Charge plate technique in recoil study: Evidence for collection of recoil charged species from solid targets on metal electrodes

The occurrence of charge on recoil⁵⁶Mn produced by the (n,γ) reaction in polycrystalline potassium permanganate has been examined using the ‘charge plate technique’. From considerations of capture gamma ray decay schemes and internal conversion it appears that, in a condensed medium, the recoil atom develops charge after losing much of its initial kinetic energy which allows collection on charged electrodes. Preliminary findings were presented at the International Symposium on Radiochemistry and Radiation Chemistry, RC-41 BARC, Bombay, Feb. 4–6 (1991).     

A model for electroluminescence in SrS:Ce ACTFEL display devices

An analytical model for electroluminescence in SrS:Ce AC thin-film electroluminescent display devices is presented. The model incorporates an exact calculation of the electric field and the effect of activator ionization and bulk traps. Activator ionization is needed to explain several features of luminescence behavior in SrS:Ce devices. These features include the second luminescence peak at the trailing edge of the voltage pulse and the time lag between the luminescence and the applied voltage when the applied voltage consists of bipolar trapezoidal pulses and rectangular pulses of low voltage amplitudes. As a mechanism for the ionization of activators, field-assisted tunneling is shown to be more likely than impact ionization by hot electrons. Physical processes are described in terms of rate equations, and field, current, and luminescence waveforms are calculated for one set of device parameters. The calculated and experimental luminescence waveforms agree     

Dielectric properties of KDP-type ferroelectric crystals in the presence of external electric field

Considering external electric field as well as third- and fourth-order phonon anharmonic interaction terms in the pseudospin-lattice coupled mode (PLCM) model Hamiltonian for KDP-type ferroelectrics, expressions for field-dependent shift, width, renormalized soft mode frequency, Curie temperature, dielectric constant and dielectric loss are evaluated. For the calculation, method of statistical double-time temperature-dependent Green’s function has been used. By fitting model values of physical quantities, temperature and electric field dependences of soft mode frequency, dielectric constant and loss have been calculated which compare well with experimental results of Baumgartner [8] and Choi and Lockwood [9]. Both dielectric constant and loss decrease with electric field.     

Catalysis by Ir(III), Rh(III) and Pd(II) metal ions in the oxidation of organic compounds with H2O2

Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H₂O₂. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd.     

Thermal effects on parallel resonance energy of whistler mode wave

In this short communication, we have evaluated the effect of thermal velocity of the plasma particles on the energy of resonantly interacting energetic electrons with the propagating whistler mode waves as a function of wave frequency and L-value for the normal and disturbed magnetospheric conditions. During the disturbed conditions when the magnetosphere is depleted in electron density, the resonance energy of the electron enhances by an order of magnitude at higher latitudes, whereas the effect is small at low latitudes. An attempt is made to explain the enhanced wave activity observed during magnetic storm periods.     

A transmit/receive IF chip set for WCDMA mobiles in 0.35 /spl mu/m CMOS

An implementation of the IF section of WCDMA mobile transceivers with a set of two chips fabricated in an inexpensive 0.35-/spl mu/m two-poly three-metal CMOS process is presented. The transmit/receive chip set integrates quadrature modulators and demodulators, wide dynamic range automatic gain control (AGC) amplifiers, with linear-in-decibel gain control, and associated circuitry. This paper describes the problems encountered and the solutions envisaged to meet stringent specifications, with process and temperature variations, thus overcoming the limitations of CMOS devices, while operating at frequencies in the range of 100 MHz-1 GHz. Detailed measurement results corroborating successful application of the new techniques are reported. A receive AGC dynamic range of 73 dB with linearity error of less than /spl plusmn/2 dB and spread of less than 5 dB for a temperature range of -30/spl deg/C to +85/spl deg/C in the gain control characteristic has been measured. The modulator measurement shows a carrier suppression of 35 dB and sideband/third harmonic suppression of over 46 dB. The core die area of each chip is 1.5 mm/sup 2/.     

HPTLC Determination of Swertiamarin and Amarogentin in Swertia Species from the Western Himalayas

JPC – Journal of Planar Chromatography – Modern TLC - A high-performance thin-layer chromatographic (HPTLC) method has been established for simple and rapid quantification of two...     

On the stability of the output characteristics of a grazing incidence grating dye laser transversely pumped by a copper vapor laser

The output characteristics of a high repetition rate pulsed dye laser has both short-term fluctuations and long-term drift. In high power high repetition rate lasers flow induced variations dominate over those due to other factors. In this paper it is shown by dye laser measurements that bandwidth fluctuations can be traced to the effective changes of the resonator dispersion due to fluctuations in the penetration depth of the pump beam in the dye medium. Short-term wavelength fluctuations can be traced to instantaneous deflection of the dye laser axis by the refractive index changes due to absorption of the pump beam. The fluctuations in both the bandwidth and the wavelength decreases with increasing flow rates within a laminar region. A copper vapor laser operating at 5.6 kHz repetition rate pumped the Rhodamine 6G dye laser used. The wavelength fluctuation of ±0.0035, 0.0030, 0.0004 nm and the bandwidth fluctuation of ±710, 132, 45 MHz over approx. 60 minutes were observed at 1.2, 3.7, 5.5 lpm flow rates respectively.     

A framework for reconfigurable computing: task scheduling and context management-a summary

Reconfigurable computing is consolidating itself as a real alternative to ASICs (Application Specific Integrated Circuits) and general-purpose processors. The main advantage of reconfigurable computing derives from its unique combination of broad applicability, provided by the reconfiguration capability, and achievable performance, through the potential parallelism exploitation. The key aspects of the scheduling problem in a reconfigurable architecture are discussed, focusing on a task scheduling methodology for DSP and multimedia applications, as well as the context management and scheduling optimizations.     

Study of photon-induced L3 vacancy alignment for elements La to U

Alignment of photon-induced L₃ vacancies is studied in rare earth and highZ elements at energies of experimental interest, near thresholds to 60 keV, under nonrelativistic dipole approximation. Numerical calculations of the matrix element are undertaken to produce theoretical data for comparison with the experimental findings. The A₂ values being s>0.1 at photoelectron energies <20 keV are certainly higher than 5–8% uncertainties quoted in experimental results. Present findings are from a very basic model, hydrogen-like and can further be treated as reference to observe the impact of screening, relativistic, multipole and retardation corrections to the model