispersed copper and containing an amine antioxidant was studied. The concentration ranges in which the catalytic effect of the metal on the polymer oxidation or the stabilizing effect of the antioxidant prevails were determined. Under certain conditions, dispersed copper enhances the stabilizing effect of the antioxidant. 相似文献
57.
Silver and copper nanowires have been synthesized using a scalable method of AC electrodeposition into porous aluminum oxide templates, which produces gram quantities of metal nanowires ca. 25 nm in diameter and up to 5 and 10 μm in length for Ag and Cu, respectively. The nanowires have been used to prepare polystyrene nanocomposites by solution processing. Electrical resistivity measurements performed on polymer nanocomposites containing different volume fractions of metal indicate that low percolation thresholds of nanowires are attained between compositions of 0.25 and 0.75 vol %. 相似文献
58.
Shih-Kai Lee Mao-Chao Lin 《Communications, IEEE Transactions on》1995,43(5):1917-1925
We propose a hybrid ARQ scheme which uses QPSK modulation for the first transmission and BPSK modulation for retransmissions. The throughput performance of the proposed ARQ scheme is better that those of ARQ schemes purely using QPSK modulation or purely using BPSK modulation for transmissions. Furthermore, the proposed scheme does not require any operation of error correction as usually required in hybrid ARQ schemes. Therefore, the ARQ scheme proposed in this paper can be easily implemented 相似文献
59.
Han-Bin Lin Jung-Young Su Yu-Pin Liao Way-Seen Wang 《Quantum Electronics, IEEE Journal of》1995,31(6):1131-1139
By using micro-prisms, improved three-dimensional (3-D) bends of the embedded and buried waveguides of step-index profile are proposed. A simple phase compensation rule for the optimal design of the micro-prism is also presented. Through the simulation of 3-D semivectorial finite-difference beam propagation method, the transmission characteristics of the improved bends are shown to have been enhanced dramatically as compared with those of the conventional ones. Even for a bend angle of as large as 10°, the normalized transmitted power can still be greater than 95%. These results of 3-D bends are then compared with those of the two-dimensional (2-D) ones which are simplified from 3-D structures by the effective index method, and physical explanation of the discrepancy between the 3-D and 2-D results is introduced. The influences of waveguide structures and prism parameters on the transmission characteristics are discussed in detail. Some criteria for the design of large-angle low-loss 3-D improved bends are also accessed 相似文献
60.
Wen-Chau Liu Lih-Wen Laih Shiou-Ying Cheng Wen-Lung Chang Wei-Chou Wang Jing-Yuh Chen Po-Hung Lin 《Electron Devices, IEEE Transactions on》1998,45(2):373-379
In this paper, a new multiple negative-differential-resistance (MNDR) device based on a metal-insulator-semiconductor-insulator-metal (MISIM)-like structure with step-compositional InxGa1-x As quantum wells has been fabricated and demonstrated. The interesting MNDR phenomena are found in the current-voltage (I-V) characteristics of this device. At room temperature, the triple switching behaviours and quadruple stable operation states are obtained. In addition, the sixfold switching behaviors and a staircase-shaped I-V characteristic are observed at -105°C. A sequential carrier accumulation at InGaAs subwells and the potential lowering process are used to qualitatively explain the interesting MNDR phenomena. From the experimental results, it is shown that the studied device has good potential in multiple-valued logic applications 相似文献