Energy Transfer Induced by TADF Polymer Enables the Recycling of Excitons in Perovskite Solar Cells

Formamidinium lead triiodide (FAPbI₃) has been demonstrated as the most efficient perovskite system to date, due to its excellent thermal stability and an ideal bandgap approaching the Shockley-Queisser limit. Whereas, there are intrinsic quantum confinement effects in FAPbI₃, which lead to unwanted non-radiative recombination. Additionally, the black α-phase of FAPbI₃ is unstable under room temperature due to the significant residual tensile stress in the film. To simultaneously address the above issues, a thermally-activated delayed fluorescence polymer P1 is designed in the study to modify the FAPbI₃ film. Owing to the spectral overlap between the photoluminescence of P1 and absorption of the above-bandgap quantum wells of FAPbI₃, the Förster energy transfer occurs at the P1/FAPbI₃ interface, which further triggers the Dexter energy transfer within FAPbI₃. The exciton “recycling” can thus be realized, which reduces the non-radiative recombination losses in perovskite solar cells (PSCs). Moreover, P1 is found to introduce compressive stress into FAPbI₃, which relieves the tensile stress in perovskite. Consequently, the PSCs with P1 treatment achieve an outstanding power conversion efficiency (PCE) of 23.51%. Moreover, with the alleviation of stress in the perovskite film, flexible PSCs (f-PSCs) also deliver a high PCE of 21.40%.     

一种宽带注入锁定三倍频器

文章提出了一种宽带注入锁定三倍频器。在传统注入方式基础上,倍频器采用了推-推差分对输入信号进行二倍频,并将产生的二次谐波通过变压器耦合至注入管的源极共模点,增强了注入管源极共模点二次谐波。由于注入电流是由注入信号与源极共模点二次谐波进行混频而产生,因此注入电流也被增强,从而增大了锁定范围。除此之外,三倍频采用了四阶谐振器,谐振阻抗的相位在过零点被平坦化,锁定范围进一步被增大。采用标准CMOS 65 nm工艺设计三倍频,芯片面积为720×670 μm²,1.2-V供电时的功耗为15.2 mW。0 dBm注入功率下三倍频的锁定范围为19.2~27.6 GHz,对应的基波抑制比大于25 dB,二次谐波抑制大于35 dB。注入锁定三倍频器可满足5G收发机中本振源的要求。     

Base on the Public Scientific Quality Improvement Research on Risk Early Warning of Online Shopping

LTE-A network offers data rates up to 1 Gbps which is 10?×?faster than LTE catering to growing demand of users. LTE improves user experience by reducing latency and increasing bandwidth efficiency. The emerging services and key enhancements such as Further Enhancement of Downlink Multiple-Input Multiple-Output (MIMO), Heterogeneous Networks, and Carrier Aggregation (CA) in LTE-A has improved performance of LTE-A networks. Scheduling optimization still remains one of the biggest challenges in high speed data transmission network. Scheduling in LTE-A networks are performed at various levels; User Equipment (UE), Serving Gateway (SGW), Air Interface and eNodeB. Remote Radio Head (RRH) is an extremely specialized device installed at antenna of eNodeB for optical to electrical signal conversion, amplification of signals and Uplink and Downlink Scheduling. Resource scheduling at Antenna of eNodeB module is constituted as a significant research optimization area. This paper proposes a soft computing based scheduler for RRH. Results of proposed technique are evaluated on Fairness Index, Throughput, Spectral Efficiency and Rank Indicator Distribution. The proposed algorithm aims to improve performance of scheduling. From experimental results, it is observed that proposed model succeeds to achieve significantly better performance as compared to state-of-art algorithms.

     

采用自适应模糊优化的目标跟踪加速方案

目标跟踪作为计算机视觉的重要方向之一,在自动驾驶、安防监控等方面有着广泛的应用,但是目标跟踪算法还无法有效地运行在嵌入式设备上。针对目标跟踪算法计算量大、复杂度高,难以部署在资源受限的嵌入式设备的问题,提出了一种基于相关滤波目标跟踪的加速方案。首先采用自适应模糊算法优化了跟踪算法整体运算量,它可以根据目标跟踪框的尺寸判定是否降低图像质量。其次采用了跟踪响应结果的峰值旁瓣比与平均相关能量比判据来评估跟踪结果的可信度,从而实现跟踪模型的自适应更新以及目标位置的重搜索。最后基于FPGA并行实现相关运算和跟踪检测器训练阶段的矩阵相乘运算,以提升算法实时能效性。所提出的加速算法基于PYNQ-Z2进行硬件测试,并在OTB-2015跟踪数据集上进行验证,该算法的跟踪精度与跟踪实时性分别为65.8%,17.28 frame/s,相比于原始算法,跟踪精度、跟踪实时分别提高了9.12%、703.7%。     

(CoFe)Se2@NC超级电容器电极材料的制备及其电化学性能

金属-有机框架(MOF)衍生的过渡金属硒化物和多孔碳纳米复合材料具有巨大的储能优势,是应用于电化学储能的优良电极材料。采用共沉淀法制备CoFe类普鲁士蓝(CoFe-PBA)纳米立方,并通过静电组装在CoFe-PBA上包覆聚吡咯(PPy)得到CoFe-PBA@PPy;通过在400℃氮气中退火并硒化成功制备了氮掺杂的碳(NC)包覆(CoFe)Se₂的(CoFe)Se₂@NC纳米复合材料,并对其结构和形貌进行了表征。以(CoFe)Se₂@NC为电极制备了超级电容器,测试了其电化学性能,结果表明,在电流密度1 A/g时超级电容器的比电容达到1047.9 F/g,在电流密度5 A/g下1000次循环后具有良好的循环稳定性和96.55%的比电容保持率。由于其性能优越、无毒、成本低和易于制备,未来(CoFe)Se₂@NC纳米复合材料在超级电容器中具有非常大的应用潜力。