Unsupervised model-driven neural network based image denoising for transmission line monitoring

With the expansion of smart grid and Internet of things (IoT) technology, edge computing has a wide variety of applications in these domains. The criteria for real-time monitoring and accuracy are particularly high in the field of online real-time monitoring of electricity lines. Based on edge technology, high-quality real-time monitoring can be performed for transmission lines using image processing techniques. Therefore, we propose an image denoising method, which can learn clean images using a stream-based generative model. The stream model uses a two-stage approach in the network to handle the different training periods of denoising separately. Experimental results show that the proposed method has good denoising performance.     

High-Efficiency Organic Solar Cells Enabled by Chalcogen Containing Branched Chain Engineering: Balancing Short-Circuit Current and Open-Circuit Voltage,Enhancing Fill Factor

The elaborate balance between the open-circuit voltage (V_OC) and the short-circuit current density (J_SC) is critical to ensure efficient organic solar cells (OSCs). Herein, the chalcogen containing branched chain engineering is employed to address this dilemma. Three novel nonfullerene acceptors (NFAs), named BTP-2O , BTP-O-S , and BTP-2S , featuring different peripheral chalcogen containing branched chains are synthesized. Compared with symmetric BTP-2O and BTP-2S grafting two alkoxy or alkylthio branched chains, the asymmetric BTP-O-S grafting one alkoxy and one alkylthio branched chains shows mediate absorption range, applicable miscibility, and favorable crystallinity. Benefiting from the enhanced π–π stacking and charge transport, an optimal power conversion efficiency (PCE) of 17.3% is obtained for the PM6: BTP-O-S -based devices, with a good balance between V_OC (0.912 V) and J_SC (24.5 mA cm⁻²), and a high fill factor (FF) of 0.775, which is much higher than those of BTP-2O (16.1%) and BTP-2S -based (16.4%) devices. Such a result represents one of the highest efficiencies among the binary OSCs with V_OC surpassing 0.9 V. Moreover, the BTP-O-S -based devices fabricated by using green solvent yield a satisfactory PCE of 17.1%. This work highlights the synergistic effect of alkoxy and alkylthio branched chains for high-performance OSCs by alleviating voltage loss and enhancing FF.     

Metal Single-Site Molecular Complex–MXene Heteroelectrocatalysts Interspersed Graphene Nanonetwork for Efficient Dual-Task of Water Splitting and Metal–Air Batteries

Development of multifunctional electrocatalysts with high efficiency and stability is of great interest in recent energy conversion technologies. Herein, a novel heteroelectrocatalyst of molecular iron complex (Fe_MC)-carbide MXene (Mo₂TiC₂T_x) uniformly embedded in a 3D graphene-based hierarchical network (GrH) is rationally designed. The coexistence of Fe_MC and MXene with their unique interactions triggers optimum electronic properties, rich multiple active sites, and favorite free adsorption energy for excellent trifunctional catalytic activities. Meanwhile, the highly porous GrH effectively promotes a multichannel architecture for charge transfer and gas/ion diffusion to improve stability. Therefore, the Fe_MC–MXene/GrH results in superb performances towards oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) in alkaline medium. The practical tests indicate that Zn/Al–air batteries derived from Fe_MC–MXene/GrH cathodic electrodes produce high power densities of 165.6 and 172.7 mW cm⁻², respectively. Impressively, the liquid-state Zn–air battery delivers excellent cycling stability of over 1100 h. In addition, the alkaline water electrolyzer induces a low cell voltage of 1.55 V at 10 mA cm⁻² and 1.86 V at 0.4 A cm⁻² in 30 wt.% KOH at 80 °C, surpassing recent reports. The achievements suggest an exciting multifunctional electrocatalyst for electrochemical energy applications.     

基于自然梯度Actor-Critic强化学习的卫星边缘网络服务功能链部署方法

鉴于低轨卫星网络的高动态性和空间环境的复杂性,如何提供在线的快速服务功能链(SFC)部署方法,成为低轨卫星边缘网络中亟待解决的问题。综合考虑节点和链路容量等约束以及服务迁移等切换代价,针对部署多接入边缘计算(MEC)服务器的低轨卫星网络,该文提出一种基于自然梯度参与者-评价者(Actor-Critic)强化学习架构的SFC在线部署方法。首先,针对低轨卫星网络的环境高动态性,对实时容量约束和迁移代价进行建模;其次,引入马尔可夫决策过程(MDP),综合考虑服务迁移和卫星坐标等因素,描述低轨卫星网络的状态转移过程;最后,提出一种基于自然梯度的在线SFC部署强化学习方法,不同于标准梯度,自然梯度法进行模型层面的更新,以避免神经网络的训练陷入局部最优解。仿真结果表明,该文方法可逼近全局最优解,并在端到端时延性能上优于基于标准梯度的强化学习部署方法。     

基于EMD方法的X波段双偏振雷达衰减订正

针对X波段双偏振雷达信号在降雨路径中的衰减现象,本文提出经验模式分解（Empirical Mode Decomposition,EMD）方法进行X波段双偏振雷达衰减订正,首先对总差分传播相移进行EMD分解得到有限个基本模式分量（Intrinsic Mode Function,IMF）,并基于皮尔逊相关系数准则将IMF分为噪声IMF和信号IMF两类,然后对信号IMF进行有效重构得到差分传播相移,再将差分传播相移通过最小二乘法拟合得到差分传播相移率,最后对求得的差分传播相移与差分传播相移率采用自适应约束方法进行反射率衰减订正。利用EMD方法和其他方法进行对比分析,其结果表明,EMD方法能够有效地消除X波段双偏振雷达回波数据中后向散射的影响,在保留真实的气象信息的同时,有效地抑制差分传播相移的显著波动,进而衰减订正效果更好。     

回波功率筛选与数字地表分类数据辅助的低空风切变风速估计方法

针对非均匀杂波环境下,低空风切变风速估计不准的问题,该文提出一种回波功率筛选与数字地表分类数据(DLCD)辅助的低空风切变风速估计方法.该方法首先利用样本回波功率对训练样本进行初选,然后利用DLCD计算各样本间的相似度,并从功率较大的训练样本中选取样本相似度较高的训练样本估计待测距离单元的杂波协方差矩阵,最后利用广义相邻多波束(GMB)-局域联合处理(JDL)的方法实现低空风切变风速的有效估计.     

Existence results for superlinear semipositone 's

We consider the existence of positive solutions to the BVP

where . Our results extend some of the existing literature on superlinear semipositone problems and singular BVPs. Our proofs are quite simple and are based on fixed point theorems in a cone.

     

在"高聚物的结构与性能"课程中应该引入的几个新概念

在“高聚物的结构与性能”课程教学中，很有必要向学生介绍高分子科学近十几年来的发展，尤其是在高分子凝聚态基本物理问题上的研究成果以及相关的新概念、新知识，特别是我国学者的贡献。本文较为详细地讨论了近年来作者在教学中介绍的几个新概念，如：动态接触浓度、单链凝聚态、凝聚缠结等。