全文获取类型
收费全文 | 5230篇 |
免费 | 521篇 |
国内免费 | 323篇 |
专业分类
化学 | 3010篇 |
晶体学 | 56篇 |
力学 | 167篇 |
综合类 | 15篇 |
数学 | 510篇 |
物理学 | 1051篇 |
无线电 | 1265篇 |
出版年
2023年 | 71篇 |
2022年 | 82篇 |
2021年 | 153篇 |
2020年 | 148篇 |
2019年 | 167篇 |
2018年 | 130篇 |
2017年 | 123篇 |
2016年 | 207篇 |
2015年 | 241篇 |
2014年 | 272篇 |
2013年 | 365篇 |
2012年 | 413篇 |
2011年 | 390篇 |
2010年 | 289篇 |
2009年 | 313篇 |
2008年 | 352篇 |
2007年 | 294篇 |
2006年 | 284篇 |
2005年 | 256篇 |
2004年 | 202篇 |
2003年 | 221篇 |
2002年 | 180篇 |
2001年 | 105篇 |
2000年 | 73篇 |
1999年 | 73篇 |
1998年 | 66篇 |
1997年 | 53篇 |
1996年 | 41篇 |
1995年 | 42篇 |
1994年 | 37篇 |
1993年 | 30篇 |
1992年 | 33篇 |
1991年 | 25篇 |
1990年 | 20篇 |
1989年 | 18篇 |
1988年 | 10篇 |
1987年 | 16篇 |
1986年 | 8篇 |
1985年 | 15篇 |
1984年 | 18篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 28篇 |
1978年 | 28篇 |
1977年 | 49篇 |
1976年 | 18篇 |
1975年 | 18篇 |
1974年 | 11篇 |
1943年 | 10篇 |
排序方式: 共有6074条查询结果,搜索用时 12 毫秒
31.
This article addresses the dynamic output feedback consensus problem of continuous‐time networked multiagent systems. Both a fixed topology and Markovian switching topologies are considered. The consensus algorithms are on the base of the output information of each agent's itself and its neighbors. Some sufficient conditions for consensus of multiagent systems are obtained in forms of bilinear matrix inequalities. The algorithm based on the homotopy continuation method is given to compute the feasible controller gains. Numerical simulations are given to show the effectiveness of the proposed results. © 2014 Wiley Periodicals, Inc. Complexity 20: 35–42, 2015 相似文献
32.
Xie Ju Yang Yanwu Xi Ziqing Yang Zhenshan Zhang Xuecheng Ni Lubin 《Journal of inclusion phenomena and macrocyclic chemistry》2022,102(9-10):751-761
Journal of Inclusion Phenomena and Macrocyclic Chemistry - The combination of the electron donor and acceptor into a donor–acceptor system can transform the intermolecular charge transfer... 相似文献
33.
Nan Zhao Huawei Mou Yuguang Zhou Xinxin Ju Shoujun Yang Shan Liu Renjie Dong 《Molecules (Basel, Switzerland)》2021,26(4)
Developing a green and sustainable method to upgrade biogas wastes into high value-added products is attracting more and more public attention. The application of solid residues as a performance enhancer in the manufacture of biofilms is a prospective way to replace conventional plastic based on fossil fuel. In this work, solid digestates from the anaerobic digestion of agricultural wastes, such as straw, cattle and chicken manures, were pretreated by an ultrasonic thermo-alkaline treatment to remove the nonfunctional compositions and then incorporated in plasticized starch paste to prepare mulching biofilms by the solution casting method. The results indicated that solid digestate particles dispersed homogenously in the starch matrix and gradually aggregated under the action of a hydrogen bond, leading to a transformation of the composites to a high crystalline structure. Consequently, the composite biofilm showed a higher tensile strength, elastic modulus, glass transition temperature and degradation temperature compared to the pure starch-based film. The light, water and GHG (greenhouse gas) barrier properties of the biofilm were also reinforced by the addition of solid digestates, performing well in sustaining the soil quality and minimizing N2O or CH4 emissions. As such, recycling solid digestates into a biodegradable plastic substitute not only creates a new business opportunity by producing high-performance biofilms but also reduces the environmental risk caused by biogas waste and plastics pollution. 相似文献
34.
Dong‐Won Lee Won‐Ju Cho Jun‐Kwang Song Oh‐Yun Kwon Won‐Hee Lee Chi‐Hong Park Kyung‐Eun Park Heesoo Lee Yong‐Nam Kim 《Progress in Photovoltaics: Research and Applications》2015,23(7):829-837
High‐temperature‐induced and humidity‐induced degradation behaviors were investigated through the failure analysis of encapsulated Cu(In,Ga)Se2 (CIGS) modules and non‐encapsulated CIGS cells. After being exposed to high temperature (85 °C) for 1000 h, the efficiency loss of CIGS modules and the resistivities of the aluminum‐doped zinc oxide (AZO) layer, CIGS layer, and Mo layer were slightly increased. After damp heat (DH) testing (85 °C/85% RH), the efficiency of some modules decreased significantly accompanied by discoloration, and in these areas, the resistivity of the AZO layers increased markedly. The causes of degradation of CIGS cells after high temperature and DH tests were suggested through X‐ray photoelectron spectroscopy analysis. The high‐temperature‐induced degradation behaviors were revealed to be increases in series resistance of the CIGS cells, due to the adsorption of oxygen on the AZO, CIGS, and Mo layers. The degradation behavior after DH (85 °C/85% RH) exposure was caused by the adsorption of oxygen, as well as the generation of Zn(OH)2 due to water molecules. In particular, the humidity‐induced degradation behavior in discolored CIGS modules was ascribed to the generation of Zn(OH)2 and carboxylic acids in the AZO layer, due to a chemical reaction between the AZO, ethylene‐vinyl acetate copolymer, and water. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
35.
In order to replace terpolymer with bipolymer, a bifunctional comonomer β-methylhydrogen itaconate (MHI) containing carboxyl group and ester group was synthesized to prepare poly[acrylonitrile-co-(β-methylhydrogen itaconate)] [P(AN-co-MHI)] bipolymers used as carbon fiber precursor for improving the stabilization and spinnability at the same time. The P(AN-co-MHI) bipolymers with different monomer feed ratios were characterized by elemental analysis, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and differential scanning calorimetry (DSC). The results show that both the polymerization conversion and molecular mass of P(AN-co-MHI) reduce with the increasing MHI amounts in the feed due to the larger molecular volume of MHI than acrylonitrile (AN). The monomer reactivity ratios were calculated by Fineman–Ross and Kelen–Tüdõs methods, the results show good agreement and MHI possesses higher reactivity than AN. Two parameters $ E_{\text{s}} = A_{{1,629\,{\text{cm}}^{ - 1} }} /A_{{2,244\,{\text{cm}}^{ - 1} }} $ and $ SI = (I_{0} - I_{\text{S}} )/I_{0} $ were defined to evaluate the extent of stabilization, and the activation energy (E a) of the cyclization was calculated by Kissinger method and Ozawa method. The FTIR, XRD, and DSC results show that P(AN-co-MHI) bipolymers exhibit significantly improved stabilization characteristics than PAN homopolymer, such as larger extent of stabilization, lower initiation temperature, and smaller E a of cyclization, which is attributed to the ionic initiation by MHI comonomer and it is beneficial to preparing high-performance carbon fiber. 相似文献
36.
A novel three‐component strategy for the azidotrifluoromethylation of alkenes has been presented here. The reaction proceeded smoothly under gentle temperature and gave the bifunctional olefins in high yields. Furthermore, 1,3‐dipolar reactions between azide‐containing products and phenylacetylene revealed great potential in molecular modification by using this method. 相似文献
37.
38.
AlxGa1−xAs LPE growth was studied within the temperature range of 930–900°C with Al concentrations in solutions from 0.04 to 2.4 at.%. AlAs concentration in layers has been shown to grow with the cooling rate increase of solution. Interface and volume nucleation parameter dependence of Ki and Kv and formation time tf on Al concentration in Ga solution have been found. Addition of Al to Ga solution increases critical values of As supersaturation (supercooling) and, as a result, increase in thickness of AlxGa1−xAs layers compared with GaAs layers have been determined in spite of As concentration lowering in Ga solution. 相似文献
39.
Cellulase could not be selectively collected from fermentation broth by simple foam fractionation, because of the presence
of other more surface-active compounds. A new approach of affinity foam fractionation was investigated for improvement. A
hardwood hydrolysate (containing cellulose oligomers, substrates to cellulase) and two substrate analogs, i.e., carboxymethyl
cellulose (CMC) and xylan hydrolysate, were added before the foaming process. The substrates and substrate analogs were indeed
found to bind the cellulase selectively and form more hydrophobic complexes that partition more readily onto bubble surfaces.
In this study, the effects of the type and concentration of substrate/analog as well as the presence of cells at different
growth stages were examined. The foam fractionation properties evaluated included foaming speed, foam stability, foamate volume,
and enrichment of filter paper unit (FPU) and individual cellulase components (i.e., endoglucanases, exoglucanases, and β-glucosidases).
Depending on the broth and substrate/analog employed, the foamate FPU could be more than fourfold higher than the starting
broth FPU. Addition of substrate/analog also deterred the enrichment of other extracellular proteins, resulting in the desired
cellulase purification in the foamate. The value of E/P (enzyme activity-FPU/g/L of proteins) in the foamate reached as high
as 18, from a lactose-based fermentation broth with original E/P of 5.6. Among cellulase components, exoglucanases were enriched
the most and β-glucosidases the least. The study with CMC of different molecular weights (MW) and degrees of substitution
(DS) indicated that the CMC with low DS and high MW performed better in cellulase foam fractionation. 相似文献
40.
Tae Woo Kim Eun‐Jin Oh Ah‐Young Jee Seung Tae Lim Dae Hoon Park Minyung Lee Sang‐Hoon Hyun Prof. Jin‐Ho Choy Prof. Seong‐Ju Hwang Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(41):10752-10761
A colloidal suspension of exfoliated, layered cobalt oxide nanosheets has been synthesized through the intercalation of quaternary tetramethylammonium ions into protonated lithium cobalt oxide. According to atomic force microscopy, exfoliated nanosheets of layered cobalt oxide show a plateau‐like height profile with nanometer‐level height, underscoring the formation of unilamellar 2D nanosheets. The exfoliation of layered cobalt oxide was cross‐confirmed by X‐ray diffraction, UV/Vis spectroscopy, and transmission electron microscopy. The maintenance of the hexagonal in‐plane structure of the cobalt oxide lattice after the exfoliation process was evidenced by selected‐area electron diffraction and Co K‐edge X‐ray absorption near‐edge structure analysis. The zeta‐potential measurements clearly demonstrated the negative surface charge of cobalt oxide nanosheets. Adopting the nanosheets of layered cobalt oxide as a precursor, we were able to prepare the monodisperse CoO nanocrystals with a particle size of ≈10 nm as well as the heterolayered film composed of cobalt oxide monolayer and polycation. 相似文献