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151.
在生产中引入高介电常数绝缘材料/金属栅电极结构,需要采用全新的制造技术,前驱物和输运系统推动了铪基材料栅极绝缘层的应用。AID技术也促进了新一代栅电极材料的推广和应用。 相似文献
152.
Jeff Meisel 《今日电子》2008,(1):69-71
根据摩尔定律,芯片上晶体管的数目每隔18~24个月就会翻一番。如同在过去40年里一样,这个定律现在还是正确的,但是在性能上却并不再呈现一个线性增强的现象。以前,芯片制造商通过提高处理器时钟速度使芯片性能翻番——从100MHz到200MHz,直至近来达到吉赫兹。 相似文献
153.
引言
把语音服务、高分辨率相机模块、MP3或PMP播放器功能整合在单个移动电话设计中,已成为未来中高端电话市场的发展趋势。除了超高的功率(〉700mW)立体声音频功能外,视频输出功能也出现在手机应用中,其输出仍主要是CVBS格式,而某些电话甚至提供S视频或模拟RGB输出。 相似文献
154.
Jeff M. VanRaden Brittany M. White Lev N. Zakharov Ramesh Jasti 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(22):7419-7423
The unique optoelectronic properties and smooth, rigid pores of macrocycles with radially oriented π systems render them fascinating candidates for the design of novel mechanically interlocked molecules with new properties. Two high‐yielding strategies are used to prepare nanohoop [2]rotaxanes, which owing to the π‐rich macrocycle are highly emissive. Then, metal coordination, an intrinsic property afforded by the resulting mechanical bond, can lead to molecular shuttling as well as modulate the observed fluorescence in both organic and aqueous conditions. Inspired by these findings, a self‐immolative [2]rotaxane was then designed that self‐destructs in the presence of an analyte, eliciting a strong fluorescent turn‐on response, serving as proof‐of‐concept for a new type of molecular sensing material. More broadly, this work highlights the conceptual advantages of combining compact π‐rich macrocyclic frameworks with mechanical bonds formed via active‐template syntheses. 相似文献
155.
Jia Zhang Yue Yuan Minling Gao Zheng Han Chengyan Chu Yuguo Li Peter C. M. vanZijl Mingyao Ying Jeff W. M. Bulte Guanshu Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(29):9976-9980
While carbon dots (C‐dots) have been extensively investigated pertaining to their fluorescent, phosphorescent, electrochemiluminescent, optoelectronic, and catalytic features, their inherent chemical exchange saturation transfer magnetic resonance imaging (CEST MRI) properties are unknown. By virtue of their hydrophilicity and abundant exchangeable protons of hydroxyl, amine, and amide anchored on the surface, we report here that C‐dots can be adapted as effective diamagnetic CEST (diaCEST) MRI contrast agents. As a proof‐of‐concept demonstration, human glioma cells were labeled with liposomes with or without encapsulated C‐dots and implanted in mouse brain. In vivo CEST MRI was able to clearly differentiate labeled cells from non‐labeled cells. The present findings may encourage new applications of C‐dots for in vivo imaging in deep tissues, which is currently not possible using conventional fluorescent (near‐infrared) C‐dots. 相似文献
156.
Yue Yuan Zhiliang Wei Chengyan Chu Jia Zhang Xiaolei Song Piotr Walczak Jeff W. M. Bulte 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(43):15658-15663
The healthy prostate contains the highest concentration of mobile zinc in the body. As this level decreases dramatically during the initial development of prostate cancer, in vivo detection of prostate zinc content may be applied for diagnosis of prostate cancer. Using 19F ion chemical exchange saturation transfer magnetic resonance imaging (iCEST MRI) and TF‐BAPTA as a fluorinated Zn‐binding probe with micromolar sensitivity, we show that iCEST MRI is able to differentiate between normal and malignant prostate cells with a 10‐fold difference in contrast following glucose‐stimulated zinc secretion in vitro. The iCEST signal decreased in normal prostate cells upon downregulation of the ZIP1 zinc transporter. In vivo, using an orthotopic prostate cancer mouse model and a transgenic adenocarcinoma of the mouse prostate (TRAMP) model, a gradual decrease of >300 % in iCEST contrast following the transition of normal prostate epithelial cells to cancer cells was detected. 相似文献
157.
158.
A probability measurep on the set of matchings in a graph (or, more generally 2-bounded hypergraph) ishard-core if for some : [0,), the probabilityp(M) ofM is proportional to
. We show that such distributions enjoy substantial approximate stochastic independence properties. This is based on showing that, withM chosen according to the hard-core distributionp, MP () the matching polytope of , and >0, if the vector ofmarginals, (Pr(AM):A an edge of ), is in (1–) MP (), then the weights (A) are bounded by someA(). This eventually implies, for example, that under the same assumption, with fixed,
as the distance betweenA, B tends to infinity.Thought to be of independent interest, our results have already been applied in the resolutions of several questions involving asymptotic behaviour of graphs and hypergraphs (see [14, 16], [11]–[13]).Supported in part by NSFThis work forms part of the author's doctoral dissertation [16]; see also [17]. The author gratefully acknowledges NSERC for partial support in the form of a 1967 Science and Engineering Scholarship. 相似文献
159.
160.
C. Jeff Harlan Simon G. Bott Andrew R. Barron 《Journal of chemical crystallography》1998,28(8):649-651
Reaction of AlH3[N(CH2CH2)3CH] with hexamethyltrisiloxane, (OSiMe2)3, gives rise to the bis-quinuclidine complex AlH3[N(CH2CH2)3CH]2, which has been characterized by 1H and 13C NMR spectroscopy and X-ray crystallography. The molecular structure of AlH3[N(CH2CH2)3CH]2 consists of a trigonal bipyramidal aluminum with axial coordination of the quinuclidine ligands. Crystal data: orthorhombic, space group Pbcn, a = 10.6895(9), b = 12.266(1), c = 12.3794(9) Å, V = 1623.2(2) Å3, and Z = 4. 相似文献