Novel approach for the synthesis of Fe3O4@TiO2 core-shell microspheres and their application to the highly specific capture of phosphopeptides for MALDI-TOF MS analysis

A novel approach is proposed to synthesize Fe(3)O(4)@TiO(2) microspheres with a well-defined core-shell structure, and the synthesized Fe(3)O(4)@TiO(2) core-shell microspheres were successfully applied for the simple and fast enrichment of phosphopeptides via direct MALDI-TOF mass spectrometry analysis.     

High‐Performance All‐Polymer Photoresponse Devices Based on Acceptor–Acceptor Conjugated Polymers

Three acceptor–acceptor (A–A) type conjugated polymers based on isoindigo and naphthalene diimide/perylene diimide are designed and synthesized to study the effects of building blocks and alkyl chains on the polymer properties and performance of all‐polymer photoresponse devices. Variation of the building blocks and alkyl chains can influence the thermal, optical, and electrochemical properties of the polymers, as indicated by thermogravimetric analysis, differential scanning calorimetry, UV–vis, cyclic voltammetry, and density functional theory calculations. Based on the A–A type conjugated polymers, the most efficient all‐polymer photovoltaic cells are achieved with an efficiency of 2.68%, and the first all‐polymer photodetectors are constructed with high responsivity (0.12 A W^?1) and detectivity (1.2 × 10¹² Jones), comparable to those of the best fullerene based organic photodetectors and inorganic photodetectors. Photoluminescence spectra, charge transport properties, and morphology of blend films are investigated to elucidate the influence of polymeric structures on device performances. This contribution demonstrates a strategy of systematically tuning the polymeric structures to achieve high performance all‐polymer photoresponse devices.     

感应耦合等离子体刻蚀机二维放电模拟

为研究感应耦合等离子体(ICP)刻蚀机腔室与线圈结构以及工艺参数对等离子体分布均匀性的影响,基于商业软件CFD-ACE 中等离子体与电磁场等模块建立了ICP刻蚀机二维放电模型.仿真研究了典型工艺条件(1.33Pa,200W,200sccm)下氩等离子体电子温度与电子数密度的空间分布,对比了不同气压与功率条件下等离子体参数在硅片表面的一维分布.结果表明,电子数密度随气压与功率的增加而升高;电子温度随气压的增加而降低,随功率增加在较小范围内先降低再升高.通过分析屏蔽板对等离子体参数的影响,发现其有助于提高等离子体密度.进而发现屏蔽板的孔隙率越大,电子温度越高,电子数密度则越低.     

Adsorption of carbon dioxide of 1-site and 3-site models in pillared clays: a Gibbs ensemble Monte Carlo simulation

Adsorption behavior of carbon dioxide confined in pillared clays is analyzed by using constant pressure Gibbs ensemble Monte Carlo (GEMC) method. In our simulation, 1-site and 3-site models are used to represent carbon dioxide. At the 1-site model, carbon dioxide is described as a Lennard-Jones (LJ) sphere, while at the 3-site model, carbon dioxide is modeled as a three-sites linear chain represented by EPM2 potential considering the quadrapolar effect. The potential model from Yi et al. for pillared clays is used to emphasize its quasi two-dimensional structure. Comparing the calculated results from the 1-site and the 3-site models at T=228.15 and 258.15 K, we observe that the adsorption amount from the two models is the same basically. However, the local density presents a significant difference, because the shoulder in the main peak near the wall from 3-site model can reflect the orientation of carbon dioxide. Accordingly, in the systematical investigation to explore the effect of porosity and pore width on the adsorption of carbon dioxide in pillared clays, the 3-site model was only used. We observe that for a narrow pore of H=1.02 nm, each isotherm shape displays type I curve, suggesting that it is not inflected by the porosity. However, for the larger pores of H=1.70 and H=2.38 nm, the increase of the porosity alters the shape of adsorption isotherms from a simple linear relation to the first order jump, indicating that the porosity is of very important factor to affect adsorption and phase behavior of fluids confined in pillared clays. The excess adsorptions of carbon dioxide at supercritical temperatures of T=323.15 and 348.15 K are also investigated. We find that the maximum exists for each excess isotherm, and the optimal pressure corresponding to the maximum increases with the pore width. However, the porosity has no significant effect on the optimal pressure.     

中间段光折变晶体材料参数的测量原理

提出了中间段光折变晶体材料参数的测量原理。利用公开报道的关于Ce:KNSBN双光束耦合的实验数据计算了该晶体的材料参数。实验与理论结果相吻合。     

输入物面上的位相型元件的用途及其制作

阐述与输入物面密贴的位相型光学元件;条形散斑屏,随机相移器和位相光栅在光学全息及信息处理中的重要应用。分析了三类元件在应用和制作 中的共性问题及各自特点;针对这类银盐板遇光后黑化失效的弊病提出了避免的方法与工艺之改进。     

含ER流体板结构的振动特性研究

本文制作了含电流变体夹层梁和模拟飞机蒙皮结构的含电流变体加筋层合板,采用响应幅频法,测试了在不同电场强度梁和层合加筋板结构各阶固有频率和振幅的变化;并着重测试了加筋层合板结构在改变板材料、电流变体作用面积等条件时各阶频响特性的变化。实验结果表明,随着电场强度的增加,夹层梁的频响特性有很大变化;而层合板的固有频率变化不大,但振幅却有显著变化,其中铝－层合加筋板的频响幅值的变化率达到５０．１％。     

锅炉炉内含尘气流冲刷管束换热器的流动和传热特性研究

本文通过模型计算和实验对于含尘烟气冲刷圆管和螺旋肋片管的管束换热器的流动和传热特性进行研究。结果表明,换热管束的形式对颗粒的传热强化作用具有明显的影响。颗粒对圆管的传热强化作用必须予以考虑,而对于螺旋肋片管则可忽略。     

水合肼还原重量法测定银

样品经过硝酸分解后,用过量的氨水分离铅、铁、铝等金属离子,用EDTA掩蔽铜、锌和其他残留的金属离子,用水合肼作还原剂,将银还原成单质沉淀,过滤,洗涤,灼烧,恒重。该方法用于实际样品测定,结果与其他方法测定值一致,误差均在允许范围内;分别对银含量为2.54%和10.00%的样品重复测定12次,相对标准偏差（RSD）分别为1.50%和0.64%,此方法适用于1%以上银含量的测定。     

ITO材料在减反射膜设计中的应用

改变ITO材料通常作为透明导电膜单独使用的状况,将其作为减反射膜系中的一层,能够在很大程度上增加ITO透明导电膜在可见光部分的透过率.通过使用将ITO材料置于膜系的内层和最外层两类不同的设计思想,可以使ITO透明导电膜达到相当优良的应用效果.使用低压反应离子镀方法制备了设计的两类减反射膜系,实验证明,膜层在可见光部分的透过率显著提高,剩余反射率明显下降,并得到了平均透过率为95.83%,最高透过率达到97.26%,方块电阻为13.2～24.6Ω/□的试验结果.