Interface characteristics in diffusion bonding of Fe3Al with Cr18-Ni8 stainless steel

Fe3Al and Cr18-Ni8 stainless steel were diffusion-bonded in vacuum and a Fe3Al/Cr18-Ni8 interface with reaction layer was formed. Microstructure in the reaction layer at Fe3Al/Cr18-Ni8 interface was analyzed by means of scanning electron microscope (SEM) and electron probe micro-analyzer (EPMA). The growth of reaction layer with heating temperature (T) and holding time (t) was researched. The results indicate that FeAl, Fe3Al, Ni3Al, and alpha-Fe (Al) solid solution are formed in the reaction layer. These phases are favorable to promote the element diffusion and to accelerate the formation of the reaction layer at Fe3Al/Cr18-Ni8 interface. The growth of reaction layer obeys the parabolic law and its thickness (X) is expressed by X2 = 7.5 x 10(-4)exp(-83.59/RT)(t - t0).     

N-（4＇-取代嘧啶-2＇-基）-取代苯氧基磺酰脲的合成及除草活性

光谱;N-（4＇-取代嘧啶-2＇-基）-取代苯氧基磺酰脲的合成及除草活性     

溶剂浓度对PVDF相转换膜大孔结构的影响

提出决定大孔能否发展的初始分相点处溶剂浓度临界点的概念 ,认为初始分相点处较高的溶剂浓度有利于大孔的发展 ,溶剂浓度低于一定的界限后 ,大孔停止发展 ,转为海绵状结构 .实验考察了不同凝胶液组成下制得的PVDF中空膜的结构 ,建立了相应的传质模型 ,模拟不同制膜条件下初生态膜内的组成分布情况 ,根据初始分相点处溶剂浓度临界点的概念 ,预测膜的形态结构 .模拟结果与相应制膜条件下的电镜照片有很好的对应关系 ,证明了上述大孔形成机理的正确性 .     

Use of on-line mass spectrometric detection in capillary electrochromatography

Capillary electrochromatography (CEC) is a liquid phase analytical separation technique that is generally carried out with packed capillary columns by electroosmotically driven mobile phase at high electric field strength. The analytes are separated by virtue of the differences in their distribution between the mobile and stationary phases and, if charged in their electrophoretic mobilities as well. It is thus considered a hybrid of liquid chromatography and capillary electrophoresis and is expected to combine the high peak efficiency of capillary zone electrophoresis (CZE) with the versatility and loading capacity of HPLC. This review explores the potential use of on-line mass spectrometric detection for CEC. It discusses key design issues that focus on the physical and electrical arrangement of the CEC column with respect to the electrospray orifice inlet. The salient features of the sheathless, sheath flow and liquid junction interfaces that are frequently employed while coupling a CEC column to an electrospray ionization mass spectrometry system are also highlighted. Possible configurations of the CEC column outlet that would obviate the need for pressurizing the capillary column are also presented. While coupling CEC with MS both the nature of the interface and the configuration of the column outlet will determine the optimal arrangement. The review also discusses bandspreading that occurs when a connecting tube is employed to transfer mobile phase from the column outlet to the atmospheric region of the electrospray source with a concomitant loss in sensitivity. Selected examples that highlight the potential of this technique for a wide range of applications are also presented.     

NMR频率综合器的微机控制

为实现ＰＴＳ系列频率综合器的微机控制，设计了一种简单的控制电路。在微机的控制下，通过该电路与微机的并行通讯口，用Ｃ语言编写的控制程序可以很方便的控制频率综合器的输出频率。控制程序采用菜单操作，电路所需的＋５Ｖ电源由微机提供，整个控制系统简单实用，值得推广。     

丙烯环氧化反应的高活性钼催化剂

在钼(Ⅵ),钒(Ⅴ)和钛(Ⅳ)等化合物存在下,丙烯与烷基过氧化氢的环氧化反应比传统的氯醇法有很多优点,其中以钼催化剂的性能最优,但目前报道的催化剂在反应过程中因易分解而降低了活性,并且丙烯与烷基过氧化氢的投料比过大(>3:1),丙烯循环次数过多。前文报道了钼烷基醇胺化合物对环已烯的环氧化反应,本文考察了钼烷基醇胺化合物对丙烯与叔丁基过氧化氢环氧化反应的催化性能。     

Preparation and characterization of polyvinyl alcohol-capped CdSe nanoparticles at room temperature

Polyvinyl alcohol (PVA)-capped CdSe nanoparticles were successfully prepared by a one-step solution growth technique at room temperature and ambient pressure. X-ray diffraction, transmission electron microscopy, infrared spectra, and X-ray photoelectron spectra were used to characterize the final product. The as-prepared CdSe nanocrystals were well dispersed and uniform in shape and the diameter of the particles was confined within 8 nm. Ultraviolet-visible absorption spectra were used to study the confined growth process of PVA-capped CdSe nanoparticles. Photoluminescence measurement showed the near band-edge luminescence of the final product.     

5′-Noraristeromycin derivatives isomeric to aristeromycin and 2′-deoxyaristeromycin

A straightforward synthesis of (1S,2R,3R,4R)-4-(6-aminopurin-9-yl)-2-hydroxymethylcyclopentane-1,3-diol (2), an isomer of aristeromycin, and its 2′-deoxy derivative 3 from readily available disubstituted cyclopentenes is presented. An antiviral analysis of 2 showed it to have significant activity versus Epstein-Barr virus (IC₅₀ 0.62 μg/mL in the Elisa assay) and to be free of cytotoxicity effects against the host cells. In a much less comprehensive antiviral analysis, 3 also was active towards Epstein-Barr (IC₅₀ 7.58 μg/mL in the Elisa assay) but this was accompanied by cellular toxicity.     

A mesoporous Pt/TiO2 nanoarchitecture with catalytic and photocatalytic functions

A novel metal/semiconductor nanocomposite with catalytic and photocatalytic functions has been prepared. The new material consists of highly dispersed platinum (Pt) nanoparticles embedded in a cubic mesoporous nanocrystalline anatase (meso-nc-TiO2) thin film. The porous thin film possesses a narrow pore-size distribution and a large surface area. The diameter of the Pt cluster can be controlled to below 5 nm, and the high dispersion of these clusters gives rise to catalytic activity for the oxidation of carbon monoxide, an important reaction for automobile exhaust treatment. This novel ordered mesoporous Pt/TiO2 nanoarchitecture is also a promising photochemical material, as demonstrated by the photo-driven killing of Micrococcus lylae cells on the film.     

Preparation of 103Pd seeds Part II. “Molecular Plating” of 103Pd onto copper rod

A method for ¹⁰³Pd molecular plating onto the surface of the copper rod is reported. The optimal composition of the plating bath was: palladium chloride 2 g/l, ammonium hydroxide (28%) 150 ml/l, sodium hypophosphite 12 g/l, and ammonium chloride 37 g/l. The whole procedure of ¹⁰³Pd molecular plating will last 50 minutes at 40 °C. This article provides valuable experience for the preparation of ¹⁰³Pd seeds.