Experimental study of the inclusiveη-spectrum fromp \bar p annihilations at rest in liquid hydrogen

The inclusive η-momentum spectrum from \(\bar p\) annihilations at rest in liquid hydrogen was measured at LEAR. Branching ratios were obtained for $$\begin{gathered} p\bar p \to \eta \omega \left( {1.04_{ - 0.10}^{ + 0.09} } \right)\% ,\eta \rho ^0 \left( {0.53_{ - 0.08}^{ + 0.20} } \right)\% , \hfill \\ \pi a_2 \left( {8.49_{ - 1.10}^{ + 1.05} } \right)\% ,\eta \pi ^0 \left( {1.33 \pm 0.27} \right) \times 10^{ - 4} , \hfill \\ \end{gathered} $$ , and ηη(8.1±3.1)×10^?5. An upper limit for \(p\bar p \to \eta \eta '\) of 1.8×10^?4 at 95% CL was found. The ratio of the branching ratios is BR(η?)/BR(ηω)=0.51 _?0.06 ^+0.20 . For the ratio of branching ratios into two pseudoscalar mesons, we have BR(ηπ⁰)/BR(π⁰π⁰)=0.65±0.14, BR(ηη)/BR(π⁰π⁰), BR(η η ^′ )/BR(π⁰π⁰) at 95% CL, and BR(ηη)/BR(ηπ⁰).     

Analysis of citrates and benzoates used in poly(vinyl chloride) by supercritical fluid extraction and gas chromatography

Supercritical fluid extraction (SFE) has been demonstrated to be a useful tool in the determination of additives in polymeric materials. This paper describes the determination of some citrates and benzoates in poly(vinyl chloride) blended with 33–34% of plasticizer using off-line SFE followed by gas chromatography. Experimental factors affecting SFE have been studied by gravimetric analysis, followed by analysis of the extracts using a gas chromatograph equipped with a flame ionization detector. The extraction process is governed by the solubility of the plasticizers in the supercritical fluid or by their diffusion through the polymer matrix, which depend on the pressure and temperature used. Maximum extraction (>99%) is obtained at pressures and temperatures higher than 40 MPa and 80 °C, respectively. Due to purge losses, the collection efficiency of plasticizers into a liquid solvent ranges from 85 to 90%. The applicability of the SFE method is demonstrated using real samples and comparing the results with those obtained by conventional Soxhlet extraction.     

The Effect of Preparation Method and Calcination Temperature on the Crystallite Size and Surface Area of Perovskite-Type SrFeO x

We have investigated the synthesis of perovskite-type SrFeO_x (2.5 x 3.0) using three preparative methods: sol-gel, mechanochemical processing and solid state reactions at high temperature of the corresponding oxides. The sample obtained after calcination of the gel from sol-gel method, contained the least amount of strontium carbonate impurity. The amount of strontium carbonate impurity decreased with the increase in calcination temperature. Perovskites obtained have been characterized by X-ray diffraction (XRD) and nitrogen adsorption isotherms. Samples obtained from three methods have been compared with respect to calcination temperature, crystallite size and specific surface area.Issued as NRCC No. 46479.     

Characterization and complementation of a Pichia stipitis mutant unable to grow on d-xylose or l-arabinose

Pichia stipitis CBS 6054 will grow on d-xylose, d-arabinose, and l-arabinose. d-Xylose and l-arabinose are abundant in seed hulls of maize, and their utilization is important in processing grain residues. To elucidate the degradation pathway for l-arabinose, we obtained a mutant, FPL-MY30, that was unable to grow on d-xylose and l-arabinose but that could grow on d-arabinitol. Activity assays of oxidoreductase and pentulokinase enzymes involved in d-xylose, d-arabinose, and l-arabinose pathways indicated that FPL-MY30 is deficient in d-xylitol dehydrogenase (D-XDH), d- and l-arabinitol dehydrogenases, and d-ribitol dehydrogenase. Transforming FPL-MY30 with a gene for xylitol dehydrogenase (PsXYL2), which was cloned from CBS 6054 (Gen Bank AF127801), restored the D-XDH activity and the capacity for FPL-MY30 to grow on l-arabinose. This suggested that FPL-MY30 is critically deficient in XYL2 and that the d-xylose and l-arabinose metabolic pathways have xylitolas a common intermediate. The capacity for FPL-MY30 to grow on d-arabinitol could proceed through d-ribulose.