Modified particle swarm optimization algorithm with simulated annealing behavior and its numerical verification

The hybrid algorithm that combined particle swarm optimization with simulated annealing behavior (SA-PSO) is proposed in this paper. The SA-PSO algorithm takes both of the advantages of good solution quality in simulated annealing and fast searching ability in particle swarm optimization. As stochastic optimization algorithms are sensitive to their parameters, proper procedure for parameters selection is introduced in this paper to improve solution quality. To verify the usability and effectiveness of the proposed algorithm, simulations are performed using 20 different mathematical optimization functions with different dimensions. The comparative works have also been conducted among different algorithms under the criteria of quality of the solution, the efficiency of searching for the solution and the convergence characteristics. According to the results, the SA-PSO could have higher efficiency, better quality and faster convergence speed than compared algorithms.     

Stepwise construction of manganese-chromium carbonyl chalcogenide complexes: synthesis, electrochemical properties, and computational studies

When trigonal-bipyramidal clusters, [PPN][E(2)Mn(3)(CO)(9)] (E = S, Se), were treated with Cr(CO)(6) and PPNCl in a molar ratio of 1:1:2 or 1:2:2 in 4 M KOH/MeCN/MeOH solutions, mono-Cr(CO)(5)-incorporated HE(2)Mn(3)-complexes [PPN](2)[HE(2)Mn(3)Cr(CO)(14)] (E = S, [PPN](2)[1a]; Se, [PPN](2)[1b]), respectively, were formed. X-ray crystallographic analysis showed that 1a and 1b were isostructural and each displayed an E(2)Mn(3) square-pyramidal core with one of the two basal E atoms externally coordinated with one Cr(CO)(5) group and one Mn-Mn bond bridged by one hydrogen atom. However, when the TMBA(+) salts for [E(2)Mn(3)(CO)(9)](-) were mixed with Cr(CO)(6) in a molar ratio of 1:1 in 4 M KOH/MeOH solutions and refluxed at 60 °C, mono-Cr(CO)(3)-incorporated E(2)Mn(3)Cr octahedral clusters [TMBA](3)[E(2)Mn(3)Cr(CO)(12)] (E = S, [TMBA](3)[2a]; Se, [TMBA](3)[2b]), respectively, were obtained. Clusters 2a and 2b were isostructural, and each consisted of an octahedral E(2)Mn(3)Cr core, in which each Mn-Mn or Mn-Cr bond of the Mn(3)Cr plane was semibridged by one carbonyl ligand. Clusters 1a and 1b (with [TMBA] salts) underwent metal core closure to form octahedral clusters 2a and 2b upon treatment with KOH/MeOH at 60 °C. In addition, 1a and 1b were found to undergo cluster expansion to form di-Cr(CO)(5)-incorporated HE(2)Mn(3)-clusters [HE(2)Mn(3)Cr(2)(CO)(19)](2-) (E = S, 3a; Se, 3b), respectively, upon the addition of 1 or 2 equiv of Cr(CO)(6) heated in refluxing CH(2)Cl(2). Clusters 3a and 3b were structurally related to clusters 1a and 1b, but with the other bare E atom (E = S, 3a; Se, 3b) further externally coordinated with one Cr(CO)(5) group. The nature, cluster transformation, and electrochemical properties of the mixed manganese-chromium carbonyl sulfides and selenides were systematically discussed in terms of the chalcogen elements, the introduced chromium carbonyl group, and the metal skeleton with the aid of molecular calculations at the BP86 level of the density functional theory.     

分幅变像管动态空间分辨率的标定

为了提高激光惯性约束聚变实验二维成像诊断的精密化程度, 提出了分幅变像管动态空间分辨率的标定方法. 标定原理是以直边函数为物, 经光学系统成像后求解系统的调制传递函数, 从而获得系统的空间分辨率. 在神光Ⅱ装置上利用八路激光打靶产生1-3.5 keV能区的连续X 射线标定源, 照射高Z刀边材料, 并成像到分幅变像管阴极上, 分幅变像管采用脉冲选通工作模式获得动态像. 对分幅变像管采集的动态图像进行处理得到系统的调制传递函数. 根据调制传递函数为0.1时对应的空间截止频率, 得到系统的空间分辨率为20 lp/mm. 根据分幅变像管的动态空间分辨理论, 计算系统的极限空间分辨率为22.8 lp/mm. 标定结果略低于极限空间分辨率, 与理论基本吻合. 根据传统标定方法得到该分幅变像管的静态空间分辨率为22 lp/mm, 比动态空间分辨率略高. 在二维成像诊断时, 分幅变像管工作于动态选通模式, 故动态空间分辨率的标定结果更能真实地反映其成像诊断能力.     

偏高岭土水热合成NaY分子筛的机理研究

采用茂名高岭土水热合成NaY分子筛,用IR,XRD,NMR,SEM,HRTEM等分析了其晶化过程。结果表明：偏高岭土水热合成Y型分子筛是固相转变机理,晶化过程是一个扩散-成胶-原位重排的过程。     

Preparation of silver nanoparticles on zinc oxide nanowires by photocatalytic reduction for use in surface‐enhanced Raman scattering measurements

To increase the sensitivity in surface‐enhanced Raman scattering (SERS) measurements, the high surface area of zinc oxide nanowires (ZnO NWs) was used. ZnO NWs on silicon substrates were prepared and used as substrates for further growth of silver nanoparticles (AgNPs). Ultraviolet (UV) irradiation was used to reduce silver ions to AgNPs on the ZnO wires. With proper growth conditions for both ZnO NWs and AgNPs, the substrates exhibit SERS enhancement factors greater than 10⁶. To understand the influences of the morphologies of the ZnO NWs on the growth of AgNPs, the growing time and temperature were varied. The concentration of silver nitrate and irradiation time of UV radiation were also varied. The resulting AgNPs were probed with para‐nitrothiophenol to quantify the SERS enhancements obtained from the varying conditions. The results indicate that ZnO NWs could be grown at temperatures higher than 490 °C and higher growth temperatures result in smaller diameter of the formed ZnO NWs. Also, the morphologies of ZnO NWs did not significantly alter the SERS signals. The concentration of silver nitrate affects the SERS signals significantly and the optimal concentration was found to be in the range of 10–20 mM. With irradiation times longer than 90 s, the resulting AgNPs showed similar SERS intensities. With optimized conditions, the AgNPs/ZnO substrates are highly suitable for SERS measurements with a typical enhancement factor of higher than 10⁶. Copyright © 2010 John Wiley & Sons, Ltd.     

GBL-based electrolyte for Li-ion battery: thermal and electrochemical performance

Thermal stability, flammability, and electrochemical performances of the cyclic carbonate-based electrolytes [where γ-butyrolactone (GBL) is a main component (at least 50 vol.%) among of EC and PC with LiBF₄] have been examined in comparison with contemporary (EC/EMC, 1:3 vol.%, 1 M LiPF₆) electrolyte by DSC, accelerating rate calorimetry (ARC), AC impedance, and cyclic voltammetry (CV). This study shows that GBL-based electrolytes have perfect thermal stability and will improve Li-ion battery safety (including flammability) without performance trade-off with the accurate combination of active materials and separator. Several types of negative electrode materials (such as hard carbon, MCMB, and SWF) have been tested to evaluate GBL-based electrolyte influence on SEI formation and battery performance. Finally, GBL-based electrolytes show not only equal electrochemical performance in comparison to commonly used electrolytes (EC/EMC in this study) but it will notably improve battery safety.     

Temperature responsive carbon nanotubes/poly(N-isopropylacrylamide)-modified electrodes for electrochemical selective determination of dopamine, uric acid, and ascorbic acid

Poly(N-isopropylacrylamide)(PNIPAAm) with a lower critical solution temperature of about 32?°C was used as matrix to prepare temperature responsive carbon nanotubes (CNT) and functionalized CNT (fCNT) composites to modify glassy carbon electrode (GCE) as working electrode for electrochemical selective detection of dopamine, uric acid, and ascorbic acid. The GCE modification temperature (25 and 37?°C, denoted as 25f and 37f), working temperature (25 and 37?°C, denoted as 25aq and 37aq), and the type of CNT (CNT and fCNT) were found to significantly affect the electrocatalytic activity of the composites toward redox reactions of Fe(CN) ₆ ^3?/4? as a probe and the selective detection ability for the three analytes. The fCNT/PNIPAAm composite with the 25f–37aq temperature combination exhibited strong electrocatalytic activity and highly selective detection ability for the three analytes. In contrast, the same composite with the other three combinations (25f–25aq, 37f–25aq, and 37f–37aq) and the CNT/PNIPAAm composite with all four combinations exhibited insignificant electrocatalytic activity and no selective detection ability.     

Performance modeling of MPEG‐4 video streaming over IEEE 802.11 using distribution coordination function

Delivering video streaming over wireless Internet is becoming increasingly popular. However, most of the research studies focused on the modeling analysis of system performance such as saturation throughput and channel utilization. Perceived quality of video streaming cannot be assessed solely based on the results of analytical models. In this paper, we propose a model to assess the perceived quality of MPEG‐4 video streaming over IEEE 802.11 distribution coordination function (DCF)‐based wireless local area networks. The analysis of our proposed model considers not only effects of losses such as collision loss from channel access competition but also wireless loss caused by wireless interferences. Moreover, the impact of the loss of specific MPEG‐4 video frames is also taken into account in the performance analysis. The model was validated by comparing our performance results with results obtained from simulation and analytical models. The results show that our proposed model is able to predict the perceived quality of MPEG‐4 video streaming over DCF‐based WLAN more accurately than other models. Copyright © 2010 John Wiley & Sons, Ltd.     

Digital Controller Design for Analog Systems Represented by Multiple Input–Output Time-Delay Transfer Function Matrices with Long Time Delays

This paper presents a digital controller design methodology for multivariable analog systems represented by minimally realizable multiple input–output time-delay transfer function matrices with long time delays. First, the analog transfer function matrix with multiple input–output time delays is minimally realized and represented by a delay-free state-space model and a multiple output-delay function. For a specific multiple time-delay transfer function matrix with complex poles, a minimal realization scheme is newly proposed. Then the minimized delay-free state-space model is utilized for linear quadratic regulator (LQR) design. Furthermore, the designed analog LQR is digitally redesigned via a predictive state-matching method for finding a low-gain digital controller from the pre-designed high-gain analog controller. For implementation of the digitally redesigned controller, a digital observer is constructed for the multiple time-delay system with long time delays. An illustrative example is given to demonstrate the effectiveness of the proposed method.