全文获取类型
收费全文 | 521篇 |
免费 | 28篇 |
国内免费 | 127篇 |
专业分类
化学 | 338篇 |
晶体学 | 9篇 |
力学 | 39篇 |
综合类 | 2篇 |
数学 | 32篇 |
物理学 | 105篇 |
无线电 | 151篇 |
出版年
2023年 | 4篇 |
2022年 | 8篇 |
2021年 | 7篇 |
2020年 | 13篇 |
2019年 | 6篇 |
2018年 | 7篇 |
2017年 | 6篇 |
2016年 | 5篇 |
2015年 | 10篇 |
2014年 | 13篇 |
2013年 | 15篇 |
2012年 | 19篇 |
2011年 | 110篇 |
2010年 | 15篇 |
2009年 | 58篇 |
2008年 | 26篇 |
2007年 | 18篇 |
2006年 | 13篇 |
2005年 | 23篇 |
2004年 | 74篇 |
2003年 | 29篇 |
2002年 | 24篇 |
2001年 | 10篇 |
2000年 | 9篇 |
1999年 | 14篇 |
1998年 | 10篇 |
1997年 | 15篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 10篇 |
1993年 | 13篇 |
1992年 | 21篇 |
1991年 | 15篇 |
1990年 | 16篇 |
1989年 | 12篇 |
1988年 | 3篇 |
1986年 | 3篇 |
1983年 | 2篇 |
排序方式: 共有676条查询结果,搜索用时 15 毫秒
41.
42.
掺铕稀土配合物的光学树脂荧光光谱研究 总被引:2,自引:0,他引:2
报道了将多种稀土铕配合物复合于苯乙烯(ST)/甲基丙烯酸(HMA)的共聚体系,研究了含稀土配合物透明光学树脂的光学性能。发现其具有发光效率高,光谱呈现尖锐的线状谱带及相对于纯稀土配合物粉末来说掺有稀土配合物的光学树脂的发射产生光谱红移等特点。特别是用电子云重排效应(当中心稀土离子与不同配体结合时,其相同的J能级间的跃迁谱带位置略有移动的现象)解释了掺有稀土配合物的光学树脂发射光谱红移现象。并推断出在含稀土配合物复合于光学树脂后。稀土中心离子和配位原子间距离有所减小。 相似文献
43.
WANG Chun-yan ZHANG Yu-jing College of Animal Science Veterinary Medicine Jilin University Changchun P. R. China 《高等学校化学研究》2011,(2)
The lack of efficient and non-toxic gene delivery, preferably with non-viral DNA vectors, is generally regarded as a major limitation for gene therapy. In this study, a wheat histone H4 gene was cloned from Triticum aestivum, sequenced, modified and expressed in E. coli. The wheat histone H4 gene and reconstructed H4TL gene encoded wheat histone H4 and a recombinant protein of 141 amino acids with an approximate molecular weight of 15500. Gel electrophoresis mobility shift assays demonstrated that the purif... 相似文献
44.
To explain the long-term existence of Uranian narrow rings, we study the dynamical evolution of Uranian epsilon ring under
the influence of its two shepherding satellites: Cordelia and Ophelia. The model of planar-elliptic restricted three-body
problem is employed, in which the three bodies are Uranus, a satellite and a test particle. Dissipations due to interparticle
collisions are also taken into consideration. A mapping system has been obtained based on the differential equation system.
Numerical results show that only those particles originally lying in the libration region of the resonance can be shepherded.
The size of the libration region depends mainly on the orbital eccentricity and mass of the shepherd satellite. For the outer
shepherd Ophelia with larger orbital eccentricity, if its mass is a third of the nominal mass 2.5 × 1019 g, most of the orbits are regular and the outer edge of the ring can be shepherded, but more fuzzy than the inner edge. Thus
we infer that Ophelia has a smaller mass. 相似文献
45.
LI Jing SHANG Yan-mei XIAO Chuan SONG Zhi-guang LI Ye-zhi HUANG Hua-min .College of Chemistry Jilin University .School of Public Health Changchun P.R.China .Key Laboratory for Supramolecular Structure Materials of Ministry of Education Changchun 《高等学校化学研究》2009,25(1)
(R)-4-Hydroxymethyl-2-thioxo thiazolidine as a new chiral catalyst in the asymmetric addition of diethyl-zinc to benzaldehyde was synthesized from (R)-4-hydroxymethyl-2-thioxo thiazolidine carboxylic acid and its crystal structure was determined by X-ray diffraction method. The compound was crystallized in the orthorhombic system, space group P212121 with unit cell dimensions a=0.67253(12) nm; b=0.89164(17) rim; c=1.06146(19) nm, volume 0.6365(2) nm3; Z=4, calculated denisity 1.557 Mg/m3; absorption coefficient 0.733 mm-1; F(000)=312. The X-ray crystal structure analysis reveals that the compound has a thione group. 相似文献
46.
47.
Single‐layer graphene has received much attention because of its unique two‐dimensional crystal structure and properties. In this review, we focus on the graphene devices in solution, and their properties that are relevant to chemical and biological applications. We will discuss their charge transport, controlled by electrochemical gates, interfacial and quantum capacitance, charged impurities, and surface potential distribution. The sensitive dependence of graphene charge transport on the surrounding environment points to their potential applications as ultrasensitive chemical sensors and biosensors. The interfacial and quantum capacitance studies are directly relevant to the on‐going effort of creating graphene‐based ultracapacitors for energy storage. 相似文献
48.
CHEN ShengBo & SONG JinHong College of Geoexploration Science Technology Jilin University Changchun China College of Resources Environment Jilin Agricultural University Changchun 《中国科学:物理学 力学 天文学(英文版)》2011,(8)
Atmospheric temperature-humidity profiles and land or sea surface temperature are coupled actions in the earth system process. Based on the numerical perturbation form of the atmospheric radiative transfer equation, a physics-based algorithm is pre- sented to integrate four pairs of MODIS measurements from the Terra and Aqua satellites to retrieve simultaneously atmospheric temperature-humidity profile, land-surface temperature and emissivity. Three pairs of MODIS data at two field sites in China, Luancheng... 相似文献
49.
Xiaomiao HouXiaoling Zhang Shutang ChenYan Fang Jilin YanNa Li Pengxu Qi 《Applied Surface Science》2011,257(11):4935-4940
A facile and novel way was reported here for the synthesis of hydrophobic Ag nanoparticles (NPs), using AgNO3, tri-n-octylphosphine (TOP) and sulfur (S) powder in process. TOP was used as solvent, reducing agent and stabilizer. S could chelate with excessive TOP to form trioctylphosphine sulfide (TOPS), which served as second capping agent. The hydrophobic Ag NPs could be transformed into hydrophilic state through ligand exchange. Furthermore, surface-enhanced Raman scattering (SERS) spectra of 4-aminothiophenol (4-ATP) were obtained on the hydrophobic and hydrophilic Ag NPs modified substrates, indicating that the as-synthesized Ag NPs had great potential for high sensitive optical detection applications. 相似文献
50.
C. W. Lim 《Acta Mechanica Solida Sinica》2011,24(6):484-494
The torsional static and dynamic behaviors of circular nanosolids such as nanoshafts, nanorods and nanotubes are established based on a new nonlocal elastic stress field theory. Based on a new expression for strain energy with a nonlocal nanoscale parameter, new higher-order governing equations and the corresponding boundary conditions are first derived here via the variational principle because the classical equilibrium conditions and/or equations of motion can- not be directly applied to nonlocal nanostructures even if the stress and moment quantities are replaced by the corresponding nonlocal quantities. The static twist and torsional vibration of circular, nonlocal nanosolids are solved and discussed in detail. A comparison of the conventional and new nonlocal models is also presented for a fully fixed nanosolid, where a lower-order governing equation and reduced stiffness are found in the conventional model while the new model reports opposite solutions. Analytical solutions and numerical examples based on the new nonlocal stress theory demonstrate that nonlocal stress enhances stiffness of nanosolids, i.e. the angular displacement decreases with the increasing nonlocal nanoscale while the natural frequency increases with the increasing nonlocal nanoscale. 相似文献