几种N-取代马来酰胺酸辅酶模型的核磁共振研究

我们对8种N-取代马来酰胺酸辅酶模型与不同类型的亲核试剂反应后生成的产物进行了¹H、¹³C NMR的研究, 测得¹H、¹³C谱化学位移,研 究探讨其规律性, 并测试了IR谱和元素分析.     

Influence of lattice self-heating and hot-carrier transport ondevice performance

As device technologies improve, the traditional drift-diffusion transport model becomes inadequate to predict the performance of state-of-the-art semiconductor devices. The reasons are believed to be the larger field and field gradient inside advanced devices which cause lattice heating and hot carrier nonlocal transport phenomena. For more accurate prediction on device performance, a new device simulator capable of full thermodynamic simulation was developed. The carrier and carrier energy transport equations are directly derived from the Boltzmann transport equation, and the energy transfer among electrons, holes and crystal lattice takes into account most of the possible mechanisms. This simulator was used to simulate the DC behavior of a BJT and a half-micron NMOS. The simulation results show that for advanced devices, not only the drift-diffusion model becomes inadequate, but including only one of the two thermal effects results in error in simulated device characteristics     

数字混沌扩频序列的盲估计

混沌序列具有非线性、宽带类噪声、大的码族、任意长的周期且容易产生的特性,因此在扩频通信系统中很有实用价值。本文将文献[1]中对伪随机扩频序列盲估计的方法推广应用到混沌扩频通信中,并对其不足提出了改进方法。在只知道扩频码周期而无其它任何先验知识的条件下,利用特征值分析的方法可以对数字混沌直扩序列进行盲估计,仿真实验证明了该方法的有效性。     

动态分组传输技术(DPT)性能分析

简要介绍动态IP光纤技术DPT的传输机制及相关的空间复用协议内容,同时分析DPT的主要特点,并与其他技术如ATM,POS等进行对比,说明DPT在大型IP网络应用中的优势.     

Synthesis of Nearly Monodisperse Iron Oxide and Oxyhydroxide Nanocrystals

Uniform magnetite, hematite, and goethite nanocrystals were prepared through an attractive method based on an oleic acid/alcohol/water system. By adjusting the synthetic parameters (base concentration, alcohol content, categories of alcohols, etc.), the controlled synthesis of uniform magnetite, hematite, and goethite nanocrystals can be easily achieved. Detailed investigations on the effect of the experimental parameters on the morphology of the final products and the phase transitions among the magnetite, hematite, and goethite phases were carried out. Finally, a method of doping other metal ions into magnetite was developed and the magnetic properties of magnetite doped with different metal elements were studied.     

原伊鲁烷型倍半萜醇芳香酸酯的碳谱研究

作者自人工发酵得到的蜜环菌Armillaria mellea (Vahl.ex Fr.) Quel.菌丝体中分离出十七个原伊鲁烷型倍半萜醇芳香酸翻,在研究这些化合物的化学结构中,对其全去偶碳谱,偏共振谱或INEPT谱,C-H COSY谱和远程C-H COSY谱进行比较仔细地分析,指定了每个化合物各碳的归属,讨论了其碳谱的特征,并指出¹³C NMR谱是对新的该类型化合物结构测定的有效方法.     

Electromagnetics of superconductors

It is shown that a superconductor cannot be simply treated as a low-loss conductor; rather, it should be treated as a negative dielectric material (with a negative dielectric constant). This approach is good only for vanishingly small field application with frequency significantly smaller than gap frequency and temperature not too close to the critical temperature of the superconductor. The electromagnetics of negative dielectric materials are discussed in terms of causality, perturbation technique, surface impedance, time-domain interpretation of current components, and computational electrodynamics     

Radiation of millimeter waves from NRD leaky wave antennas withtapered transition and tuning aperture

The radiation of millimeter waves from the nonradiative dielectric (NRD) leaky wave antennas with the tapered transition and the tuning aperture is investigated. An accurate theory for the leakage constant and the phase constant of the antennas is presented, which is based on the generalized scattering parameters considering the higher-order mode interactions at the discontinuities. The associated transverse equivalent network involves the characterization of the mode couplings at two air-to-dielectric interfaces, the coupled mode analysis of the tapered transition, and the calculation of the radiation fields at the tuning aperture via the extended spectral domain approach. The interesting behavior of the present modified configuration of NRD leaky wave antennas is illustrated by typical examples. The validity of the theory is confirmed by the comparison of the theoretical results with experimental data for the limiting cases     

Effects of Background Plasma on Free Electron Laser with Planar Wiggler

Dispersion equation of planar-wiggler free-electron laser with background plasma is derived using linear fluid theory. The characteristic of this plasma FEL is analyzed in detail. It is shown that reasonable background plasma density tends to improve FEL growth rate. We also find there exits a critical plasma density for FEL operating. When the background plasma density is higher than critical density, the FEL can no longer be excited.     

One convenient synthesis route to boron nitride nanotube

We describe one convenient synthesis route to boron nitride (BN) nanotube by the reaction of boron powder, iron oxide, and ammonium chloride at 600 °C for 12 h. Characterized by XRD, FTIR, XPS, TEM and SAED, the composition and morphology of the products are confirmed. The possible reaction mechanism is also discussed.