全文获取类型
收费全文 | 371篇 |
免费 | 17篇 |
国内免费 | 8篇 |
专业分类
化学 | 221篇 |
晶体学 | 5篇 |
力学 | 9篇 |
综合类 | 1篇 |
数学 | 29篇 |
物理学 | 85篇 |
无线电 | 46篇 |
出版年
2023年 | 9篇 |
2022年 | 17篇 |
2021年 | 10篇 |
2020年 | 8篇 |
2019年 | 13篇 |
2018年 | 20篇 |
2017年 | 9篇 |
2016年 | 9篇 |
2015年 | 12篇 |
2014年 | 9篇 |
2013年 | 32篇 |
2012年 | 23篇 |
2011年 | 21篇 |
2010年 | 16篇 |
2009年 | 11篇 |
2008年 | 8篇 |
2007年 | 15篇 |
2006年 | 15篇 |
2005年 | 12篇 |
2004年 | 13篇 |
2003年 | 12篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 8篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1985年 | 3篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1968年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有396条查询结果,搜索用时 15 毫秒
41.
Yuan Hsing Fu Ai Qun Liu Wei Ming Zhu Xu Ming Zhang Din Ping Tsai Jing Bo Zhang Ting Mei Ji Fang Tao Hong Chen Guo Xin Hai Zhang Jing Hua Teng Nikolay I. Zheludev Guo Qiang Lo Dim Lee Kwong 《Advanced functional materials》2011,21(18):3589-3594
A micromachined reconfigurable metamaterial is presented, whose unit cell consists of a pair of asymmetric split‐ring resonators (ASRRs); one is fixed to the substrate while the other is patterned on a movable frame. The reconfigurable metamaterial and the supporting structures (e.g., microactuators, anchors, supporting frames, etc.) are fabricated on a silicon‐on‐insulator wafer using deep reactive‐ion etching (DRIE). By adjusting the distance between the two ASRRs, the strength of dipole–dipole coupling can be tuned continuously using the micromachined actuators and this enables tailoring of the electromagnetic response. The reconfiguration of unit cells endows the micromachined reconfigurable metamaterials with unique merits such as electromagnetic response under normal incidence and wide tuning of resonant frequency (measured as 31% and 22% for transverse electric polarization and transverse magnetic polarization, respectively). The reconfiguration could also allow switching between the polarization‐dependent and polarization‐independent states. With these features, the micromachined reconfigurable metamaterials may find potential applications in transformation optics devices, sensors, intelligent detectors, tunable frequency‐selective surfaces, and spectral filters. 相似文献
42.
Sarah Almazroa Mohamed H. Elnagdi Abdellatif M. Salah El‐Din 《Journal of heterocyclic chemistry》2004,41(2):267-272
The enaminones 1b,d,f react with 4‐phenyl‐3‐methyl‐5‐pyrazoleamine 3a to yield the pyrazole derivatives 4a‐c that cyclised readily on reflux in pyridine solution in presence of hydrochloric acid to yield the pyrazolo[1,5‐a]pyrimidines 5a‐c. Similarly 3(5)‐amino‐1H‐triazole (3b) reacted with 1b,d,f to yield the triazolo[1,5‐a]pyrimidines 5d‐f. In contrast attempted condensation of the 5‐tetrazoloamine (3c) with 1a,d,e resulted in its trimerisation and only triaroylbenzene 8a,d,e was isolated. The reaction of 1a,b,d with anthranilonitrile 9a and the reaction of 1a‐c with the 2‐aminocyclohexene thiophene‐3‐nitrile 10a afforded the cis enaminones 11a‐c and 12a‐c. Similarly, reaction of 1a‐c with the methylanthranilate 9b and reaction of 1b,e with ethyl 2‐aminocyclohexene thiophene‐3‐carboxylate 10b afforded the cis enaminones 11d‐f and 12d,e respectively. Attempted cyclization of 11a‐c into quinoline failed. Successful cyclization of 11d into the quinolinone 13 could be affected, on heating for five minutes in a domestic microwave oven at full power. The reaction of 1a‐c,f with piperidine afforded the trans enaminones 14a‐d. Similarly, trans 14e was formed from the reaction of 1b with morpholine. The coupling reaction of 1b with excess of benzene diazonium chloride afforded the formazane 16. The enaminone 2 reacted with heterocyclic amines to yield the pyridones 17,18. 相似文献
43.
44.
关于两类污染数据回归分析的参数估计 总被引:21,自引:0,他引:21
研究简单回归模型:yj=a+βxj+εj,j=1,2,…,n,其中Eεj=0,Eε^2j=σ^2j;但y1,y2,…,yn受到另一独立同分布随机变量序列t,t2,…,tn两种不同方式的污染,tj与yj独立。本文给出了两种污染方式下的a、β和污染参数的估计。 相似文献
45.
Kinetics of the DL ‐valine‐ninhydrin reaction has been studied spectrophotometrically under varying conditions of [CTAB], [ninhydrin], [DL ‐valine], pH, temperature, and %(v/v) organic solvents (solvents used: 1‐propanol, methylcellosolve, acetonitrile, and dimethyl sulfoxide). Addition of CTAB and increase in the proportion of organic solvents, both showed catalyzing effect on the reaction. The effect of simultaneous presence of CTAB and DMSO in the reaction mixture has also been seen. The rate profiles obtained for solutions containing from 10% to 70% DMSO exhibited clear maxima that shifted progressively to higher concentrations of CTAB. The experimental results are explained in terms of specific solvent effects and the formation of stoichiometric hydrate DMSO · 2H2O and the inhibitory effect of DMSO on micelle formation. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 634–642, 2006 相似文献
46.
本文在文[1],[2]的基础上,进一步讨论了算子超等距膨胀的性质,证明了T∈L(H)可超等距膨胀的充分必要条件是T≌P_H M|_H,或者T≌∑■ P_H M|_H这里M是Bergman位移,H∈LatM~*。 相似文献
47.
We calculate the action and the topological charge of classical solutions in two-dimensional euclidean grassmannian σ models (for both generic and special solutions). We show that all the above non-instanton or non-anti-instanton solutions are unstable. We also find solutions of the Dirac equation describing fermions in the background of these grassmannian fields, and we exhibit relations between these fermionic solutions and those of the associated Hilbert-Riemann problem. 相似文献
48.
R.M. Saleh J.M. Abd El Kader A.A. El Hosary A.M. Shams El Din 《Journal of Electroanalytical Chemistry》1975,62(1):297-310
The dissolution of Cu in solutions of HNO3 of different concentrations has been studied by the thermometric method. Starting from the initial temperature, Ti, the temperature—time curves exhibit an induction period followed by a rapid rise in temperature to a maximum value, Tm, attained t min after the start of the reaction. Tm increases and t decreases with increase of the acid concentration, M. ΔT (i.e.Tm ? Ti) and the reaction number (R.N. = (Tm ? Ti)/t) vary with M according to: ΔT = k(M ? M0) and R.N. = A1Mn, where k, M0, A1 and n are constants.The effect of varying concentrations of HCl, H2SO4 and H3PO4 on the R.N. of Cu in 3.5 M HNO3 was examined. Small amounts of these acids lower the R.N. (inhibition) due to the displacement of an active species on the surface of the metal by the anion of the acid. Larger additions of the acids accelerate dissolution. The concentration at which the added acid changes from corrosion-inhibitor to accelerator varies as HCl < H2SO4 < H3PO4. This sequence is considered to parallel the strength of adsorption of the respective anions. The results of experiments with salt additions confirm this view; all salts act only as dissolution-retardants. Calculations pertaining to the effect of the various ions on the R.N. support the conclusion that the dissolution of Cu in HNO3 is autocatalytic in nature, and depends on the [H+]/[NO3?] ratio.Cu does not dissolve in air-free, cold HCl. Attack takes place, however, in the presence of KNO3. Under these conditions attack is of the pitting- rather than the general type. The temperature rises suddenly after an incubation period, which decreases in length with increase of the amount of the added salt.Proof of the involvement of HNO2 in the autocatalytic cycle of Cu dissolution in HNO3 is obtained from the results of urea additions to the solution. 相似文献
49.
Excitation functions for a number of proton groups for the reactions 23Na(d, p)24Na and 27Al(d, p)28Al were measured in the energy range Ed = 1.5 to 3.0 MeV. The angular distributions for a number of proton groups were measured at a number of deuteron energies below 3.0 MeV for the three reactions 12C(d, p)13C, 23Na(d, p)24Na and 27Al(d, p)28Al. The theory of deuteron stripping reactions at incident energies below the Coulomb barrier has been considered. A closed analytical form for the differential cross-section has been obtained considering three cases according to the incident deuteron and outgoing proton energies. An attempt has been made to fit the angular distribution measurements at a number of deuterons bombarding energies accordingly. 相似文献
50.
As a perturbation to the P(?)2 theory we consider interaction densities of the form V(?(x)), where ?(x) is a scalar hermitian boson field and V(α) is a bounded real continuous function. It is proved that the asymptotic fields exist and are equal to the asymptotic fields of the P(?)2 theory. The connection with non-polynomial theories of rational type is indicated. Furthermore the consequences of a bounded perturbation for the S-matrix and the spectral properties are discussed. 相似文献